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Content

Welcome to Schott
pH measurement in the process application examples page 6

Electrodes for process chemistry pH combination electrodes page 8


metal combination electrodes
single electrodes pH glass, pNa, metal and reference elec., electrolyte bridges
resistance thermometers
grounding rod
conductivity cells

AquaLine electrodes in water economy page 34

SteamLine electrodes in biotechnology page 36

MultiSens electrodes page 40

Oxygen electrodes page 50

Accessories connection cables page 52


other accessories
buffer, electrolyte and further solutions

Index type no. / order no. page 60

3
SCHOTT Instruments welcomes you!

Precise measuring during the process Great variety of sensors Certified safety for 10 bar and 135 °C
with sensors from Schott. The electrochemical sensors from Schott cover The HD electrodes of Schott ensure an examined
Schott is the leading manufacturer of special glass all applications for measurements in aqueous solu- and certified pressure and temperature resistance
in Europe and is a leader worldwide. We offer tailor tions. They enable the determination of pH value, up to 10 bar and 135 °C. Thus they meet the
made customer solutions for sophisticated glass redox potential, silver and halogenide ion activity, requirements of the chemical industry. We supply
applications and systems in the household, health dissolved oxygen, conductivity and temperature. these electrodes in normal batches with Works
sector and industrial fields. Production and market- Operating ranges are from -30 °C up to +135 °C Certificate 2.1 or against additional charge with
ing companies in all major regions represent us in and pressures up to 10 bar. Acceptance Test Certificate 3.1 B.
the vicinity of our customers.
Sensors for various pH and AquaLine electrodes for the water industry
Electrodes from own research, development temperature ranges These electrodes are especially suitable for
and manufacture Different application conditions require correspon- measurements carried out in drinking water and
Schott has been active for more than 60 years in dingly adjusted pH sensor. H Glass is utilised for in the sewage sector. They quickly attain a stable
the field of pH measuring. Schott, however, supplies normal to high temperatures and the total pH ran- measuring value. Their smooth surface and sym-
not only electrodes. Our sensors are tailored ac- ge (very small alkali errors), S Glass for hot lye, metrical ring gap diaphragm are resistant to soiling
cording to the requirements of your applications and L Glass for low temperatures, and A Glass is formu- and ensure reliability coupled with a long life.
are characterized by maximum quality, reliability lated especially for the drinking water and sewage
and a long life. These demands are met via close range. MultiSens
cooperation with our customers (research, develop- MultiSens electrodes enable the obtainment of
ment and manufacture) leading to tailor made, Shaft glasses with high chemical resistance, optimi- more information from a standard measuring point.
technically detailed solutions. You will find a detailed zed to the application field of the sensor, are Measurement of pH, temperature, redox voltage
description of these precision sensors that have important for the reliability of the electrode. Being and conductivity can be made with a single electro-
been optimized according to process requirements a manufacturer of special glass types, Schott pro- de (in combination with a suitable measuring trans-
in this Catalogue. duces these as a matter of course. former), all of which can be done under process
conditions! Select the suitable MultiSens elctrode for
Quality the parameters required by you. A double pH elec-
The electrodes supplied by Schott are manufac- trode with temperature sensor can, for example,
tured with high precision according to the latest automatically check the reliability of the pH measur-
manufacturing methods. Each electrode must meet ing point. This will reduce maintenance expenditure
the strict requirements of the final examination. and increase the measuring reliability without the
need to dismantle the sensor each time and without
having to employ buffer solution.

Recommended by international process


analytic experts:
SMEK plug system

4
pH Glasses with unequivocal contact identification for sensors
Schott electrodes are manufactured with different that supply more than only the pH value. The
pH glasses. These are optimized for their various robust SMEK plug system meets the requirements
applications and offer a high measuring precision of the chemical industry and has been proven
and reliability. many times under practical conditions.

Reference system Mounting possibilities


The Ag/AgCl system is suitable for all pH applicati- The electrodes and sensors of Schott are offered in
ons up to temperature ranges of 135 °C. Silamid®, various designs that allow them to be mounted in
developed by Schott, is increasingly used as a practically all the usual fastenings and probes. The
novel reference system. Silamid®, in practical op- electrodes with screw plug head allow the plug
eration, produces fewer measuring errors through connection of cables of variable length and are
interference currents as well as more stable suitable for all fastening devices and probes with
measuring value display under critical conditions. mounting thread Pg 13.5. The electrodes with a
The reference electrolyte is a silver chloride-free throated shaft can be installed by means of O-ring
potassium chloride medium. Long diffusion stret- and Pg 13.5 bolting. The electrodes with flanged
ches in the electrodes make an additional heavy cap may be held by a union nut or mounted.
metal such as silver ion blocking superfluous. This Wolfgang Knappek

means improved measuring function with environ- What to do with electrode waste?
mental protection under practical conditions. Schott has accepted used sensors from their own
manufacture for many years and arranges proper
Diaphragm waste disposal or a reuse of materials.
Also of decisive importance for the quality of the SCHOTT Instruments GmbH
measuring result is, in the case of combination Information and application P.O. Box 2443
electrodes and reference electrodes, the diaphragm: Do you have any questions about the use of 55014 Mainz
the platinum diaphragm ensures in a wide range Schott electrodes? We will be glad to give you Hattenbergstraße 10
of applications an unsurpassable stable and rapid advice on your application. 55122 Mainz
measuring value adjustment. We offer, together Germany
with additional diaphragm types, an optimum
solution for practically every possible measuring Phone: + 49 61 31/66-51 11
medium. Fax: + 49 61 31/66-50 01
E-Mail: support@ schottinstruments.com
Connection to electrodes www.schottinstruments.com
The Plug Head System (also called S7 or S8 respec-
tively) developed in 1972 is now well proven in
industry and has long been approved unofficially
as European standard. Schott has, with the coop-
eration of major electrode and pH meter manufac-
turers, developed the new 6-pin SMEK plug system

5
Instructions on measuring pH
during a process

Process electrodes are, in general, used in fixed Selection criteria for electrodes pH Glasses
installed measuring points for continuous measur- The selection of a suitable pH electrode results Select the pH glass that offers the optimum
ing. The permanent availability of reliable and pre- from the character of the process conditions. results:
cisely measured values along with minimal main- Select a suitable electrode from the following
tenance expenditures are substantial requirements tables on the basis of the required pH and temper- H Glass: for high temperatures, in both the acid
regarding these measuring points. ature range as well as the pressure range. Know- and alkaline range, also for high sodium
ledge of the conductivity or the salt content of the ion concentrations
This results in the question of which pH electrode measuring medium is helpful for selection. S Glass: in hot alkaline media with good
is most suitable for the measuring point con- reproducibility and rapid reaction time
cerned? In answer, the electrodes can be subdi- Avoiding undesired influences on the L Glass: for low temperatures and general
vided into the following groups: measuring process applications
Sometimes it is not possible to completely prevent A Glass: with fast reaction time in drinking water,
Electrodes with liquid electrolyte the soiling of the sensor through the measuring industrial water, sewage; for general
These are suitable for a higher temperature appli- medium. It is possible that a coating is formed or applications and in media with low ion
cation range and have a longer life than mainte- the diaphragm is soiled. What is more, poisoning content
nance limited electrodes. It is also possible to of the reference electrode through agents from
expect a higher measuring accuracy, in particular the measuring medium (e.g. heavy metals, ammo- Diaphragm
in the case of electrodes with a platinum diaphragm nia, cyanide, sulphides) may occur. However, it is Also decisive for a safe and reproducible pH meas-
and pressure application of the coating electrolyte. possible to minimize these influences through uring activity is the correct selection of an elec-
The installation is more expensive than in the careful selection of the electrode, but they cannot trode type with a suitable diaphragm.
case of electrodes with gel or polymer electrolyte. completely be prevented. A regular manual or
automatic maintenance process ensures reliable Platinum diaphragm:
Electrodes with polymer electrolyte (Referid ®) measuring values in these cases. Universal, showing its strength particularly in the
These are low maintenance and are characterized case of solutions with solid matter content and
by high resistance to pressure and pressure When laying the cables for electrode connection, extreme pH values and temperatures. High flow
change. They are suitable for general applications splash water density is required for each connec- resistance.
and also for taking measurements in sophisticated tion. The connection at the measuring device Ceramic diaphragm:
chemical processes. must be carried out in compliance with the Robust for general applications, low electrolyte
instructions of the manufacturer of that device. outflow rate.
Electrodes with gel electrolyte Ground diaphragm:
Require little maintenance and are favorable in In most cases, the measuring solution has been Preferred for liquids with high solid matter
price. They are primarily used for standard appli- already earthed on the process side. Measuring content, easy to clean.
cations in aqueous media. points in solutions with little conductivity as well KPG®Ring Gap diaphragm:
as in glass or plastic fittings are earthed with Electrodes requiring little maintenance, symmetri-
Single electrodes an earthing electrode integrated in the sensor or cal ring gap, high resistance to soiling, extreme
Used as separate glass and reference electrodes, by means of a separately grounding rod. pH values/temperatures can shorten life.
particularly in difficult conditions. With the addi- Hole diaphragm:
tional use of an electrolyte bridge and pressure Electrodes requiring little maintenance, high resis-
application of the electrolyte it is possible to tance to soiling, extreme pH values/temperatures
achieve highly accurate measurements and long can shorten life.
electrode life even under extreme application
conditions. Mounting dimensions
The dimensions can generally be adapted to the
existing measuring point. You will find a great
number of electrodes in the usual dimensions to
choose from.

