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I. P R O P O RT I O N S I N C H E M I C A L C O M P O U N D S ( 2 )

True (T) or false (F) [2]:

1. The law of definite proportions proves that CO2 and CO both decompose to produce the same
weight of carbon and oxygen. _______________
2. Joseph Proust stated that a specific compound always contains the same elements in definite
proportions by mass. _______________

II. THE CHEMICAL MOLE (30)

Calculate the number of molecules in 20.05 g of P2S5 (s) [3] :

Calculate the mass of 2.893 x 1020 molecules of BF3 (g) [3] :

Calculate the number of moles in 15.0 g of CaO (s) [3] :

Calculate the number of copper ions found in 13.7 moles of chalcocite (Cu 2S (s)) [3] :

Calculate the mass of 20.00 mL of O2 (g) at STP [3] :

Calculate the moles of iodine atoms in 2.00 L of hydrogen iodide (HI (g)) at SATP [3] :
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Calculate the mass of 1.27 x 1024 molecules of sodium orthoperiodate (Na5IO6 (aq)) [3] :

Calculate the moles of bromine vapour (Br2 (g)) in 72.48 kg [3] :

Calculate the moles of chloride ions found in 7.894 moles of PbCl 4 (s) [3] :

Calculate the mass of galena (PbS2 (s)) required to produce 4.96 x 1023 sulfide ions [3] :

I I I. P E R C E N TA G E C O M P O S I T I O N ( 2 0 )

Calculate the percentage composition of soda ash (Na 2CO3) from its formula [3] :

In an experiment, 6.900g of sodium metal reacted with 10.66g of chlorine gas to give 17.56g of sodium
chloride. Calculate the percentage composition of table salt (NaCl) from empirical data [3] :
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When a 6.00g sample of an organic compound (CXHXOX) was completely combusted, 2.34g of water and
5.74g of carbon dioxide were produced. Calculate the percentage composition of this compound [4] :

Calculate the percentage composition of chloromycetin (C 11H12N2O5Cl2) [3] :

Calculate the weight of chlorine that can be obtained from the decomposition of 100.0g of calcium
chloride (CaCl2) [3] :

A 24.00g sample of a mixture of KClO3 and KCl is heated until all the oxygen is removed. The product,
completely KCl, weighs 18.00g. Calculate the percentage of KClO3 in the original mixture [4] :

I V. EMPIRICAL & MOLECULAR FORMULAE (22)

What do the subscripts in a formula represent [1] ? ____________________

Indicate whether the following formulas are empirical (E) or molecular (M) [5] :
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CH4 SO2 CH2O C6H12O6 Na2O2

____________________ ____________________ ____________________ ____________________ ____________________

233.7g of aluminum react with 417.0g of sulfur. Determine the empirical formula for the compound [3] :

A compound contains 82.5% carbon and 17.5% hydrogen. Determine the empirical formula for the
compound [3] :

Titanium(_) chloride (TiClX) is converted into 2.40g of TiO2 and 12.9g of AgCl. Determine the empirical
formula for the original compound [3] :

The percentage composition of a compound is 5.9% hydrogen and 94.1% oxygen. Determine the
molecular formula for the compound if its weight is 34g/mol [3] :

The simplest formula of 1,2-dibromoethane, a colourless liquid with a sweet odour and manufactured
synthetically by the reaction of ethylene with bromine, is CH 2Br. Determine the molecular formula for
the compound if its molar mass is 187.86g/mol [4] :
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V. B A L A N C I N G C H E M I C A L E Q U AT I O N S ( 2 0 )

Balance the following equations [20] :

1. SiCl4 (l) + H2O (l) SiO2 (s) + HCl (aq)

2. As (s) + NaOH (aq) Na3AsO3 (s) + H2 (g)

3. Au2S3 (s) + H2 (g) Au (s) + H2S (g)

4. V2O5 (s) + HCl (aq) VOCl3 (aq) + H2O (l)

5. Hg(OH)2 (aq) + H3PO4 (aq) Hg3(PO4)2 (aq) + H2O (l)

6. SiO2 (s) + HF (g) SiF4 (g) + H2O (l)

7. Zn(s) + HCl (aq) ZnCl2 (s) + H2 (g)

8. HClO4 (aq) + P4O10 (s) H3PO4 (aq) + Cl2O7 (aq)

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9. N2 (g) + O2 (g) + H2O (l) HNO3 (aq)

10. NH4NO3 (s) N2 (g) + O2 (g) + H2O (l)

V I. G R AV I M E T R I C S TO I C H I O M E T RY ( 3 1 )

The average human requires 120.0 grams of glucose (C 6H12O6) per day. How many grams of CO2 (in the
photosynthesis reaction) are required for this amount of glucose? The photosynthetic reaction is [3] :

