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Title: Exam 1
Started: February 24, 2010 4:08 PM
Submitted: February 24, 2010 4:57 PM
Time spent: 00:49:42
Total
19/20 = 95% Total score adjusted by 0.0 Maximum possible score: 20
score:

1.

Which type of intermolecular force ("interparticle force") is the most important in

CH2I2(l)?

  Student Response Value Correct

Answer

1. London Dispersion  

  2. Dipole-dipole forces 100%  

3. Hydrogen bonds  

4. Ion-dipole forces  

5. Ionic bonds  

Score: 1/1
 

2.

Which of the following substances would be expected to have the highest heat of
fusion?

  Student Response Value Correct

Answer

1. CF4  

2. methane  
 
3. CI4 100%  

4. CCl4  

5. CBr4  

Score: 1/1
 

3.
 How much energy in J is needed to convert 99 g of solid ethanol at -130 oC to
liquid at -85oC. You might need to know that:
mp = -114 oC and bp = 78oC
The heat of fusion is 4.6 kJ/mol and the heat of vaporization is 46.0 kJ/mol.
Finally, the specific heats of the solid, liquid and gas are, respectively 2.1, 3.2
and 1.8 J/g oC.

  Student Response Value Correct

Answer

  1. 12510  

2. 22400 100%  

3. 20100  

4. 468000  

5. 112000  

Score: 1/1
 

4.

Which of the following statements is true?

  Student Response Value Correct

Answer

A. The critical point of a substance decrease when the  

temperature increases.

B. Both the triple point and the critical point of a 100%  

substance are dependent on the substance only, but
not on temperature or pressure.
 
C. The triple point of a substance increases when the  
pressure increases.

D. Both the triple point and the critical point of a  

substance increase with a decrease in temperature.

E. None of these are true.  

Score: 1/1
 

5.

  Which of the following statements is true?

  Student Response Value Correct

Answer

A. The addition of a non-volatile solute to a solvent  

increases the vapor pressure of the resulting
 solution.

B. Molarity is independent of temperature  

C. Substances with similar intermolecular forces have 100%  

solute-solvent interactions that favor solution
formation.

D. Just about all ionic compounds are soluble in water.  

E. An unlimited amount of any solute can be dissolved  

in any solvent

Score: 1/1
 

6.

What is the strongest form of intermolecular force between solute and solvent in
a solution of pentane, C5H12(l), in toluene, C7H8(l)?

  Student Response Value Correct

Answer

1. hydrogen bonding  

  2. dispersion 100%  

3. dipole-induced dipole  

4. ion-dipole  

5. dipole-dipole  

Score: 1/1
 

7.

Which of the following is more soluble in water, methanol or CI2H2(l). Don't try to
type the subscripts, just use letters and numbers.

  Student Response Value Correct Answer

 
1.  methanol  100% Equals methanol (100%)

Score: 1/1
 

8.

  Calculate the molality of an aqueous solution that is 20.1% by mass calcium

chloride. You might need to know that the density is 1.20 g/mL.

  Student Response Value Correct

Answer
 A. 2.26 100%  

B. 2.17  

C. 2.63  

D. 3.33  

E. 1.81  

Score: 1/1
 

9.

Describe acetic acid (CH3COOH) as a strong electrolyte, weak electrolyte,or non-

electrolyte.

  Student Response Value Correct Answer

  1.  weak electrolyte  100% Equals weak electrolyte (100%)
Equals weak (100%)

Score: 1/1
 

10.

Which of the following aqueous solutions will have the highest boiling point?

  Student Response Value Correct

Answer

A. 0.100 m CaCl2  

B. 0.100 m K3PO4 100%  

 
C. All have the same molality so all will have the same  
value.

D. 0.100 m glucose (C6H12O6)  

E. 0.100 m NaCl  

Score: 1/1
 

11.