6
Application examples

The following electrode recommendations are Application Recommended electrode (Page of Catalogue in brackets)
only mentioned as examples. Depending on Sewage AquaLine electrode series (p. 34)
measuring point and measuring conditions, it is General, aqueous L 8281 HD (p. 13)
quite possible that other electrodes may also AL 70 pH (p. 34)
be suitable. We would be pleased to discuss these H 6181 HD (p. 8)
items with you. Extreme conditions S 1181 HD (p. 16) + B 1981 HD (p. 20)
S 6191 HD (p. 8)
Media containing hydrofluoric acid N 2981 (p. 16) + B 1881 (p. 20)
Sb 1101 (p. 18) + B 1881 (p. 20)
Boiler feeding water, condensate L 9080 (p. 10)
H 9090 (p. 10)
Paper industry H 8281 HD (p. 13)
Sterilizable electrodes SteamLine (p. 36) + S 22120 (p. 38)
Media that are partly aqueous H 9180 (p. 10)
H 6191 HD (p. 8)
Low temperatures (-30 °C) L 9080 (p. 10)
L 9180 (p. 10)
L 9090 (p. 10)
Drinking water, industrial water L 9080 (p. 10)
AquaLine electrode series (p. 34)
Water, general AquaLine electrode series (p. 34)
Sugar industry S 6181 (p. 8)
9517/85 (p. 16) + 9801/85 (p. 20)

We reserve the right to introduce technical alterations.


Silamid, Referid, DURAN, KPG are registered trade marks of the SCHOTT Group, Mainz, Germany

7
pH combination electrodes
with liquid electrolyte and screw plug head

D
H

H
81

81

91

91
81

81

91

81
62

63

62

63
61

64

61

61
H

H
H

S
membrane glass H H H H H H H S
membrane resistance (25°C) [MΩ] 300 300 300 300 300 300 300 400
temperature range [°C] 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 10 ...135
pH range [°C] 0 ...14 0 ...14 0 ...14 0 ...14 0 ...14 0 ...14 0 ...14 2...14
pressure range p/∆p [bar] 10/3 6/3 6/3 6/3 10/3 6/3 6/3 10/3
length L [mm] 170 120 320 170 170 120 320 170
diaphragm ceramic ● ● ● ●

platinum ● ● ●

ground joint ●

certified press. and temp. consistency 1) ● ● ●

design corresponding illustration A A A B A A A A

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A H 6191 HD
H 6181 HD
H 6281
H 6381
H 6291
H 6391
S 6181 HD
S 6281
S 6381
S 6191 HD
S 6291
S 6391
L 6191

B H 6481
S 6481

8
D
H
91

91

91

91
81

81

81

61

62

63

61
62

63

64

L
S

S
S S S S S S L pH combination electrodes with liquid
400 400 400 400 400 400 30 electrolyte and screw plug head
10 ...135 10 ...135 10 ...135 10 ...135 10 ...135 10 ...135 -30 ...+80 For high sophisticated pH measurements in
2...14 2...14 2...14 2...14 2...14 2...14 0...12 chemical processes.
6/3 6/3 6/3 10/3 6/3 6/3 6/3
120 320 170 170 120 320 170 Electrolyte:
● ● ◗ 3 mol/l KCl (Type L 300), refillable
● ● ● ● (triple) except L 6191: low temperature electrolyte
● type L 200
● Zero point:
A A B A A A A ◗ pH = 7.0
Shaft diameter:
◗ 12 mm
Connection:
◗ screw plug head coaxial
with thread Pg 13.5

The use of these electrodes is chiefly intended in


combination with the miniature pressure probe
assembly 9921/51 HD and suitable pressure hose
type 9961/09. This assembly reduces the stated
installation length by 50 mm. The side support
with screw fitting serves for application of counter
pressure.

Supply:
◗ HD version: HD sealing type 9980/51
◗ standard: washer 9980/52,
O-ring type 9932/07
Connecting cable:
◗ e.g. type 9902/05 (length 5 m with free end)
For additional connecting cables, see under
Accessories.
Note:
◗ at temperatures above 100 °C sufficient over-
pressure must counteract the boiling of the
reference electrolyte, e.g. 3.2 bar at 135 °C.

9
pH combination electrodes with liquid electrolyte and hose olive

90
80

80

80
80

90
80

90
90

91

90
91

90
90

H
H

S
L

L
L
membrane glass L L L H H H S
membrane resistance (25°C) [MΩ] 30 30 30 300 300 300 400
temperature range [°C] - 30 ...+ 80 - 30 ...+ 80 - 30 ...+ 80 0 ...135 0 ...135 0 ...135 10 ...135
pH range 0 ...12 0 ...12 0 ...12 0 ...14 0 ...14 0 ...14 2...14
pressure range p/∆p [bar] 6/3 6/3 6/3 6/3 6/3 6/3 6/3
length L [mm] 120 120 120 120 120 120 120
diaphragm ceramic ● (triple) ● ●

platinum ● ●

ground joint ● ●

design corresponding illustration A B A A B A A

A L 9080
L 9090
H 9080
H 9090
S 9080
S 9090

B H 9180
L 9180
S 9180

10
80

90
91

90
S

S S pH combination electrodes with liquid Supply:


400 400 electrolyte and hose olive ◗ pressure screw type 9980/55 with thread Pg 13.5
10 ...135 10 ...135 For high sophisticated pH measurements in ◗ washer 9980/52
2...14 2...14 chemical processes. ◗ O-ring type 9932/06
6/3 6/3 Connecting cable:
120 120 Electrolyte: ◗ e.g. type 9902/05 (length 5 m with free end)
◗ 3 mol/l KCl (type L 300), refillable – except For additional connecting cables, see under
● L 9080, L 9180, L 9090: low temperature Accessories.
● electrolyte type L 200 Note:
B A Zero point: ◗ at temperatures above 100 °C sufficient overpres-
◗ pH = 7.0 sure must counteract the boiling of the reference
Shaft diameter: electrolyte, e.g. 3.2 bar at 135 °C
◗ 12 mm
Connection: The use of these electrodes is effected usually with
◗ plug head coaxial electrolyte reservoir (e.g. type 9955/00).
Design: This vessel is connected by means of silicone tube
◗ refilling opening as hose olive (e.g. type 9980/00) with the electrode.
◗ shaft constriction

11
pH combination electrodes with liquid electrolyte

5
5

5
/8

/9

/9
/8

/8

/8
83

82

82
82

82

83
95

95

91
95

91

91
membrane glass H H H S S S
membrane resistance (25°C) [MΩ] 300 300 300 400 400 400
temperature range [°C] 0 ...135 0 ...135 0 ...135 10 ...135 10 ...135 10 ...135
pH range 0 ...14 0 ...14 0 ...14 2...14 2...14 2...14
pressure range p/∆p [bar] 6/3 6/3 6/3 6/3 6/3 6/3
length L [mm] 120 120 120 120 120 120
diaphragm ceramic ● ●

platinum ● ●

ground joint ● ●

design corresponding illustration A B A A B A

A 9582/85
9582/95
9182/85
9182/95

B 9583/85
9183/85

pH combination electrodes with liquid Shaft diameter:


electrolyte ◗ 12 mm
For high sophisticated pH measurements in Design:
chemical processes. Specially for installation in ◗ refilling opening, double, at the side
immersion probe assembly. ◗ shaft constriction and fixed cable 5 m
Note:
Electrolyte: ◗ at temperatures above 100 °C sufficient overpres-
◗ 3 mol/l KCl (type L 300), refillable sure must counteract the boiling of the reference
Zero point: electrolyte, e.g. 3.2 bar at 135 °C
◗ pH = 7.0

12
Low maintenance pH combination electrodes

D
D
D

H
H
H

81

81
81

81
81
81

81

84
82

83
82
77

H
H

H
L
L
membrane glass L L H H H H
membrane resistance (25°C) [MΩ] 30 50 400 400 400 400
temperature range [°C] - 5...+ 80 - 5...+ 80 0 ...100 0 ...100 0 ...100 0 ...100
pH range 2...12 2...12 2...13 2...13 2...13 2...13
pressure range p/∆p [bar] 0,5 10 10 10 10 10
length L [mm] 120 120 170 120 360 225
electrolyte gel Referid® Referid® Referid® Referid® Referid®
diaphragm ceramic ●

KPG® annular gap ● ● ● ● ●

certified pressure and temperature consistency 1)


● ● ● ●

design corresponding illustration A B B B B B

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A L 7781

B H 8281 HD
L 8281 HD
H 8181 HD
H 8381
H 8481 HD

Low-maintenance pH combination Shaft diameter:


electrodes ◗ 12 mm
For uncomplicated pH measurement in the water Connection:
industry and for process chemistry. ◗ screw plug head coaxial with thread Pg 13.5
Supply:
Electrolyte: ◗ HD version: HD sealing type 9980/51
◗ gel with visible KCl reserves, not refillable ◗ standard: washer 9980/52, O-ring type 9932/07
◗ Referid (polymer with visible KCl reserves),
®
Connecting cable:
not refillable ◗ e.g. type 9902/05 (length 5 m with free end)
Zero point: For additional connecting cables, see under
◗ pH = 7.0 Accessories.