6 CO2 (g) + 6 H2O (l) C6H12O6 (aq) + 6 O2 (g)

Silver sulfide (Ag2S) is the common tarnish on silver objects. What weight of silver sulfide can be made
from 1.23 mg of hydrogen sulfide (H2S) obtained from a rotten egg? The reaction of formation of silver
sulfide is given below, however, the equation must first be balanced [5] :

Ag(s) + H2S(g) + O2(g) Ag2S(s) + H2O(l)

Given the following equation: 2 C4H10 (g) + 13 O2 (g) 8 CO2 (g) + 10 H2O (l) , show what the
following molar ratios should be [5] :

a. C4H10 / O2
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b. O2 / CO2

c. O2 / H2O

d. C4H10 / CO2

e. C4H10 / H2O

Given the following equation: 2 K(s) + Cl2 (aq) 2 KCl (aq) :

a) How many grams of KCl are produced from 2.50 g of K and excess Cl 2? [3]
b) From 1.00 g of Cl2 and excess K? [3]

Given the following equation: Na2O(s) + H2O (l) 2 NaOH (aq)

a) How many grams of NaOH are produced from 1.20 x 102 grams of Na2O? [3]
b) How many grams of Na2O are required to produce 1.60 x 102 grams of NaOH? [3]

Given the following equation: Cu (s) + 2 AgNO3 (aq) Cu(NO3)2 (aq) + 2 Ag (s)

a) How many moles of copper are needed to react with 3.50 moles of silver nitrate? [3]
b) If 89.5g of silver were produced, how many grams of copper reacted? [3]
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V I I. N O M E N C L AT U R E ( 7 0 )

Give the correct name of the following compounds [15] :

1. HBr (aq) ______________________________

2. CoSO2 ______________________________

3. Ni2(CO4)3 ______________________________

4. KO2 ______________________________

5. Ba3(PO3)2 ______________________________

6. SO3 ______________________________
7. RbOH ______________________________

8. SnH4 ______________________________

9. Hg(VO2)2 ______________________________
10. PbC ______________________________

11. Au(C2H3O2)3 ______________________________

12. NH4ClO4 ______________________________

13. H2CrO4 ______________________________

14. Na2O2 ______________________________

15. LiNO3 • 12H2O ______________________________

Name the following polyatomic ions [5] :

1. SO42- ____________________

2. C2H3O2- ____________________

3. NO3- ____________________

4. NH4+ ____________________
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5. PO43- ____________________

What is the difference between HCN(g) and HCN(aq) in terms of nomenclature [2] ?
______________________________________________________________________________
______________________________________________________________________________
Give the correct chemical formula of the following compounds [15] :
1. Ammonium Acetate ______________________________
2. Hydrogen Peroxide ______________________________
3. Nitrous Acid ______________________________
4. Strontium Sulfite Octahydrate ______________________________
5. Chromium(VI) Orthohypoaresnite ______________________________
6. Chromium(II) Metaperarsenate ______________________________
7. Tin(IV) Oxide ______________________________
8. Diphosphorus Pentachloride ______________________________
9. Titanium(II) Pertitanate ______________________________
10. Gold(III) Hypostannite ______________________________
11. Thallium Carbide ______________________________
12. Cobalt(III) Selenide ______________________________
13. Chlorine gas ______________________________
14. Iron(III) Carbonate ______________________________
15. Disulfur Tetroxide ______________________________

Explain why F3N is not a correct chemical formula [1] :

______________________________________________________________________________
______________________________________________________________________________

Give two valences of the following multivalent metals [16] :

1. lead _____ _____
2. nickel _____ _____
3. mercury _____ _____
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4. gold _____ _____

5. iron _____ _____
6. tin _____ _____
7. cobalt _____ _____
8. copper _____ _____

Give the IUPAC name for sulfuric acid (H2SO4 (aq)) [1] :
____________________________________

Fill in the missing blanks [8] :

Formula
Type Name

LiBr(s)
MONOVALENT BINARY IONIC COMPOUND _________________________

MULTIVALENT BINARY IONIC COMPOUND ____________ Copper(II) Chloride

TERTIARY IONIC COMPOUND Na3PO4 (aq) _________________________
Copper(II) Sulfate
HYDRATED COMPOUND ____________ Pentahydrate
MOLECULAR COMPOUND H2S _________________________
BINARY ACID ____________ Hydrofluoric Acid
OXYACID HClO4 (aq) _________________________
BASIC COMPOUND (BASE) ____________ Aqueous Sodium Hydroxide

Give the formula for the following polyatomic ions [5] :

1. thiosulfate ____________________
2. hydroxide ____________________
3. carbonate ____________________
4. cyanide ____________________
5. chlorate ____________________

Fill in and name the cation that will complete this acid reaction chemical equation [2] :
>99% -
HNO3 (aq) + H2O(l) NO3 (aq) + ________ (aq)
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Cation: ____________________