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sIJtLTINGGIPERSEKoLAHANMALAYSIA

Instructions to candidates:

DoNoTOPENTHISQI,ESTIoNPAPERUNTILYOUAREToLDToDoSo.
afrrwersare given'
Thereme fifty questionsin thispaper. For eachquestion,four suggested
Chooseonecorrect i^rt, and indicate it on the multiple-choiceanswersheetprovided.

Readall instructionson the multiple-choiceanswersheetvery carefully,

Answer tll questions.Marfts will not be deductedforwrong an$4)ers'

This questionpaper consistsof 33 printed pages'

STPM9621r
is over.
*Thisquestionpaperis GONFIDENTIAL until theexamination CO}TFIDENTIAL*
CONFIDENTIAL- 2

SectionA

Four suggesfedansurerslabelledA, B, C and D arc givenfor each question.Chooseone

corrcctanswer.

1. Whichof the followingsketchesshowpartof the massspectrumof the refrigerant,

1'c, ttF,tuc,ttcll
flhe isotopesare :
CF2C!I?

A abundance
abundance

B D abundance
abundance

ry'e ratio
120 122 r24

2. Theunitcellof a metalM is shownbelow.Giventhe volumeof the unitcellis Vr cm3and

thevolumeof 1 molof M atomsis V2cm3.Whatis the valueof theAvogadroconstant?

A. Y zlV t B. ( VzlVr ) x4

c. Nz lYi x7 c. M/Vr ) x14

CONFIDENTIAL-
3. Sb, is in Group15 of the PeriodicTable.The ion belowhasa square-based
Antimony,
pyramidalshape.

I
,r,pry'
Deducethe totalnumberof electronsaroundthe antimonyatomandthe valueof n?
Total numberof electrons valueof n
A 10 1
B 10 2
c 12 1
D 12 2

4. GaseousparticleX hasa protonnumbern anda chargeof +1.GaseousparticleY hasa

withX. WhichstatementcorrectlydescribesX and
protonnumberof (n+1)and is isoelectronic
Y?
A X hasa largerradiusthanY
B X requiresmoreenergythanY whenthe secondelectronis removedf
fromeachparticle
C X releasesmoreenergythanY whenan electronis addedto eachparticle
D X andY belongto thesamegroupInthe PeriodicTable

^o H
or|
L \o
HLe -ao$Ln
I
valuesof the bondanglesin
Whichof the followingSrr""tly describesthe approximate
the moleculeabove?
6 v o
A 900 1900 900
B 1050 1800 900
c 1200 1050 10go
D 1200 10go 10go

{
CONFIDENTIAL*

6. In whichpairof molecules
is the permanent
dipolein molecule/ greaterthanthatin
molecule
ll?
It/,

Acrcl
\,/
C =C
t' ,rc\
C
/\
CHS CHS
f
cl CHs

B CH3CHzCI cH3cHcl2

CI
c
d"'
D
CI
I'
CI
6. CI Icl

7. The rateequationfor the decompositionof hydrogenbromide

2 H B (g ))H z(9 )+B r z( 9)
is: Rate= k[HBr]2

Whichof thefollowingconclusions
canbe drawnfromthis information?
A Thevalueof k dependson the concentration
of HBr.
B The rateof appearance
of Brzis halfthe rateof disappearance
of HBr.
C Doublingthe concentrationof HBrwilldoublethe rateof reaction.
D The presenceof a suitablecatalystwill increasethe valueof k.
CONFIDENTIAL*

\'lirrhmeg{*nrruen
fnnnod

8. In thediagramabove,curveXwas obtainedby observing

the decomposition
of 100cm3of
1.0moldm-3hydrogenperoxide,catalysed
by manganese (lV)oxide.
Whichalteration
to theoriginalexperimental wouldproducecurve)?
condition
A Addingwater
B peroxide
Addingsome0.1 moldm-3hydrogen
C Usinglessmanganese(lV)
oxide
D Loweringthe temperature