13
Metal combination electrodes

D
H
81

81
80

80

81

81
80
61

82
90

90

68

69
90
gS

gS
g

Pt

Pt
Pt
A

A
A

A
sensor silver silver silver gold platinum platinum platinum
sensor sulphidized ● ●

sensor form pin ● ● ● ●

disk
ring ● ● ●

temperature range [°C] - 5 ... + 100 - 5 ... + 100 - 5 ... + 100 - 5 ... + 100 - 5 ... + 100 - 5 ... + 100 - 5 ... + 100
pressure range p/∆p [bar] 6/3 6/3 10 6/3 6/3 6/3 10/3
length L [mm] 120 170 120 120 120 120 170
electrolyte liquid, refillable ● ● ● ● ● ●

gel, low-maintenance
Referid®, low-maintenance ●

diaphragm ceramic ● ● ● ● ● ●

KPG® annular gap ●

certified pressure and temperature consistency 1)


design corresponding illustration A D B A A E E

Application recommendations
water management
process chemistry ● ● ● ● ●

photo ● ●

redox potential measurement ● ● ●

silver/halid ions concentration ● ● ●

determination of cyanide/rhodanide ●

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A Ag 9080
Au 9080
Pt 9080

B AgS 8281
Pt 8181
Pt 8281 HD

C Pt 7781

14
D
H
81

81

81
81

82

77
Pt

Pt

Pt
platinum platinum platinum Metal combination electrodes Supply (design A):
For redox measurements in water industry and ◗ pressure screw type 9980/55
● process chemistry. with thread Pg 13.5
● ● ◗ washer 9980/52
Electrolyte: ◗ O-ring type 9932/06
- 5 ... + 100 - 5 ... + 100 - 5 ... + 60 ◗ 3 mol/l KCI (type L 300), refillable Supply (design B-E, except HD):
10 10 0,5 except Ag S 6181: electrolyte type L 320 K ◗ washer 9980/52
170 120 120 ◗ gel with visible KCl reserves, not refillable ◗ O-ring type 9932/07
◗ Referid® (polymer with visible KCl reserves), Supply (HD version):
● not refillable ◗ HD sealing type 9980/51
● ● Shaft diameter: Connecting cable:
● ◗ 12 mm ◗ e.g. type 9902/05 (length 5 m with free end)
● ● Connection: For additional connecting cables, see under
● ◗ screw plug head with thread Pg 13.5 Accessories.
B B C Note (for electrodes with liquid electrolyte):
◗ at temperatures above 100 °C sufficient overpres-
sure must counteract the boiling of the reference
electrolyte, e.g. 3.2 bar at 135 °C
● ● ●

● ● ●

D AgS 6181

E Pt 6981 HD
Pt 6881

15
pH glass electrodes

D
D

D
D

H
H

H
H

71

81

81
91

81

81
81

11

11

27
11

14

11
11

H
H

S
L
membrane glass L H H H H H S
membrane resistance (25°C) [MΩ] 30 300 300 2000 600 500 400
zero point at pH 7.0 4.6 7.0 7.0 7.0 7.0 7.0
temperature range [°C] - 30 ... + 80 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 10 ...135
pH range [°C] 0 ... 12 0 ... 14 0 ... 14 0 ... 14 0 ... 14 0 ... 14 2 ... 14
sensor form sphere ● ● ● ● ●

dome ●

spear ●

shaft material glass ● ● ● ● ● ● ●

plastic
certified pressure and temperature consistency 1)
● ● ● ● ● ●

design corresponding illustration A A A A C B A

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.
2)
glass electrode with increased HF resistance
3)
pNa electrode for determination of sodium ion concentration, range of application pNa: 0 … 6, zero point pNa = 2.0

A S 1181 HD
L 1181 HD
H 1171
H 1181 HD
H 1191 HD
S 1191 HD
N 2981

B H 2781 HD
S 2781 HD

C H 1481 HD

D 9701/85
9501/75
9501/85
9101/85
9601/85

E 9517/85
9117/85

F 9504/85

16
D

2)
H

5
/8

/7

/8

/8

/8

/8

/8

/8
81
91

81

01

01

01

04

17

01

17

01
29
11

27

97

95

95

95

95

91

91

96
N
S

S S N L H H H H S S Na
2000 600 100 30 300 300 600 500 400 600 300
7.0 7.0 7.0 7.0 4.6 7.0 7.0 7.0 7.0 7.0 3)

10 ...135 10 ...135 0 ... 50 -30 ... + 80 0 ...135 0 ...135 10 ...135 10 ...135 10 ...135 10 ...135 0 ... 80
2 ... 14 2 ... 14 0 ... 14 0 ... 12 0 ... 14 0 ... 14 0 ... 14 0 ... 14 2 ... 14 2 ... 14 3)

● ● ● ● ● ● ●

● ● ●

● ● ● ● ● ● ● ● ● ●

● ●

A B A D D D F E D E D

pH combination electrodes without Supply (design A-C, except HD):


reference electrode ◗ washer 9980/52
Single electrodes are useful if the life of glass and ◗ O-ring type 9932/07
reference electrode is significantly different. For Supply (HD version):
measuring the pH value, a separate reference elec- ◗ HD sealing type 9980/51
trode is required. Supply (design D-F):
◗ O-ring type 9932/07
Length L: ◗ pressure screw type 9980/55-14 has to be
◗ 120 mm ordered separately
Shaft diameter: Connecting cable (design A-C):
◗ 12 mm ◗ e.g. type 9902/05 (length 5 m with free end)
Pressure range: For additional connecting cables, see under
◗ max. 10 bar Accessories.
Connection and Design A-C:
◗ screw plug head with thread Pg 13.5
Connection and Design D-F:
◗ 5 m fixed cable
◗ flange cap

17
Metal electrodes

D
H
01

5
01

01

01

01

01

/1
11
11

11

11

18

11

08
gS
g

90
Sb

Pt

W
A

A
A
sensor silver silver gold antimony platinum wolfram platinum
sensor sulphidized ●

sensor form pin ● ● ● ● ●

ring ● ●

sensor diameter [mm] 5 5 2 6 6 2 6


temperature range [°C] 0 ... 70 0 ... 70 0 ... 70 0 ... 70 - 30 ...+135 - 30 ...+135 0 ... 70
shaft material glass ● ● ●

PVDF ● ● ● ●

Polyamid-12
certified pressure and temperature consistency 1)

design corresponding illustration A A A A B A D

Application recommendations
redox potential ● ● ●

redox potential, rhodanide, cyanide ●

silver/halid ions concentration ● ●

pH measurement in HF bearing media ●

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A Ag 1101
AgS 1101
Au 1101
Sb 1101
W 1101

B Pt 1801 HD

C 9006/25
9006/35
9006/95

D 9008/15

18
5

5
/2

/3

/9
06

06

06
90

90

90
silver gold antimony Metal electrodes without Supply (design A – B, except HD):
reference electrode ◗ washer 9980/52
● ● ● Single electrodes are useful if the life of metal and ◗ O-ring type 9932/07
reference electrode is significantly different. For Supply (HD version):
5 2 6 measuring with single electrodes, a separate refer- ◗ HD sealing type 9980/51
0 ... 70 0 ... 70 0 ... 70 ence electrode is required. Supply (design C – D):
◗ O-ring type 9932/07
Length L: ◗ pressure screw type 9980/55-14 has to be
● ● ● ◗ 120 mm ordered separately
Shaft diameter: Connecting cable:
C C C ◗ 12 mm ◗ e.g. type 9902/05 (length 5 m with free end)
Pressure range: For additional connecting cables, see under
◗ max. 10 bar Accessories.
Connection and design A – B:
● ◗ screw plug head with thread Pg 13.5
● Connection and design C – D:
● ◗ 5 m fixed cable
◗ flange cap

19
Reference electrodes

D
D

D
H

H
H

H
5
/8
81

81

91

91
81

91
01
18

11

14

15
19

13
98
B

B
B

B
temperature range [°C] 0 ... 100 0 ... 100 0 ... 50 0 ... 50 - 5 ... + 135 - 5 ... + 135 - 5 ... + 135
pressure range p/∆p [bar] 10 10 10 0.5 10/3 10/3 6/3
length L [mm] 120 120 120 120 170 170 170
electrolyte liquid (type L 300) ● ● ●

gel (KCI saturated) ● ● ●

Referid® (visible KCl reserves) ●

liquid (type L 200)


internal resistance (25 °C) [KΩ] 2 2 2 2 3 3 2
shaft material glass ● ● ● ● ● ●

PVDF ●

diaphragm ceramic ● ● ●

KPG® annular gap ●

platinum ●

PVDF ●

ground joint ●

frit
certified pressure and temperature consistency 1) ● ● ● ● ●

design corresponding illustration A B B C G G F

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A B 1981 HD

B B 1181 HD
B 1881 HD

C 9801/85

D 9828/95

E 9834/95

20
5

5
/9

/9
28

34
98

98

- 5 ... + 135 - 30 ... + 50 Reference electrodes Supply (HD version):


6/3 6/3 Single electrodes are useful if the life of measuring ◗ HD sealing type 9980/51
120 120 and reference electrode is significantly different. Supply (design C):
● ◗ O-ring type 9932/07
Shaft diameter: ◗ pressure screw type 9980/55-14 has to be
◗ 12 mm ordered separately
● Connection and design A, B, F, G: Supply (design D + E):
3 1 ◗ screw plug head coaxial with Pg 13.5 ◗ pressure screw type 9980/55 with thread Pg 13.5
● ● Connection and design C: ◗ washer 9980/52
◗ 5 m fixed cable ◗ O-ring type 9932/06
● ◗ flange cap Connecting cable (design A, B, F, G):
Connection and design D + E: ◗ e.g. type 9905/05 (length 5 m with free end)
◗ 5 m fixed cable For additional connecting cables, see under
◗ refilling opening as hose olive Accessories.
◗ shaft constriction Note (for electrodes with liquid electrolyte):
● Supply (design A, B, F, G, except HD): ◗ at temperatures above 100 °C sufficient overpres-
◗ washer 9980/52 sure must counteract the boiling of the reference
D E ◗ O-ring type 9932/07 electrolyte, e.g. 3.2 bar at 135 °C

F B 1591

G B 1491 HD
B 1391 HD

21
Detachable reference electrode, according to DIN 19 264

5
/9
71
98
temperature range [°C] - 5 ... + 135
pressure range p/∆p [bar] 3/3
length L [mm] 95
internal resistance (25°C) [KΩ] 2
diaphragm ceramic ●

material of head PPS


design and connection 5 m fixed cable

9871/95

Detachable reference electrode, according


to DIN 19 264
Preferably for measuring pH in industrial plants.
Advantage: Reference electrode and electrolyte
vessel can be replaced. The detachable reference
electrode must be accompanied by a suitable elec-
trolyte vessel (see page 24).

