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On Wednesday, May 18, 1949, the Minister of According to the Pauli exclusion principle which
P.T.T. presided over the presentation of the states that “In an atom there cannot be two
Transistron triode P.T.T. 601 and some instruments electrons defined by the same quantum
equipped with this device at the laboratories of coordinates” (1) it is not possible to have several
Service des Recherches et du Contrôle Techniques electrons with the same energy in an atom. We say
(S.R.C.T.) of P.T.T. that each electron has a defined “energy level” and
It was similar to a presentation held in America that energy level can vary by a quantum jump
at Bell Telephone Laboratories in 1948. under the influence of X-rays, for example.
Work on semiconductors conducted in France in We know that this quantum energy is equal to dw
recent years in collaboration between the
Administration des PTT and the Société des Freins dw = h v
et Signaux Westinghouse has produced similar
results to those of the Americans. Building on where h is Planck's universal constant equal
previous work, Doctors Welker and Matare and a
team of researchers prepared germanium of high
resistivity and started manufacturing high back
voltage detectors, a prelude to the development of
the of germanium triode or Transistron triode.
During the same year the first germanium
Transistrons manufactured in France left the
Laboratories. In French we could call this device
“transistance” which is the literal translation of the
American term “transistor.” However transistance
in French would be like resistance, an electrical
Fig. 1
quantity. Thus we have the name “Transistron”, or Unit cell of Ge. All other Projection on a horizontal
resistance of transfer, the suffix “tron” indicating atoms in the network are plane, the atoms num-
active elements involving electrons or ions. inferred from these by bered in the unit cell.
translations ha1 + ka2 + la3
1o Semiconductors
to 6.55 10-27 erg sec. and v is the frequency of the
electromagnetic wave radiated in the quantum
At room temperature, solids can be divided into jump of the electron.
three classes according to their electric Germanium is the 32nd element in the
conductivity. Mendeleev table normally with 32 electrons around
- Conductors its nucleus.
- Insulators The atoms form a solid body in a simple
- Semiconductors arrangement known as a three dimensional crystal
The phenomenon of conductivity is related to the lattice. Fig. 1 gives the example of the theoretical
electronic organization of atoms of the material crystal lattice for germanium.
being considered, the organization of its crystal In the crystal lattice of a particular solid there
lattice and its physical crystalline imperfections and may be free lattice electrons liberated from atoms
chemical properties. that are chemical impurities or from atoms of the
We know that the latest theories on the material itself occupying energy levels. In a
constitution of matter shows the atom consists of a structure without impurities or physical defects
central nucleus and electrons with fixed energy energy levels are grouped into bands and each band
levels. Of these electrons, we distinguish two
kinds: electrons bound to atoms and free electrons.
The energy of a bound electron is insufficient for
it to separate from its atom and its energy is (1) There are four quantum coordinates: n, l, m, s
quantized. n: characterizes the position of the electron, between 1 and 7
l: is related to the momentum
The energy of a free electron is sufficient for it to m: is the magnetic quantum number
be separated from its atom and its energy is not s: is the quantum number that characterizes the spin
quantized.
L'ONDE ÉLECTRIQUE
where R is called the “Hall coefficient” named after In addition the measurement of σ and R allows
the physicist Hall who demonstrated this effect in the calculation of b:
1879.
With the direction given to the current I and the
field H, the emf E can appear positively or
and consequently that of l.
negatively oriented.
Knowledge of these different quantities is
This sign has a direct impact on the coefficient of
essential to define the best properties of
R and depends on the material subjected to the
semiconductors, the existing methods of chemical
experiment. Electronic conductive bodies have a
and spectrographic analysis being insufficient to
negative Hall coefficient, (N type); those
make an adequate determination of impurities.
conductive by holes have a positive coefficient (P-
In addition, defects in the crystal structure have a
type).
huge influence on the behavior of semiconductors
In general, germanium at room temperature has
and these defects have an impact on their physical
electronic conductivity.
properties, particularly on mobility.
The value of R can be between 10-7 and about
For different kinds of French N type germanium
10-4 for germanium.
The origin of the Hall Effect can be explained by
the deviation of the trajectories of free electrons
liberated by the electric current by the magnetic
field.
The sign of the Hall coefficient enables the
determination of the type of conductivity of the
material and its magnitude:
- The number of conducting electrons per unit
volume.
- The mean free path of electrons.
- Their mobility.
The conductivity, σ, of a semiconductor with
conductivity due to electrons or holes is given by at room temperature, typical data is given in the
the expression: following table:
where:
where:
v = is a function of (h, k, T, n);
e = Electron charge;
ʋ = Contact potential difference;
xs =Work function of the semiconductor;
xm = Work function of metal;
k = Boltzmann constant;
T = Absolute temperature;
It still must undergo physical and chemical N1 = Number of donator energy levels per unit
treatment to give suitable P or N type volume, located a level below the band gap.
characteristics and resistivity appropriate to the
required end use. n1= number of electrons excited to the empty band
Figure 5 shows a germanium processing facility. per unit volume.