9. Thegraphbelowshowsthe variationof pHvaluewithvolumeof baseaddedin an acid-

basetitration.
l4
l3
t2
ll
l0
9
8
pH7
6
5
4
3
2
I
0
Volumeof baseadded/crn3

Whichof thefollowingstatements
is not true aboutthetitrationabove?
A Theacidandbaseusedin the titrationmayprobablybe ethanoicacid
andsodiumhydroxide respectively.
B ThepK"of the acidusedis equalto 4.7.
C Thesaltformedin the titrationundergoes to produceOH-
hydrolysis
ions.
D A suitableindicator
for the abovetitrationis methylorange.
CONFIDENTIAL" 10

10. The pH of a 1.0 mol dm-3solutionof a weak monobasicacid is 5. What is the

dissociationconstant of the weak acid?
A 1.0x 10a moldm'3
B 1.0x 10 8 mol dm-3
C 1.0x 10 to mot dm-3
D 1.0x 10la moldm-3

11. Hydrogensulphidereactswith water accordingto the followingequation.

H2s(aq) + 2Hzo(aq) +' 2Hao*(aq) + S'- (aq)

Whichof the followingaqueoussolutionswhenaddedwouldcausethe systemat

to shiftto the left?
equilibrium
A Ammoniumchloride
B Sodiumcarbonate
C Sodiumethanoate
D Ammonia

12. Whenthe systemChG) + PCls(g) +' at 600oC,at 1

PCl5(g)is in equilibrium
atmpressure,the valueof the equilibriumconstant,Kois 30.
\Nhatis the valueof t$ at a pressureof 2 atmat the sametemperature?
A 2 0 8 3 0 C .6 0 D 1 0 0

13. A solute,S exists in the same molecularstate when dissolvedin ether and water.
of soluteS in ethersolutionis 6
Whenthe two solutionsare in equilibrium,the concentration
timeshigherthanthat of the aqueoussolution. A solutioncontaining14.0g of S in 240cmsof
wateris extractedwith40 cm3of ether.Calculatethe totalmassof S extractedfromwater.
A 2 .0 9
B 6 .0 g
C 7 .0 9
D 8 .0 g
CONFIDENTIAL- t2

14. diagramsrepresentsa mixtureof

Whichof the followingboilingpoint- composition
waterand hydrogenchloride.
.A
Boilingpoint

0%Hp r00%Hp 0EoHrO

B D
Boilingpoint

{S. \Arhichof the followingstatementsis not truefor a standardcell whichconsistsof the

two half-cellsgivenbelow?
MnOr- + 8H* + 5e- ) Mnz*+ 4H2O Ee=+1.52V
Fe3*+d ) Fe2* Ee=+0.77V

A Thee.m.f. of the cellis 2.29V

B The MnOr /Mn2*cellundergoes oxidation.
c Electronsflowfromthe electrodein the MnOr'/Mn2*cellto the electrodein the
cell.
Fe3*/Fe2*
D of Fe3*(aq)
Concentration cellwillincrease.
ionsin the Fe3*/Fe'*
CONFIDENTIAL* l4

16. of cardiacpacemakers,
tnthe construction it is possibleto usea verysmallmagnesium
are
whichcreatesan electricalcellwiththe inhaledoxygen.The relevanthalf-cells
electrode
as follows.
Mg'** 2e ) Mg E0 = '2.38V
1/zO2+2H*+ 2e ) HzO E0 = +1.23Y

Understandardconditions, the celle.m.fwouldbe 3.61V, but in the bodya potentialof 3.25V

is moreusual.Whatis the bestexplanationof thislowere'm.f?

A Thesmallsizeof the magnesium electrode

B The low concentration the magnesiumelectrode
of Mg2*ionssurrounding
C Thehighresistance the electrodes.
of the bodyfluidssunounding
D ThepH between7 andI of the bodyfluidsunoundingthe electrodes.

aregivenby the followingequations.