Electrolyte:
◗ KCl saturated, refillable
Supply:
◗ O-ring type 9932/05

22
Which reference electrode to which measuring electrode

Reference electrodes are used outside the tempera- 9834/9 respectively must be used. For applications higher temperature employment range and
ture application ranges stated in this catalogue above 100 °C, a sufficient overpressure must coun- a longer life than low-maintenance electrodes.
with the help of an electrolyte bridge. For applica- teract the boiling of the reference electrolyte, eg In the case of liquid electrolyte electrodes,
tions below 0 °C, the low temperature electrolyte 3.2 bar at 135 °C. Electrodes with liquid electrolyte a higher measuring accuracy can be expected.
L 200 or the low temperature reference electrode render, in a corresponding pressure application, a

reference electrodes with fixed cable reference electrodes with plug head, inst. thread
9801/8. 9828/9. 9834/9. 9871/9. B1181HD B1391HD1) B1491HD1) B15911) B1881HD B1981HD
pH glass electrodes 9101/8. « ∑ « ® « ∑ ∑ « « «

with fixed cable 9117/8. « ® « ∑ « ∑ ∑ « « «

9501/7. « ® « ∑ « ∑ ∑ ∑ ∑ «

9501/8. « ∑ « ® « ∑ ∑ ∑ ∑ «

9504/8. « ® « ∑ « ∑ ∑ « « ∑

9517/8. « ® « ∑ « ∑ ∑ ∑ ∑ «

9701/8. « ∑ ® ∑ « ∑ ∑ ∑ « «

metal electrodes 9006/2. « ® « ∑ « « ∑ ∑ « ∑

with fixed cable 9006/3. ∑ ® « ∑ ∑ « ∑ ∑ ∑ ∑

9006/9.2) « « « « « « « « ® «

9008/1. ∑ ® « ∑ ∑ « ∑ ∑ ∑ ∑

pNa glass electrode 9601/8. ® ∑ « « ∑ ∑ ∑ ∑ ∑ «

with fixed cable


pH glass electrodes with plug L 1181 HD « ∑ ® ∑ ∑ ∑ ∑ ∑ « «

head and installation thread H 1171 ∑ ∑ « ∑ « ∑ ® ∑ ∑ «

H 1181 HD « ∑ « ∑ « ∑ ® ∑ ∑ «

H 1191 HD « ∑ « ∑ « ∑ ® ∑ ∑ «

H 1481 HD « ∑ « ∑ « ∑ ∑ « « ®

H 2781 HD « ∑ « ∑ « ∑ ∑ ® ∑ «

N 2981 2)
« « « « « « « « ® «

S 1181 HD « ∑ « ∑ « ® ∑ « « «

S 1191 HD « ∑ « ∑ « ® ∑ « « «

S 2781 HD « ∑ « ∑ « ® ∑ « « «

metal electrodes with plug head Ag 1101 « ∑ « ∑ « « ® ∑ « ∑

and installation thread AgS 1101 « ∑ « ∑ « « ® ∑ ∑ ∑

Au 1101 « ∑ « ∑ ∑ « ® ∑ ∑ ∑

Pt 1801HD « ∑ « ∑ ∑ « ® ∑ ∑ ∑

Sb 11012) « « « « « « « « ® «

W 1101 « ∑ « ∑ ∑ « ® ∑ ∑ «

1)
To be used only with miniature pressure adapter type 9921/51 HD
2)
Use of other reference electrodes to be recommended only with the use of electrolyte key 9844/21 or B 4491

® = recommended; application outside the stated temperature application ranges with electrolyte bridge
∑ = suitable; application outside the stated temperature application ranges with electrolyte bridge
« = conditionally suitable; suitable depending on the application and installation of the measuring point;
under certain circumstances the use of an electrolyte bridge is advisable.

23
Electrolyte vessels for detachable reference electrodes, according
to DIN 19 264

3
1

1
/0

/0

/0

/0
/0

/0

/0
63

63

64

64
63

63

64
98

98

98

98
98

98

98
temperature range [°C] 0 ...135 - 10 ... +135 0 ...135 - 30 ... + 135 0 ...135 0 ...135 0 ...135
pressure range p/∆p [bar] 3/3 3/3 3/3 3/3 3/3 3/3 3/3
internal resistance (25°C) [KΩ] 1.5 0.5 0.1 0.1 1.5 0.5 0.5
diaphragm ceramic ● ●

triple ceramic ● ●

ground joint ●

frit ●

platinum ● (side)
permeability [ml/h] 1) 0.05 0.15 2 2 0.05 0.1 0.15
reservoir (vessel) height [mm] 35 35 35 35 85 85 85
design corresponding illustration A A A A B B B

1)
Average values at overpressure of 0.1 bar.

A 9863/01
9863/03
9863/04
9863/05

B 9864/05
9864/01
9864/02
9864/03
9864/04
9864/07

24
4

7
/0

/0

/0
64

64

64
98

98

98
0 ...135 - 30 ... + 135 0 ...135 Electrolyte vessels for detachable reference
3/3 3/3 3/3 electrodes, according to DIN 19 264
0.1 0.1 0.5
Length L:
◗ 120 mm
● Shaft diameter:
● ◗ 12 mm
● Design:
2 2 0.1 ◗ shaft constriction
85 85 85 Shaft material:
B B B ◗ glass
Supply:
◗ pressure screw type 9980/55 with thread Pg 13.5
◗ washer 9980/52
◗ O-ring type 9932/06

25
Electrolyte bridges for reference electrodes

4
3
/1

/0

/1

/0
/0
11

41
44

44

44

44
44
44

44
98

98

98

98
98
B

B
temperature range [°C] 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135
pressure range p/∆p [bar] 6/3 6/3 6/3 6/3 6/3 6/3 6/3
internal resistance (25°C) [KΩ] 1.5 1.5 1.5 0.5 0.1 0.1 0.1
shaft material glass ● ● ● ● ● ● ●

PTFE
PVDF
diaphragm frit
platinum
ground joint ● ● ●

ceramic ● ● ● ● (triple)
PTFE
permeability [ml/h] 1) 0.05 0.05 0.05 0.15 2 2 2
design corresponding illustration A C F F A C F

1)
Average values at overpressure of 0.1 bar.

A B 4441
B 4411
B 4451
B 4471

B B 4491

C 9844/11
9844/14
9844/15

D 9844/21

E 9844/26
(Ill. with
pressure screw)

F 9844/01
9844/03
9844/04
9844/05
9844/02
9844/07

26
2

6
5

/0

/0

/2

/2
/1

/0
51

71

91
44

44

44

44
44

44

44
44

44

98

98

98

98
98

98

B
B

B
- 30 ... + 135 0 ...135 - 30 ... + 135 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135 0 ...135
6/3 6/3 6/3 6/3 6/3 6/3 2/2 2/2 6/3
0.1 0.1 0.1 0.5 0.5 0.5 1.5 1.5 1.0
● ● ● ● ● ●

● ●

● ● ●

● ● (side) ●

● ●

2 2 2 0.1 0.1 0.1 4 4 0.1


A C F A F F B D E

Electrolyte bridges for reference electrodes Supply (design A + B):


Accessory for sophisticated pH measurement in ◗ washer 9980/52
chemical processes. An electrolyte bridge is advis- ◗ O-ring type 9932/07
able if the measuring solution contains strong Supply (design C – E):
electrode poisons or if the electrolyte of the refer- ◗ pressure screw type 9980/55-14 with
ence electrode reacts with the measuring solution. thread Pg 13.5
◗ O-ring type 9932/07
Hose olive: Supply (design F):
◗ d = 10 mm (except type 9844/26: d = 4 mm) ◗ pressure screw type 9980/55 with
Length L: thread Pg 13.5
◗ 120 mm ◗ washer 9980/52
Shaft diameter: ◗ O-ring type 9932/06
◗ 12 mm Accessories:
Design A + B: ◗ hose type 9980/00
◗ thread Pg 13.5 (except for 9844/26: hose type 9961/09)
Design C - E: ◗ spare diaphragm for 9844/21 and B 4491:
◗ flange cap type 9980/65
Design F:
◗ shaft constriction

27
Resistance thermometers with plug head

D
D

H
H
41

61

61

81
21

81

21
20

20

20

20
20

20

20
W

W
W

W
sensor Pt 100 ● ● ● ● ● ● ●

sensor Pt 1000
secondary platinum electrode ● ●

pressure range [bar] 10 10 10 10 10 10 10


shaft material stainless steel 1.4571 ● ●

glass ● ● ●

DURAN® ● ●

PVDF
connection 2-pole 2-pole 4-pole 2-pole SMEK SMEK SMEK
certified pressure and temperature consistency 1)
● ● ●

design corresponding illustration A B C D A C D

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A W 2021 HD
W 2021
W 4011
W 2121
W 4111

B W 2041

C W 2061 HD
W 2061
W2161

D W 2081
W 2081 HD
W 4081
W 2181

28
81

11

21

61

81

11
40

40

21

21

21

41
W

W
W

W
● (double) ● Resistance thermometers with plug head
● ● ● ● Suitable for separate temperature measurement
● and temperature compensation in the process.
10 10 10 10 10 10
● Length L:
● ◗ 120 mm
● ● Shaft diameter:
● ● ◗ 12 mm
4-pole 2-pole 2-pole 4-pole 2-pole 2-pole Temperature range:
◗ - 30 ... + 135 °C
D A A C D A Connection:
◗ screw plug head with Pg 13.5

You will find combined sensors with integrated


temperature probe in the respective chapters.

Supply (except HD):


◗ washer 9980/52
◗ O-ring type 9932/07
Supply (HD version):
◗ HD sealing type 9980/51
Connecting cable (design A, B, F, G):
◗ 2-pole: e.g. type 9907/05
(length 5 m with free end)
◗ 4-pole: e.g. type 9909/15
(length 5 m with free end)
◗ SMEK: e.g. type SMEK 20/05
(length 5 m with free end)
For additional connecting cables, see under
Accessories.

29
Resistance thermometers with fixed cable

5
5
5

/2
/8
/2

11
10
10

90

90
90
sensor Pt 100 ● ●

sensor Pt 1000 ●

pressure range [bar] 10 10 10


shaft material stainless steel 1.4571 ● ●

DURAN® ●

design corresponding illustration A B A

A 9010/25
9011/25

B 9010/85

Resistance thermometers with fixed cable


Suitable for separate temperature measurement and
temperature compensation in the process.