It is known that two different materials in contact n2 = number of free holes [in the full band] per unit
with one another create a potential difference in the volume.
vicinity of the point of contact called the "contact The difference in contact potential causes the
potential difference" related to the difference in the emergence of barrier potentials located in the
work function of electrons in each material. vicinity of the surfaces in contact. Between these
The work function is the work done to remove an barriers there is an area known as insulating barrier
electron from the body and make it free. The work layer with high dielectric constant.
function xn in a extrinsic semiconductor depends on Explanations on the formation and existence of
the level of impurities found there. The difference barrier potentials have been given by many authors
in work function between a metal and a (Schottky, Mott etc). They refer to the difference of
semiconductor is about 0.2 to 0.5 eV. work function that is to say the difference in energy
Formulas for the difference in work function levels that may exist between the two bodies
were given by Fowler for different cases. For an involved. Following the conventional
extrinsic semiconductor that is: representation, Figure 6 indicates the position of
the bands and energy levels that exist in the vicinity
of the surface of a metal and an N-type
TYPE N semiconductor before and after contact.
In the semiconductor energy levels of electrons
created by the impurities are located around the
Weak ionisation (n1 ≤ N1) normally empty upper band and they are higher
than the upper band, of the conductor.
When contact is made it is found that the
electrical current flows more easily in the direction
L'ONDE ÉLECTRIQUE
RE = input resistance,
Rr = feedback resistance between the output and
input
Rc= coupling resistance which loads the voltage
gain of the circuit
Rs = output resistance.
These two equations allow us to establish the
A very high voltage E (50 to 100 volts) is applied following equivalent circuit (Fig. 12).
through a resistance R (20,000 to 30,000 ohms) to Where:
the point “c” in the reverse direction so the
resistance of the semiconductor is very large. We
note that the current Is depends on IE and the
current Is must certainly flow in the layer between
the points "a" and "c". The valve is then
represented by the resistance of the layer, it is
controlled by the current IE and it is found that the
control power required is much less than that which
appears in the output resistance, Rs.
The magnitude of the input to output power ratio
given by where by applying the Thevenin Theorem we
readily obtain from the schematic in Figure 11:
R1 = R E - Rr
R2 = R r
R3= Rs - Rr
can now reach 100 to 200 and output power Ws is Es = (Rc- Rr) dIE
of the order of several tens of milliwatts. The family of curves in Figure 13 found for a
Explanations or physical phenomenon of type 601 Transistron shows, as might be expected,
variation of surface conductivity attributed to the P (see fig. 9) that Is increases with IE.
layer and the bulk N semiconductor as a function of
We can now establish a convenient method for For RG ≠ ZE the first term is negative and the
calculating the various characteristics of an second for RE ≠ Rs, they are equal to zero for:
amplifier in terms of the previously defined
variables. R G = ZE
Place the Transistron between an EMF generator
where e = E(sinωt) for example and input RE = R s
impedance RG and output impedance equal to RR.
Figure14 shows the equivalent circuit in this case For good power gain the source and output
excluding the bias circuits. impedance should be matched to ZE and Rs.
respectively and the gain will be:
RE ≈ 170 ohms
Rr ≈ 70 ohms
Rc ≈ 30,000 ohms
Rs ≈ 20,000 ohms
a) Input impedance ZE
ZE = RE (1- μβ)
b) Ouput impedance Zs
Zs = Rs + Rr (1- μoβ) ≈ Rs
We find for RR = Rs and RG = ZE
c) The voltage gain in Nepers
μo = 30,000/170 = 176
μ = 176/2 = 88
β = 3.5 10-3
μβ = 0.308
ZE = 170 (1 – 0.308) ≈ 188 ohms
Zs = 20,000 ohms
Gt ≈ 5.5 Nepers
If RR is very large GoM ≈ 5.15 – 2.38 – 0.1 ≈ 2.7 Nepers ≈ 24.5 dB
4° Making Transistrons.
The key to the production Transistrons lies in the -A 4 Transistron television video amplifier
preparation of germanium, in the selection of bars bandwidth. 40-10000 p/s, gain of 5.2 Neper and
where pellets should be cut, in the search for points 20 milliwatts of output power.
of contact and optimal adjustment of the spacing of
the point contacts. These last two operations are
carried out moreover under the microscope and are
made easier in the type 601 by the mechanical
arrangements that are used (Fig. 16).
Legend Fig 16 Ceramic body ... ... ..Soldered bronze caps with
the ceramic
5° Transistron Applications.
Of test equipment currently operating in the Due to the simplicity of the possible source of
laboratories of S.R.C.T. there is: polarization of its electrodes and low consumption,
Transistrons are conveniently powered remotely
-A broadcast receiver (Fig. 18); via the telephone line they are installed on. To the
extent that the life-time projections of this
-A transmitter for 300 metres longwave. equipment are borne out they will reduce the cost
L'ONDE ÉLECTRIQUE
(2) In figure 17 a Transistron is shown with a cap Forward and Reverse Bias
placed over the window used to adjust the point
contacts on the crystal. This version of the The treatment by Sueur is somewhat confusing in
Transistron is used in the broadcast receiver and the relation to point contacts on N or P germanium.
telephone circuit repeater (figs 18 and 19) and other The following provides a consistent explanation
equipment such as the long wave transmitter shown from Pfann 1950.
in Aberdam 1949:
Conductivity Polarity of Point
Type of the Forward Reverse
Semiconductor Direction Direction
N-Type + -
P-Type - +
References