17. Theenthalpychangefor two reactions

2Fe(s)+ 3l"Oz(gl) FezOa(s)

; aH = - 822 kJ mol-l
C(s)+ %C,z/6,l
) CO(g); AH= -110kJ mol-1

Whatis the enthalpychangefor thefollowingreaction?

3C(s)+ Fe2O3(s)) 2Fe(s)+ 3CO(g)

A +712kJmo1'1
B +492kJmo1-l
C - 492 kJ mot-1
D - 712kJ mol-1

iB. ionic
Whichvaluewouldbe requiredto estimatethe latticeenergyfor the hypothetical
MgH?
compound,
A The electronaffinitYof hYdrogen
B energyof hydrogen
Thefirstionisation
C Themagnesium-hydrogen bondenergy
D of MgHz
Thestandardenthalpychangeof formation
CONFIDENTIAL* t6

19. 4.0g of a hydrocarbon and9.0g of

required16.0g of oxygenfor completecomb*ustion
waterwas producedin the reaction.Whatwasthe massof carbondioxideproduced?
atomicmassof 0=16, C=12,H=11
[Refative
A 4 .0 9 B 9.0g
C 1 1 .0g D 22.0g

20. Thevaluesof pK6of severalsubstancearegivenbelow.

Substance PKu
NHg 4.75
CHsNHz 3.36
cH3cH2NH2 3.27
CsHsNHz 9.38

Whichof the followingis the strongestacid?

A NHO* B CHSNHS*
C CH3CH2NH3* D CeHsNHs"

21. Gonsiderthe sequenceof oxidesgivenbelow.Whichseriesshowsan increasingorder

of meltingpoint?
A AlzO.,SOs,SiOz
ClzOz,
B AlzOg,
SOs,ClzOz, SiOz
C SiO2,AlrO.
SOg,ClzOz,
D SiOz,AlzOg, SOs
ClzOz,

22. Theprocessof chemicaletching consistsof partiallydissolvinga metalin a suitable

solvent.By carefulmaskingof the metal,it is possibleto producea patternin or on the metal.
Whichof thefollowingaqueoussolutions couldbe usedto etcha patternin aluminium?
A Ethanoicacid
B Dilutenitricacid
C Sodiumhydroxide
D nitricacid
Concentrated
CONFIDENTIAL* l8

\Mrichof the followingstatementsregardinglead(lV)oxideis nottrue?

A lt is amphoteric
B lt easilydecomposeswhenheated
C lt hasionicbondingwithcovalentcharacteristics.
D lt is formedby heatingstronglylead(ll)oxidein oxygen

24. \ /hich reactionof ammoniadoes not involvethe non-bondingpair of electronson the

nitrogenatom?
A NHs(g)+ GHsl(g)+ CHsNHg.l-(s)
B NHs(g) + HCI(g) --+ NHrCI(s)
c 2NH3(l) + 2Na(s) + 2NaNH2(s)+ H2(g)
D 2NHg(aq)+ Ag.(aq) + [Ag(NHa)z].(aq)

25. P-ionis
P, Q, andR arethreeelementsin Group17.Q is a solidat roomtemperature.
the weakestreducingagentamongP-, Q- and R-
of the elementsin increasingintensityof colour?
Whatis the arrangement
A P ,R ,Q
B R ,Q,P
C P ,Q,R
D Q,R ,P

Whichof the followingcomplexesdoesnot exhibitopticalisomerism?

A [Cr(GzOr)z(HzO)zf
B [Cr(CzOr)slL
C lCo(en)zClz]
D [Co(NHs)s(NOz)sl

27. The intermediate speciesformedin the mechanismof the reactionbetweenmethane

andchlorinein the presenceof lightis
A CHs* B Cr C CHCI3 D .CH2C|
CONFIDENTIAL- 20

ZB. When60 cm3of a hydrocarbon wereburntcompletelyin oxygen,240 cm3of carbon

dioxideand0.0125molof waterwereproduced. Whatis the molecularformulaof-the
hydrocarbon?(Ihe volumesof all gasesweremeasured at roomconditions.The molar
is 24.0dm3)
volumeof anygasat roomconditions
A CzH. B CSH,
C CgHs D CoHro

29. Whichtypeof isomerismis shownby eachof the followingorganiccompounds?

A
B
c
D

30. hasthe highestpKuvalue?