Length L:
◗ 120 mm
Shaft diameter:
◗ 12 mm
Temperature range:
◗ - 30 ... + 135 °C
Connection:
◗ 5 m fixed cable, flange cap
Supply:
◗ O-ring type 9932/07
◗ pressure screw type 9980/55-14 has to be
ordered separately

30
Grounding rod

51
16
E
temperature range [°C] 0 ...135
pressure range [bar] 10
shaft material stainless steel 1.4571 ●

E 1651

Grounding rod
The grounding rod serves for potential compensa-
tion for measuring in ungrounded liquids.

Length L:
◗ 120 mm
Shaft diameter:
◗ 12 mm
Connection:
◗ screw plug head with thread Pg 13.5
Supply:
◗ washer 9980/52
◗ O-ring type 9932/07
Connecting cable:
◗ e.g. type 9905/05 (length 5 m with free end)
For additional connecting cables, see under
Accessories.

31
Conductivity cells

D
H
T

T
01

01

01
01
51

01
11

12

51
11

11
10

LF

LF

LF
LF

LF

LF
temperature sensor integrated Pt 1000 Pt 1000
temperature range [°C] - 30 ... + 100 - 30 ... + 100 - 30 ... + 100 - 30 ... + 100 - 30 ... + 135 0 ... 80
cell constant (± 10 %) [cm -1] 0.5 1.0 2.0 1.0 1.0 1.0
recommended measuring range (25°C) up to [mS/cm] 2) 100 200 400 200 200 200
pressure range [bar] 10 10 10 10 10 10
platinum electrodes, design 2-flat 2-flat 2-flat 2-flat 2-flat 2-ring
shaft material glass ● ● ● ● ●

POM ●

connection 2-pole 2-pole 2-pole 4-pole SMEK 2-pole


certified pressure and temperature consistency 1)

design corresponding illustration A A A A B C

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.
2)
Out of the recommended conductivity range the error of measurement can be >10%, also depending on conductivity meter.

A LF 1201
LF 1051
LF 1101
LF 1101T

B LF 1101T HD

C LF 5101T
LF 5101

D LF 71T

32
T
01

T
51

71
LF

LF

Pt 1000 Pt 1000 Conductivity cells Supply (except HD):


0 ... 80 - 30 ... + 100 Robust conductivity cells for on-line measuring. ◗ washer 9980/52
1.0 1.0 Cells with glass shaft for high chemical resistance. ◗ O-ring type 9932/07
200 2.000 Robust cells with plastic shaft. Supply (HD version):
10 10 ◗ HD sealing type 9980/51
2-ring 4-ring Length L: Connecting cable:
● ◗ 120 mm ◗ 2-pole: e.g. type 9907/05
● Shaft diameter: (length 5 m with free end)
4-pole SMEK ◗ 12 mm ◗ 4-pole: e.g. type 9909/15
Connection: (length 5 m with free end)
C D ◗ screw plug head with thread Pg 13.5 ◗ SMEK: e.g. type SMEK 18/05
(length 5 m with free end)
For additional connecting cables, see under
Accessories.

For additional conductivity measuring cells, see


chapter MultiSens electrodes.

33
AquaLine combination electrodes

T
T

T
pH

pH
pH

pH

pH
Pt

Pt
79

80

83

89
70

81

82
L

L
L

L
A

A
A

A
pH sensor 1) ● ● ● ● ●

redox sensor 2)
● ●

conductivity sensor 3)

temperature sensor integrated Pt 1000 Pt 100 NTC 30KΩ


temperature range [°C] - 5 ... + 80 - 5 ... + 80 0 ... 80 0 ... 80 0 ... 80 0 ... 80 0 ... 80
pH range 2 ...13 2 ...13 2 ...13 2 ...13 2 ...13 2 ...13 2 ...13
pressure range [bar] 3 3 10 10 10 10 10
diaphragm ceramic ● ●

KPG® annular gap ● ● ● ● ●

fibre
shaft material glass ● ● ● ● ● ● ●

plastic
electrolyte gel, low-maintenance ● ●

Referid®, low-maintenance ● ● ● ● ●

connection coaxial coaxial coaxial SMEK SMEK SMEK coaxial


design corresponding illustration A B C D D D E

1)
pH sensors with A Glass
2)
Redox sensors with platinum disk d = 4 mm
3)
Cell constant c=1.0 [cm-1] (±10 %)

A AL 70 pH

B AL 79 Pt

C AL 80 pH

D AL 82 pHT
AL 81 pHT
AL 83 pHT

E AL 89 Pt

34
T

T
pH

pH

LF
90

93

63
L

L
A

A
● ● AquaLine combination electrodes Connection:
Especially for measuring in drinking water, industri- ◗ screw plug head with thread Pg 13.5
● al water and sewage range. Low-maintenance elec- Supply:
NTC 30KΩ NTC 30KΩ trodes. ◗ washer 9980/52
0 ... 80 0 ... 80 - 5 ... + 80 ◗ O-ring type 9932/07
2 ...13 2 ...13 – Electrolyte: Connecting cable:
– – – ◗ gel with visible KCl reserves, not refillable ◗ coaxial: e.g. type 9902/05
◗ Referid® (polymer with visible KCl reserves), (length 5 m with free end)
not refillable ◗ SMEK (design D+G): e.g. type SMEK 19/05
● ● Length L: (length 5 m with free end)
◗ 120 mm ◗ SMEK (design H): e.g. type SMEK 18/05
● ● ● Shaft diameter: (length 5 m with free end)
● ● ◗ 12 mm For additional connecting cables, see under
Zero point: Accessories.
coaxial SMEK SMEK ◗ pH = 7.0
F G H

F AL 90 pH

G AL 93 pHT

H AL 63 LFT

35
SteamLine
Sterilizable electrodes for biotechnological applications

Specification pH combination electrodes redox combination electrodes


sensor membrane glass type S platinum
sensor form sphere disk
membrane resistance (25°C) [MΩ] 500
zero point at pH 6.8
temperature range [°C] 0…140 0…140
pH range 0 ...14 0 ...14
pressure range vacuum to 10 bar vacuum to 10 bar
diaphragm ceramic ceramic
design corresponding illustration A to B C

Design length L / type no. length L / type no.


combination electrode 120 mm / SL 80-120pH 120 mm / SL 89-120Pt
connection: plug head, coaxial 225 mm / SL 80-225pH 225 mm / SL 89-225Pt
325 mm / SL 80-325pH 325 mm / SL 89-325Pt
360 mm / SL 80-360pH
425 mm / SL 80-425pH 425 mm / SL 89-425Pt
design corresponding illustration A C

with integrated temperature sensor Pt 100 120 mm / SL 82-120pHT


connection: plug head, SMEK* 225 mm / SL 82-225pHT
325 mm / SL 82-325pHT
360 mm / SL 82-360pHT
425 mm / SL 82-425pHT
design corresponding illustration B

with integrated temperature sensor Pt 1000 120 mm / SL 81-120pHT


connection: plug head, SMEK* 225 mm / SL 81-225pHT
325 mm / SL 81-325pHT
425 mm / SL 81-425pHT
design corresponding illustration B

* SteamLine SL81 and SL82 are also available with VP plug.

36
Sterilizable low maintenance electrodes Electrolyte: For sterilizable electrodes with integrated tempera-
for biotechnology, foodstuff and process ◗ pressurized gel, with KCl reserves ture, redox and conductivity sensors, see chapter
chemistry Shaft diameter: MultiSens electrodes.
SteamLine electrodes are steam-sterilizable sensors ◗ 12 mm
with a high degree of reliability and precision. Connection:
Very fast and stable response thanks to pH glass ◗ screw plug head with Pg 13.5
type S and new design. The pressurized reference Connecting cable:
electrode is stable over a long period of time. ◗ coaxial (design A+C):
Safe sterilization with temperature monitoring is e.g. type 9902/05 (length 5 m, with free end)
possible. CIP- and SIP-capable, can be used under ◗ SMEK (design B):
most difficult conditions. Come with quality cer- e.g. type SMEK 19/05 (length 5 m, with free end)
tificate, individual serial no. and seal of originality. For additional cables, see under Accessories.

A SL 80-120pH
SL 80-225pH
SL 80-325pH
SL 80-360pH
SL 80-425pH

B SL 81-120pHT
SL 81-225pHT
SL 81-325pHT
SL 81-425pHT
SL 82-120pHT
SL 82-225pHT
SL 82-325pHT
SL 82-360pHT
SL 82-425pHT

C SL 89-120Pt
SL 89-225Pt
SL 89-325Pt
SL 89-425Pt

37
Sterilizable electrodes for biotechnological applications

Specification pH combination electrodes redox combination electrodes


sensor membrane glass type S platinum
sensor form cylinder ring, d = 6 mm
membrane resistance (25°C) [MΩ] 600
temperature range [°C] 10 ...135 0 ...135
pH range 2 ...14
pressure range p/∆p [bar] 6/3 6/3
diaphragm ceramic ceramic
design corresponding illustration A to C D to F

Design length L / type no. length L / type no.


electrolyte reservoir vessel: length = 70 mm 120 mm / S 22120 120 mm / Pt 22120
150 mm / S 22150 150 mm / Pt 22150
200 mm / S 22200 200 mm / Pt 22200
design corresponding illustration A D

electrolyte reservoir vessel, large: 120 mm / S 26120 120 mm / Pt 26120


length = 130 mm 150 mm / S 26150 150 mm / Pt 26150
200 mm / S 26200 200 mm / Pt 26200
design corresponding illustration B E

electrolyte reservoir vessel: length = 70 mm 120 mm / S 22125


with double electrolyte system 150 mm / S 22155
200 mm / S 22205
design corresponding illustration A

electrolyte reservoir vessel, large: 120 mm / S 26125


length = 130 mm with double electrolyte system 150 mm / S 26155
200 mm / S 26205
design corresponding illustration B

double electrolyte system 120 mm / S 23128 120 mm / Pt 23128


for unpressurized mounting 150 mm / S 23158 150 mm / Pt 23158
200 mm / S 23208 200 mm / Pt 23208
design corresponding illustration C F

Other lenghts on request.