  Calculate the vapor pressure (in torr) at 293 K in a solution prepared by

dissolving 19.6 g of the non-volatile non-electrolye urea {CO(NH2)2} in 152 g of
water. The vapor pressure of water at 293 K is 17.54 torr.

  Student Response Value Correct Answer

Answer: 16.89   100% 16.89

 Score: 1/1
 

12.

2.22 grams of an unknown non-electrolytic solute were dissolved in 60.0 g of

water (Kfp = 1.86 K/m). If the freezing point of the solution was -0.240 oC,
determine the molar mass of the unknown solute.

  Student Response Value Correct

Answer

A. 287 g/mol 100%  

  B. 209 g/mol  

C. 4.77 g/mol  

D. 298 g/mol  

E. 0.29 g/mol  

Score: 1/1
 

13.

H2Z is a nonvolatile, water-soluble substance. When 1.23 x 10-2 mol of H2Z is

dissolved in 40.0 g of water (Kfp = 1.86 oC/m), the freezing point of the resulting
solution is –1.43 oC. Choose the equation that best describes the dissolution of
H2Z.

I. H2Z(s) => H2Z(aq)

II. H2Z(s) => H+(aq) + HZ-(aq)

III. H2Z(s) => 2H+(aq) + Z2-(aq)

  Student Response Value Correct

  Answer

A. I only  

B. II only  

C. Equal combination of II and III 100%  

D. III only  

E. Equal combination of I and II  

Score: 1/1
 

14.
 For the reaction, 4 A(g) + 3 B(g) => 2 C(g), the following data were obtained at
constant temperature.
Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min
1 0.200 0.150 5.00
2 0.400 0.150 20.0
3 0.200 0.300 10.0
4 0.400 0.300 40.0
  Calculate the value of k to 3 significant figures.

  Student Response Value Correct Answer

1.  833  100% Equals 833 (100%)

Equals 8.33E2 (100%)

Score: 1/1
 

15.

In a first order decomposition, how long does it take (in seconds) for 33% of the
compound to decompose given that k is 0.0402 sec-1 (give answer to 3 sig figs
using E notation)?

    Student Response Value Correct Answer

Answer: 9.96E0   100% 10.0

Score: 1/1
 

16.

The rate law for the reaction 2A => 4B is rate = k[A] with a rate constant of
0.445 sec-1. What is the half-life of the reaction?

  Student Response Value Correct

Answer

1. 0.223  

2. 1.56 100%  
 
3. 4.49  

4. Cannot answer without knowing the initial  

concentration.

5. 0.642  

Score: 1/1
 

17.
 The rate law of a particular reaction is found to be, rate = k[A]2[B]. Which of the
following statements is FALSE?

  Student Response Value Correct

Answer

A. Tripling the concentration of A will result in a nine-  

fold increase in the rate

B. The actual value of k will depend on the  

  temperature

C. The units of k could be (L2/mol2 sec)  

D. The actual value of k will depend on the 100%  

concentrations of A and B.

E. The reaction is third order overall.  

Score: 1/1
 

18.

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2

By what factor does the rate change if the concentration of BrO3- is decreased by
a factor of 2, that of Br- is decreased by a factor of 2 and that of H+ is doubled?

  Student Response Value Correct Answer

 
1.  1  100% Equals 1 (100%)
Equals 1/1 (100%)

Score: 1/1
 

19.

  What is the overall reaction order for CO in a reaction with the following rate law?

Rate = k[Cl2][H+]2[CO]2

  Student Response Value Correct

Answer

1. First  

2. Fourth  

3. Second  

4. Fifth 0%  

5. Third  

Score: 0/1
 
 20.

Consider the equation, 4 NH3 + 5 O2 => 4 NO + 6 H2O. If the ammonia is being

used at a rate of 0.30 M/s, how quickly is the concentration of water increasing?

  Student Response Value Correct

Answer

A. 0.30 M/S  

B. -0.45 M/s  
 
C. 0.20 M/s  

D. -0.20 M/s  

E. 0.45 M/s 100%  

Score: 1/1