Whichoneof thefollowingcompounds

A B @-*r,ruH,
@*t,
c cH3-N-cH3 D ozN-@-ruHz
I
CHs

3i. Lacticacidcan be formedfromethanolas shownin the rea-cti; schemebelow.

sbDI *cpII stcPltr I

cqcqoH: c4cHo5* Q-.*L - - c =o
f"

I andstep lll.
J*.
Namethe typesof reactionthat occurin step

Step I Steplll

A Oxidation Hydrolysis

B Reduction Esterification

c Condensation Oxidation

D Dehydration Condensation
CONFIDENTIAL* 22

32. is formedwhenethanoylchlorideis reactedwith

Whichof thefollowingcompound

HN<O-cHzoH
OH

A HN{O-cHzococH,
ao"

B HrNI{d-cHzoH
t1'
ococH3

c HN<O-cHzococHr
1o.o.",

D cHrcoHN{O>cH2ococFr2
-1
OCOCH.

33. is shownbelow.
Thestructureof cyclohexanone

an*
.-.

is true aboutcyclohexanone?
Whichstatement
A lt is an aromaticketone.
B formulais CeHrzO.
lts molecular
C lt canbe oxidisedto benzoicacid.
D lt will givea precipitate
with2,4-dinitrophenylhydrazine.

34. Naturalrubberis a polymermadeup of isopreneunitswiththe structuralformula

CH2= C(CH3)CH = CHz. Whichof thefollowingis not trueaboutthis statement?
A The IUPACnamefor isopreneis 2-methylbuta-1,3-diene
B Naturalrubberis madefromunsaturated molecules
C Naturalrubberbecomeshardwhenvulcanized
D andtranspolymers
Naturalrubberis a mixtureof cis polymers
CONFIDENNAT 24

35. X, Y andZ arethreedifferentcompounds. X reactswithsodiumto give off hydrogen

gas.X andY reactto forman ester.X andZ alsoreactto formthe sameesterbutat a much
slowerrate.Compound Y is probably
A propan-1-ol
B propana
C propanoic
acid
D propanoyl
chloride

36. \Mich of the followingslatements the compoundbelow?

is incorrectregarding
cH3(oH)cHcH2cocH3

A acidifiedpotassium
lt will decolourise manganate(Vll).
B lt canreactwithalkalineiodineto givea yellowprecipitate.
C active.
lt is opticallY
D lt will producea brick-redprecipitate
withFehling'ssolution.

andCH2BTCH2OH
97. WhenX (a gas)reactswith Y, a mixtureof CHzBTCH2BT are
produced.
X and Y are ProbablY

x
A Ethene Brominewater

B Ethene Sodiumbromidesolution

C HB(g) Ethene

D Br2vapour Ethene

38. A compoundQ hasthe followingcomposition by mass.Carbon,64.30/o; hydrogen,

Q reducesFehling's
oxygen,28.6To.
7.1o/ai solutionto copper(l)oxide.0.1 mol Q reactswith
4480cm3hydrogen gasat s.t.p.withnickelas catalyst.Q is
mass:H, 1; C, 12iO,16. 1 molgasoccupies22.4
atornic
[Relative dm3at s.t.p.l
A CH2= CHCHC C CH3CH = CHCH= CHCHO
B CH = CCHzOH D CH3COCH = CHCH= CHOH
CONFIDENTIAL*

39. An organiccompound,1,4/,is boiledwith aqueoussodiumhydroxideand the reaction

mixtureis allowedto cool..Upon cooling,compoundX and compoundY (an alcohol)are
produced. compound
On acidification, X is convertedto compoundZ (CaH6O2).
CompoundY
givesa positivetriiodomethane(iodoform)test. Compoundt4l is likelyto have the structural
formula
A CftCH2COOCH3 '
B CH3COOCHs
c cHscH2coocH2cH3
D CH3CH(OH)CH2COCI

40. Whichof the followingpairsof reactantsWillnot producethe compoundwiththe

formulashownbelow.
structurat

CHa
I
:-C-CHzCHs
I
OH

A cH3cH2MgBr and €)-cocn.