38
Sterilizable electrodes for biotechnological Electrolyte: Connecting cable:
applications ◗ 2 mol KCl/l, refillable, with increased viscosity ◗ e.g. type 9902/05 (length 5 m with free end)
Particularly suitable for application in the fields of (type no. L 310) For additional connecting cables, see under
biotechnology and pharmaceuticals. Can be Zero point: Accessories.
sterilized at 135 °C, and may be autoclaved. ◗ pH = 7.0
Optional double electrolyte system for particularly Connection: For sterilizable electrodes with integrated tempera-
sophisticated applications. Redox combination ◗ plug head, coaxial ture, redox and conductivity sensors, see chapter
electrodes with large platinum ring for reliable and MultiSens electrodes.
stable measuring values.

A S 22120

B S 26120

C S 23128

D PT 22120

E PT 26120

F PT 23128

39
MultiSens electrodes pH, °C

D
D
D

H
H
H

25

25
20
20

70

20
70

-2

-2
-1
-1

-1

-1
-1

50

50

80

30
60

80
10

T
T

T
PE

PE

PE

PE
PE

PE

PE
temperature sensor Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000
membrane glass A A A A A A S
membrane resistance (25°C) [MΩ] 500 500 500 500 500 500 900
temperature range [°C] 0 ...135 0 ... 100 0 ... 100 0 ...135 0 ... 100 0 ... 100 0 ...135
pH range 0 ... 14 2 ... 13 2 ... 13 0 ... 14 2 ... 13 2 ... 13 2 ... 14
pressure range [bar] 10 10 10 6 6 6 6
length L [mm] 170 120 225 170 120 225 120
sterilizable ●

diaphragm ceramic ● ●

platinum ●

hole ● ● ● ●

electrolyte liquid, refillable (L 300) ●

liquid, refillable (L 310) ● ●

Referid®, low-maintenance ● ● ● ●

certified pressure and temperature consistency 1) ● ● ●

connection SMEK SMEK SMEK VP VP VP SMEK


design corresponding illustration A A A B B B C
type no. of variant with VP plug head PET 20-120

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A PET 50-120 HD
PET 10-170 HD
PET 50-225 HD

B PET 80-120
PET 60-170
PET 80-225

40
00

50

00
20
-2

-2

-2
-1
30

30

36

36
T

T
PE

PE

PE

PE
Pt 1000 Pt 1000 Pt 1000 Pt 1000 MultiSens electrodes
S S S S More information from a single measuring point.
900 900 900 900 Type series PET: pH combination electrode with
0 ...135 0 ...135 0 ...135 0 ...135 integrated temperature sensor.
2 ... 14 2 ... 14 2 ... 14 2 ... 14
6 6 6 6 Zero point:
200 250 120 200 ◗ pH = 7.0
● ● ● ● Connection (design A+B):
● ● ● ● ◗ screw plug head with thread Pg 13.5
Connection (design C+D):
◗ smooth plug head for sterilizable electrode
● ● ● ● holders
Supply (design A):
◗ HD sealing type 9980/51
Supply (design B):
SMEK SMEK SMEK SMEK ◗ washer 9980/52
C C D D ◗ O-ring type 9932/07
PET 20 -200 PET 20-250 PET 26-120 PET 26-200 Connecting cable:
◗ SMEK: e.g. type SMEK 19/05
(length 5 m with free end)
◗ VP: e.g. type VP6-19/05
(length 5 m with free end)
For additional connecting cables, see under
Accessories.

C PET 20-120
PET 20-200
PET 20-250
PET 30-120
PET 30-200
PET 30-250

D PET 26-120
PET 26-200
PET 36-120
PET 36-200

41
MultiSens electrodes pH, mV, °C

D
D

H
H

20

25

25
70

20
70

20
-1

-2

-2
-1

-1
-1

-1
50

50

80

30
60

80
10

TR

TR

TR

TR
TR

TR

TR
PE

PE

PE

PE
PE

PE

PE
redox sensor platinum ring ● ● ● ● ● ● ●

temperature sensor Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000


membrane glass A A A A A A S
membrane resistance (25°C) [MΩ] 500 500 500 500 500 500 900
temperature range [°C] 0 ...135 0 ...100 0 ....100 0 ...135 0 ...100 0 ...100 0 ...135
pH range 0 ... 14 2 ... 13 2 ... 13 0 ... 14 2 ... 13 2 ... 13 2 ... 14
pressure range [bar] 10 10 10 6 6 6 6
length L [mm] 170 120 225 170 120 225 120
sterilizable ●

diaphragm ceramic ● ●

platinum ●

hole ● ● ● ●

electrolyte liquid, refillable (L 300) ●

liquid, refillable (L 310) ● ●

Referid®, low-maintenance ● ● ● ●

certified pressure and temperature consistency 1) ● ● ●

connection SMEK SMEK SMEK VP VP VP SMEK


design corresponding illustration A A A B B B C
type no. of variant with VP plug head PETR 20-120

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A PETR 50-120 HD
PETR 10-170 HD
PETR 50-225 HD

B PETR 80-120
PETR 60-170
PETR 80-225

42
00

00
20
-2

-2
-1
30

36

36
TR

TR

TR
PE

PE

PE
● ● ● MultiSens electrodes Supply (design A):
Pt 1000 Pt 1000 Pt 1000 More information from a single measuring point. ◗ HD sealing type 9980/51
S S S Type series PETR: pH combination electrode with Supply (design B):
900 900 900 integrated redox and temperature sensor. ◗ washer 9980/52
0 ...135 0 ...135 0 ...135 ◗ O-ring type 9932/07
2 ... 14 2 ... 14 2 ... 14 Zero point: Connecting cable:
6 6 6 ◗ pH = 7.0 ◗ SMEK: e.g. type SMEK 19/05
200 120 200 Connection (design A+B): (length 5 m with free end)
● ● ● ◗ screw plug head with thread Pg 13.5 ◗ VP: e.g. type VP6-19/05
● ● ● Connection (design C+D): (length 5 m with free end)
◗ smooth plug head for sterilizable electrode For additional connecting cables, see under
holders. Accessories.
● ● ●

SMEK SMEK SMEK


C D D
PETR 20-200 PETR 26-120 PETR 26-200

C PETR 20-120
PETR 20-200
PETR 30-120
PETR 30-200

D PETR 26-120
PETR 26-200
PETR 36-120
PETR 36-200

43
MultiSens electrodes pH, mV, µS, °C

D
D

H
H

20

25

25

00
70

70

20
-1

-2

-2

-2
-1

-1

-1
50

50

80

30
10

60

80
TL

TL

TL

TL
TL

TL

TL
PE

PE

PE

PE
PE

PE

PE
redox sensor: 2 platinum rings ● ● ● ● ● ● ●

temperature sensor Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000 Pt 1000


membrane glass A A A A A A S
membrane resistance (25°C) [MΩ] 500 500 500 500 500 500 900
temperature range [°C] 0 ...135 0 ...100 0 ...100 0 ...135 0 ...100 0 ...100 0 ...135
pH range 0 ...14 2 ...13 2 ...13 0 ...14 2 ... 13 2 ... 13 2 ... 14
pressure range [bar] 10 10 10 6 6 6 6
conductivity range (25°C) 10 10 10 10 10 10 10
up to [mS/cm] 2)
cell constant about [cm -1] 0.6 0.6 0.6 0.6 0.6 0.6 0.6
length L [mm] 170 120 225 170 120 225 200
sterilizable ●

diaphragm ceramic ● ●

platinum ●

hole ● ● ● ●

electrolyte liquid, refillable (L 300) ●

liquid, refillable (L 310) ● ●

Referid®, low-maintenance ● ● ● ●

certified pressure and temperature consistency 1)


● ● ●

connection SMEK SMEK SMEK VP VP VP SMEK


design corresponding illustration A A A B B B C
type no. of variant with VP plug head PETL 20-200

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.
2)
Out of the recommended conductivity range the error of measurement can be >10%, also depending on conductivity meter.

A PETL 50-120 HD
PETL 10-170 HD
PETL 50-225 HD

B PETL 80-120
PETL 60-170
PETL 80-225

44
00
-2
36
TL
PE

● MultiSens electrodes Supply (design A):


Pt 1000 Five parameters from one MultiSens electrode: ◗ HD sealing type 9980/51
S pH, redox, conductivity, temperature and reference Supply (design B):
900 system. ◗ washer 9980/52
0 ...135 ◗ O-ring type 9932/07
2 ... 14 Zero point: Connecting cable:
6 ◗ pH=7.0 ◗ SMEK: e.g. type SMEK 18/05
10 Connection (design A+B): (length 5 m with free end)
◗ screw plug head with thread Pg 13.5 ◗ VP: e.g. type VP6-18/05
0.6 Connection (design C+D): (length 5 m with free end)
200 ◗ smooth plug head for sterilizable electrode For additional connecting cables,
● holders see under Accessories.

