U n iv e r s ity o f th e P h ilipp in es

C h em ic al E n g in e er in g S o c iety, In c .

Chemistry 17 (Second Long Sample Exam—Answers)

I. Modified True or False: Ka=H3O[CN−][HCN]

1. HI < HBr < HCl 6.50 x 10−10=(x)(x)0.2−x;0.2−x≈0.2
2. Increase x = 1.140175425 x 10-15
3. Less [H3O+] = 1.140175425 x 10-15
4. True pH = -log[H3O+]
5. True pH = 4.943028324
6. Lesser
7. Remain constant HCN + → CN- + H2O
OH-
8. Less I 40mmol 0.35x mmol 0
9. True C -0.35x -0.35x +0.35x
10. More E 40-0.35x 0 0.35x
pH=pKa+log[CN−][HCN]
II. Multiple Choice: 4.943028324+3=-log(6.50x10-10)+
1. C log0.35x40−0.35x
2. B 0.35x40−0.35x = 0.057008771
3. D x= 
4. A 40(0.057008771)0.35+0.35(0.0570087
5. D 71)
x= 6.16389224 mL
III. Cause and Effect: x=6.16 mL
1. Decrease
2. No Effect 2. a.
3. Increase C3H5O(COOH)3 ⇌ H+ + C4H5O3(COOH)2-
4. Decrease I 0.90 0 0
5. No Effect C -x +x +x
E 0.90-x x x
IV. Problem Solving:
1. a. Ka1=C4H5O3(COOH−)[H+][C3H5O(COOH)3]
ΔG˚ = -RTlnK = ΔH˚ - TΔS˚ 7.4 x 10−3=(x)(x)0.90−x
x2 = -7.4 x 10-3x + 0.90(7.4 x 10-3)
lnK= ΔH˚ − TΔS˚−RT x2 + 7.4 x 10-3x + 6.6 x 10-3 = 0
lnKa=84  x  103Jmol−298K  (0.106  x  103  J/mol  x = 0.077992655, -0.085392655
K)−(8.314Jmol K)(298 K)
[H+] = 0.077992655
Ka = 6.50 x 10-10
pH = 1.11
b.
b.
HCN + H2O → CN- + H3O+ C3H5O(COOH)3 + OH- ⇌ C4H5O3(COOH)2- + H2O
I 0.2 0 0 I 45 mmol 30 mmol 0
C -x +x +x C -30 mmol -30 mmol + 30mmol
E 0.2-x x x E 15 mmol 0 30 mmol
 U n iv e r s ity o f th e P h ilipp in es
C h em ic al E n g in e er in g S o c iety, In c .

pH= 
pKa1+logC4H5O3(COOH−)[C3H5O(COOH)
3]
pH=  −log7.4  x  10−3 
+log30mmol/150mL15mmol/150mL
pH = 2.43

c.
C3H5O(COOH)3 + OH- ⇌ C4H5O3(COOH)2- + H2O
I 45 mmol 45 mmol 0
C -45 mmol -45 mmol + 45mmol
E 0 0 45 mmol
pH = 12(pKa1 + pKa2)
pH = 12(-log(7.4 x 10-3)+ -log(1.7 x 10-5))
pH = 3.45

d.
C3H5O(COOH)3 + OH- ⇌ C4H5O3(COOH)2- + H2O
I 45 mmol 90 mmol 0
C -45 mmol -45 mmol + 45mmol
E 0 45 mmol 45 mmol

C4H5O3(COOH)2- + OH-⇌ C5H5O5COOH2- + H2O

I 45 mmol 45 mmol 0
C -45 mmol -45 mmol + 45mmol
E 0 0 45 mmol
pH = 12(pKa2 + pKa3)
pH = 12(-log(1.7 x 10-5)+ -log(7.4 x 10-7))
pH = 5.45

3.
AgI(s) ⇌ Ag+(aq) + I-(aq) Ksp=1.5x10-16
Ag+(aq)+2S2O32-(aq)⇌[Ag(S2O3)2]3-(aq) Kf = 2.0 x 10-13
K = (Ksp)(Kf)
K = (1.5x10-16) x
AgI(s)+2S2O32-(aq)⇌[Ag(S2O3)2]3-(aq)+I-(aq)
( 2.0 x10-13)
K = 3.0 x 10-3
K=Ag(S2O3)23−[I−][S2O32−]2
3.0 x 10−3=(s)(s)(0.200−2s)2
3.0 x 10−3=s2(0.200−2s)2

s0.200−2s=0.05477225575
s = 9.87 X 10-3 M