CHs
I and
CH3CH2-C=O @-nase'
c and cH3MgBr
@aocHzcHs

D 6\-cnrcHsMgBr and cH3cHo

CONFIDENNAL- 28

SectionB

For each questionin this section,one or moreof the threenumbercdstatemenfs1 to 3 may be

conect.The rcsponsesA to D shouldbe selectedas follows:

A B c D

{ only I and2 only 2 and3 only 1,2and3

is conect are correc't are correct are correct-

41 The energy-level diagramfor a hydrogenatomshowsseveralelectronictransitionswith

f1,f2,fs,fq andfs.
frequencies

n=qo
n--4
n=3

n=2

n=l

Whichof the followingstatementsis/aretrueof the abovediagram?

1. faandfsr€pl€sentlinesin the Balmerseries.
2. The linesrepresentedby f1,f2andfgare non-visible.
3. fsG?nbe usedto calculatethe ionisationenergyof hydrogen.

42. Whichof the followingmixtureswouldproducea solutionof pH greaterthan7.

1. 25 cm3of 1.0moldm-3NaOH(aq) and25 cm3of 1.0moldm4CH.COOH(aq).
2. and25 cm3of 1.0moldm€ NH.(aq).
25 cm3of 1.0motdm-3NHrCI(aq)
3. 25 cm3of 1.0moldm{ NaOHand25 cm3of 1.0moldm4CH.COONa.

43. Whichof the followingcan be determined ?

by usinga massspectrometer
1. massof an organiccompound
The relativemolecular
2. Theaccuratemassof a nuclide(isotope)
3. The protonnumberof an unidentified
element
CONFIDENTIAL" 30

A B c D

I only 1 and2 only 2and 3 only 1,2and3

is correct are correct are correct are correct

A cellis represented by the celldiagrambelow.

c(s) ll Cf.(aq) ll Fe3*1aq1,
Fe2*(aq) lp(t)
\Arhichof thefollowingwill increasethe e.m.fof the cell?
1 of Cf*
Increasethe concentration
2 Decreasethe concentrationof Fe2*
3 of Fe3*
tncreasethe concentration

45. idare
TheelementXhasa protonnumberof 25.Whichof the followingstatements
true of X?
1 ThemetalXhasa highdensitY
2 X formscolouredcomplexions
3 The highestoxidationnumberof X in its ionis +7

46. Whichof the followingelement(s)has/havethe abovearangementof atomsin its

1. diamond
2. silicon
3. boron

47. Whichof the foltowingreagentsreact(s)withbothbenzeneand methylbenzene?

1 Chlorinegasin the presence of anhydrousaluminiumchloride
2 Concentrated acidon reflux
sulphuric
3 Acidifiedpotassiummanganate(Vll)on reflux
CONFIDENTIAL- 32

A B c D

1 only 1 and2 only 2and 3 only 1,2and3

is conect are correct are correct are correct

48.
cn =cu-@-cHgBr

Whattype(s)of reactionwouldthe abovecompoundundergo?

1. Nucleophilicsubstitution
2. addition
Electrophilic
3. Freeradicalsubstitution

49. A compoundP decolourisebrominewateranddoesnotform a whiteprecipitatewith

P is
silvernitratesolution.Compound
ethanolic

1 ./
92_CH=CHz
cl

3. CHr=gggtr"'

Al
/\-r, cooH
"o-(u I
OH

S0. \Mich of the followingstatementsis/aretrue regardingthe compoundabove?

1. lt canformcondensation homopolymer.
2. lt canrotatethe planeof plane-polarised
light.
3. 1 molof the compound wouldreactwithsodiumto produce2 moles
of hydrogengas.