SMEK
D
PETL 26-200

C PETL 20-200
PETL 30-200

D PETL 26-200
PETL 36-200

45
MultiSens electrodes double pH, °C

D
D

H
H

20

25

00
70

20

00
-1

-2

-2
-1

-1

-2
50

50

36
10

30

30
T

T
T

T
PE

PE

PE
PE

PE

PE
D

D
D

D
temperature sensor NTC 30KΩ NTC 30KΩ NTC 30KΩ NTC 30KΩ NTC 30KΩ NTC 30KΩ
membrane glass A A A S S S
membrane resistance (25°C) [MΩ] 500 500 500 900 900 900
temperature range [°C] 0 ...135 0 ...100 0 ...100 0 ...135 0 ...135 0 ...135
pH range 0 ...14 2 ...13 2 ...13 2 ...14 2 ... 14 2 ... 14
pressure range [bar] 10 10 10 6 6 6
length L [mm] 170 120 225 120 200 200
sterilizable ● ● ●

diaphragm ceramic ● ● ●

platinum ●

hole ● ●

electrolyte liquid, refillable (L 300) ● ● ●

liquid, refillable (L 310) ●

Referid®, low-maintenance ● ●

certified pressure and temperature consistency 1) ● ● ●

connection SMEK SMEK SMEK SMEK SMEK SMEK


design corresponding illustration A A A B B C
type no. of variant with VP plug head DPET 20-120 DPET 20-200 DPET 26-200

1)
These types are supplied in series with Works Certificate 2.1 according to DIN EN 10204 regarding resistance to pressure and temperature.

A DPET 50-120 HD
DPET 10-170 HD
DPET 50-225 HD

B DPET 20-120
DPET 30-120
DPET 30-200
DPET 20-200

46
MultiSens electrodes
Double pH measuring technology for measure- Supply (design A):
ment point monitoring. Integrated temperature ◗ HD sealing type 9980/51
sensor. Connecting cable:
◗ SMEK: e.g. type SMEK 18/05
Zero points: (length 5 m with free end)
◗ pH = 7.0 and pH = 4.6 ◗ VP: e.g. type VP6-18/05
Connection (design A): (length 5 m with free end)
◗ screw plug head with thread Pg 13.5 For additional connecting cables,
Connection (design B+C): see under Accessories.
◗ smooth plug head for sterilizable electrode
holders

C DPET 26-200
DPET 36-200

47
MultiSens electrodes µS, °C

20
20

-1
-1

60
10

H
H

4T
4T

LF
LF
conductivity sensor: 4 platinum rings ● ●

temperature sensor Pt 1000 Pt 1000


temperature range [°C] - 5 ... + 80 - 5 ... + 80
pressure range [bar] 10 6
conductivity range (25°C) 1000 1000
up to [mS/cm] 1)
cell constant about [cm -1] 1.0 1.0
length L [mm] 120 120
connection SMEK VP
design corresponding illustration A B

1)
Out of the recommended conductivity range the error of measurement can be >10%, also depending on type of conductivity meter.

A LF 4TH 10-120

B LF 4TH 60-120

48
MultiSens electrodes
4-pole conductivity cells with integrated tempera-
ture sensor.

Connection:
◗ screw plug head with thread Pg 13.5
Supply:
◗ washer 9980/52
◗ O-ring type 9932/07
Connecting cable:
◗ SMEK: e.g. type SMEK 18/05
(length 5 m with free end)
◗ VP: e.g. type VP6-18/05
(length 5 m with free end)
For additional connecting cables,
see under Accessories.

49
Oxygen electrodes

2
01

/2
11

09
X

90
O
temperature range [°C] 0 ... 45 0 ... 45
pressure range [bar] ± 0.1 ± 0.1
measuring range oxygen in water [mg/l] 0 ... 20 0 ... 20
length L [mm] 120 120
shaft material plastic (POM) plastic (POM)
temperature sensor integrated NTC 100 kΩ NTC 100 kΩ
design and connection screw plug head Pg 13.5 2 m fixed cable, flange cap
supply 1 spare membrane head 1 spare membrane head
1 ampoule zero point solution 1 ampoule zero point solution
50 ml electrolyte type L 6708 50 ml electrolyte type L 6708
washer type 9980/52 O-ring type 9932/07
O-ring type 9932/07
design corresponding illustration A B

A OX 1101

B 9009/22

50
Oxygen Electrodes for measuring dissolved Cathode:
oxygen ◗ platinum
Particularly suitable for the drinking water, Anode:
industrial water and sewage range. ◗ silver
Electrolyte:
Mode of functioning: ◗ sodium phosphate solution type L 6708
For measuring dissolved oxygen in liquids, the Membrane:
“Clark” principle is applied with this electrode. The ◗ PTFE, 25µm
electrode is filled with an alkaline electrolyte and Shaft diameter:
covered with a membrane that is permeable to ◗ 12 mm
oxygen. For measuring, a minimum flow speed of Connection cable for OX 1101:
10 cm/sec should prevail. The electrodes possess an ◗ e.g. type 9909/23 (length 3 m with free end),
integrated temperature sensor for automatic tem- max. recommended cable length: 5 m
perature compensation. For additional connecting cables,
see under Accessories.

Accesssories:
◗ zero point solution type OX 060:
60 ampoules á 25 ml
◗ electrolyte solution type L 6708: PE bottle 50 ml
◗ service set type OX 928: 5 spare membrane
heads, 50 ml electrolyte solution L 6708,
6 ampoules zero point solution
◗ type OX 929: 5 spare membrane heads

51
Accessories: Connection cables

Connection cables for ◗ combination electrodes


◗ measuring electrodes

connection cable electrode socket cable type, length1) instrument connection max. temp.
9901/01 socket 9901/00 KA 01, 1 m free end 80 °C
9901/05 KA 01, 5 m free end 80 °C
9901/010 KA 01, 10 m free end 80 °C
9902/01 KA 02, 1 m free end 135 °C
9902/05 KA 02, 5 m free end 135 °C
9902/010 KA 02, 10 m free end 135 °C

9903/01 socket 9901/00 KA 01, 1 m, as extension plug 9903/00 80 °C


9903/05 KA 01, 5 m, as extension 80 °C
9904/02 KA 02, 2 m, as extension 135 °C
9904/05 KA 02, 5 m, as extension 135 °C

9912/01 socket 9901/00 KA 01, 1 m plug 9912/00 80 °C

9917/01 socket 9901/00 KA 01, 1 m plug 9917/00 80 °C


9917/02 KA 01, 2 m 80 °C
9917/05 KA 01, 5 m 80 °C
9918/05 KA 02, 5 m 135 °C

1)
Other cable lengths on request. Recommended max. cable length 20 m.

Connection cable for ◗ reference electrodes

connection cable electrode socket cable type, length1) instrument connection max. temp.
9905/01 socket 9905/00 KA 06, 1 m free end 80 °C
9905/05 KA 06, 5 m free end 80 °C
9905/010 KA 06, 10 m free end 80 °C

9906/05 socket 9905/00 KA 06, 5 m, as extension plug 9906/00 80 °C

9915/01 socket 9905/00 KA 06, 1 m plug 9915/00 80 °C


9915/05 KA 06, 5 m 80 °C

1)
Other cable lengths on request. Recommended max. cable length 50 m.

52
Connection cables

Connection cables for ◗ conductivity cells without temperature sensor


◗ resistance thermometers

connection cable electrode socket cable type, length1) instrument connection max. temp.
9907/01 socket 9907/00 KA 07, 1 m free end 80 °C
9907/05 KA 07, 5 m free end 80 °C

9907/21 socket 9907/00 KA 07, 1 m 2 x plug 9915/00 80 °C

9908/05 socket 9907/00 KA 07, 5 m, as extension plug 9908/00 80 °C

1)
Other cable lengths on request. Recommended max. cable length 5 m.

Connection cables for ◗ conductivity cells with temperature sensor


◗ resistance thermometers with two resistances

connection cable electrode socket cable type, length1) instrument connection max. temp.
9909/12 socket 9909/00 KA 09, 2 m free end 80 °C
9909/15 KA 09, 5 m free end 80 °C

9910/11 socket 9909/00 KA 09, 1 m plug 9910/00 80 °C

9909/31 socket 9909/00 KA 07, 1 m; for platinizing of 2 x plug 9915/00 80 °C


conductivity cells with
temperature sensor

1)
Other cable lengths on request. Recommended max. cable length 5 m.

53
Connection cables

Connection cables for oxygen electrodes

connection cable electrode socket cable type, length1) instrument connection max. temp.
9909/21 socket 9909/00 KA 10, 1 m free end 80 °C
9909/23 KA 10, 3 m free end 80 °C

9910/21 socket 9909/00 KA 10, 1 m plug 9910/00 80 °C


9910/25 KA 10, 5 m 80 °C

1)
Other cable lengths on request. Recommended max. cable length 5 m.

Connection cables for MultiSens electrodes

connection cable electrode socket cable type, length1), MultiSens instrument connection max. temp.
SMEK-18/05 socket SMEK-B KA 18, 5 m, (PETL, DPET, LF) free end 120 °C
SMEK-18/10 KA 18, 10 m (PETL, DPET, LF) free end 120 °C
SMEK-19/05 KA 19, 5 m (PET, PETR) free end 130 °C
SMEK-19/10 KA 19, 10 m (PET, PETR) free end 130 °C
SMEK-20/05 KA 20, 5 m free end 80 °C

VP6-18/05 socket VP6-B KA 18, 5 m (PETL, DPET, LF) free end 120 °C
VP6-19/05 KA 19, 5 m (PET, PETR) free end 130 °C

1)
Other cable lengths on request. Recommended max. cable length 10 m.

54
Connection cable

Plugs, sockets and accessories for self assembly

type no. housing material description


9901/00 PPS coaxial socket for measuring electrodes and combination electrodes
9903/00 PPS coaxial plug for measuring electrodes and combination electrodes, for instrument connection or as extension
9905/00 PPS socket for reference electrodes
9906/00 PPS plug for reference electrodes, for instrument connection or as extension
9907/00 PPS 2-pole socket for resistance thermometers and conductivity cells without temperature sensor
9908/00 PPS 2-pole plug for resistance thermometers and conductivity cells without temperature sensor
9909/00 PPS 4-pole socket for resistance thermometers with two resistances,
conductivity cells with temperature sensor and oxygen electrodes
9910/00 PPS 4-pole plug for resistance thermometers with two resistances,
conductivity cells with temperature sensor and oxygen electrodes
9911/50 mounting tool for cable socket 9901/00 and 9905/00
9911/51 PPN cover cap for electrode plug head and plugs 9903/00, 9906/00, 9908/00 and 9910/00
9911/52 PPN cover cap for sockets 9901/00, 9905/00, 9907/00, 9909/00, 9911/53, 9911/54, 9911/55 and 9911/56
9911/53 polysulfone instrument socket for plug 9903/00
9911/54 polysulfone instrument socket for plug 9906/00
9911/55 polysulfone instrument socket for plug 9908/00
9911/56 polysulfone instrument socket for plug 9910/00
9915/00 PVC banana plug 4 mm
9917/00 brass, nickel-plated DIN plug for connection to instruments with DIN socket
SMEK-B PPS SMEK cable socket for SMEK electrode plug head
SMEK-S PPS SMEK-plug for connection to instruments with SMEK socket
SMEK-GB PPS SMEK instrument socket
VP6-B brass, nickel-plated VP-6-pole-cable socket for VP electrode plug head
Z 515 mounting tool for SMEK plug/socket

Cables for self assembly

type no. description Ø application max. temp.


KA 01 coaxial cable 5 mm measuring electrodes, combination electrodes 80 °C
KA 02 coaxial cable 5 mm measuring electrodes, combination electrodes 135 °C
KA 03 triaxial cable 5 mm combination electrodes with temperature sensor 80 °C
KA 04 three-core cable 5 mm resistance thermometers with grounding 80 °C
KA 05 single-wire cable 5 mm reference electrodes 135 °C
KA 06 single-wire cable 4 mm reference electrodes 80 °C
KA 07 twin-core cable 5 mm resistance thermometers, conductivity cells 80 °C
KA 08 twin-core cable 5 mm resistance thermometers, conductivity cells 135 °C
KA 09 four-core cable 5 mm conductivity cells with temperature sensor, double temp. sensors 80 °C
KA 10 four-core cable, shielded 5 mm oxygen electrodes 80 °C
KA 18 double coaxial cable, 3 cords 7.5 mm MultiSens electrodes (PETL, DPET, LF) 120 °C
KA 19 coaxial cable, 4 cords 6 mm MultiSens electrodes (PET, PETR) 130 °C
KA 20 six-wire cable, shielded 5.5 mm resistance thermometers with SMEK head 80 °C

55
Other accessories and spare parts

Accessories for electrodes and electrolyte bridges

type no. description


9921/62 electrolyte pressure reservoir, 110 ml, up to 6 bar
9940/03 watering cap
9955/00 KCl reservoir, 200 ml, suitable pressure tubing: 9980/00
9961/09 flexible pressure tubing, NW 4 mm, 2 m, PU, e.g. for miniature pressure adapter type 9921/51 HD
9980/00 flexible pressure tubing, silicone, textile mantle, 8x2 mm,
e.g. for electrolyte pressure reservoirs type 9921/62 and 9955/00
9980/10 hose coupling for hose type 9980/00
9980/21 hose band clip, Ø = 11–19 mm, for hose type 9980/00
9980/65 PTFE diaphragm for electrolyte bridges type 9844/21 and B 4491
9980/66 PTFE knurled nut for electrolyte bridges type 9844/21 and B 4491

Accessories for mounting electrodes

type no. description


9980/51 high pressure sealing unit, with 2 O-rings
9980/52 washer 18/14/4, PVDF
9980/55 pressure screw, Pg 13.5, PPS,
for closing of openings with Pg 13.5
9921/25 O-ring 12-3.5, PTFE mantle
9932/05 O-ring 26-3
9932/06 O-ring 10-4
9932/07 O-ring 10-3.5
Z 501 O-ring 10.5-1.5

Accesssories for oxygen electrodes

type no. description


OX 928 Service set: 5 spare membrane heads,
50 ml electrolyte L 6708, 6 ampoules of zero point solution
OX 929 5 spare membrane heads

Miniature pressure adapter

type no. description


9921/51 HD miniature pressure adapter, PPS, for mounting of electrodes with lateral electrolyte
refill opening and Pg 13.5 thread, up to a pressure of 10 bar. The maximum permissible
pressure difference between the inside of the reference electrode and the measuring
media amounts to 3 bar. 9921/51 HD (Illust. with reference electrode B 1491 HD)

56
Buffer solutions

ST
d NI
Working reference buffer solutions according to DIN 19 266 PTB an
e to
eabl
◗ sterilized for longer storability, without preservation Trac

type no. pH value at 25 °C content


L 4794 4.01 60 ampoules à 25 ml, with manufacturer certificate
L 4796 6.87 60 ampoules à 25 ml, with manufacturer certificate
L 4799 9.18 60 ampoules à 25 ml, with manufacturer certificate
L 4790 4.01/6.87 2 x 30 ampoules à 25 ml, with manufacturer certificate
L 4798 4.01/6.87/9.18 3 x 20 ampoules à 25 ml, with manufacturer certificate
L 401 4.01 1000 ml in DURAN® glass bottle, with manufacturer certificate
L 4014 4.01 250 ml in DURAN® glass bottle, with manufacturer certificate
L 687 6.87 1000 ml in DURAN® glass bottle, with manufacturer certificate
L 6874 6.87 250 ml in DURAN® glass bottle, with manufacturer certificate
L 918 9.18 1000 ml in DURAN® glass bottle, with manufacturer certificate
L 9184 9.18 250 ml in DURAN® glass bottle, with manufacturer certificate

Technical buffer solutions according to DIN 19 267


◗ sterilized for longer storability, without preservation

type no. pH value at 25 °C content


L 4694 4.00 60 ampoules à 25 ml
L 4697 7.00 60 ampoules à 25 ml
L 4691 10.00 60 ampoules à 25 ml
L 4690 4.00/7.00 2 x 30 ampoules à 25 ml
L 4698 4.00/7.00/10.00 3 x 20 ampoules à 25 ml
L 400 4.00 1000 ml in DURAN® glass bottle
L 4004 4.00 250 ml in DURAN® glass bottle
L 700 7.00 1000 ml in DURAN® glass bottle
L 7004 7.00 250 ml in DURAN® glass bottle
L 100 10.00 1000 ml in DURAN® glass bottle
L 1004 10.00 250 ml in DURAN® glass bottle

Colored technical buffer solutions in plastic bottles

type no. pH value at 25 °C content


LC 4004 K 4.00 250 ml in PE bottle
LC 7004 K 7.00 250 ml in PE bottle
LC 1004 K 10.00 250 ml in PE bottle

Technical buffer solutions according to DIN 19 267 in canisters


◗ for longer storability preserved with thymol

type no. pH value at 25 °C content


L 4655 4.65 5 l in plastic canister
L 6795 6.79 5 l in plastic canister
57
Electrolyte solutions

Electrolyte solutions, aqueous


◗ for reference electrodes and electrolyte bridges

type no. description content


L 200 for low temperature (-30 °C) 1000 ml in DURAN® glass bottle
L 2004 for low temperature (-30 °C) 250 ml in DURAN® glass bottle
L 2114 2 mol/l KNO3 + 0.001 mol/l KCl 250 ml in DURAN® glass bottle
for Ag combination electrodes
L 300 KCl solution 3 mol/l 1000 ml in DURAN® glass bottle, sterilized
L 3004 KCl solution 3 mol/l 250 ml in DURAN® glass bottle, sterilized
L 310 KCl solution 2 mol/l, thickened 1000 ml in DURAN® glass bottle
L 3104 KCl solution 2 mol/l, thickened 250 ml in DURAN® glass bottle
L 350 KCl solution 3.5 mol/l 1000 ml in DURAN® glass bottle, sterilized
L 3504 KCl solution 3.5 mol/l 250 ml in DURAN® glass bottle, sterilized
L 420 KCl solution 4.2 mol/l 1000 ml in DURAN® glass bottle
L 4204 KCl solution 4.2 mol/l 250 ml in DURAN® glass bottle

Electrolyte solutions, organic


◗ for measurements in organic solutions: for reference electrodes and electrolyte bridges

type no. description content


L 5014 LiCl 0.1 mol/l in glacial acetic acid 250 ml in DURAN® glass bottle
L 5024 LiCl 0.1 mol/l in methanol 250 ml in DURAN® glass bottle
L 5034 LiCl 0.1 mol/l in ethanol 250 ml in DURAN® glass bottle
L 4804 for tensides containing solutions 250 ml in DURAN® glass bottle

58
Other solutions

Solutions for oxygen measurements

type no. description content


OX 060 zero point solution 60 ampoules à 25 ml
L 6708 electrolyte solution 50 ml in PE bottle

Solutions and accessories for conductivity measurements

type no. description content


LF 906 platinizing solution 1 x 6 ampoules à 25 ml
LF 990 test solution KCl 0.001 mol/l (147 µS/cm) 3 x 6 ampoules à 25 ml
LF 991 test solution KCl 0.01 mol/l (1.41 mS/cm) 3 x 6 ampoules à 25 ml
LF 992 test solution KCl 0.1 mol/l (12.9 mS/cm) 3 x 6 ampoules à 25 ml
LF 995 test solutions KCl 0.01/0.1/1 mol/l (1.41/12.9/112 mS/cm) 3 x 6 ampoules à 25 ml
LF 999/Set test solutions KCl 0.01/0.1 mol/l and solution LF 906 3 x 6 ampoules à 25 ml
LF 1000/Set like LF 999, additionally platinizing vessel and cable B1N 3 x 6 ampoules à 25 ml
LF 1024K test solution KCl 0.01 mol/l (1.41 mS/cm) 250 ml in PE bottle

Redox test solutions

type no. redox voltage content


Pt/calomel (KCl sat.) Pt/Ag/AgCl (KCl 3 mol/l)
L 4619 180 mV 220 mV 60 ampoules à 25 ml, according to DIN 38 404-C6
L 4643 430 mV 470 mV 60 ampoules à 25 ml
L 4660 600 mV 640 mV 60 ampoules à 25 ml
L 4648 180, 430, 600 mV 220, 470, 640 mV 3 x 20 ampoules à 25 ml
L 430 430 mV 470 mV 1000 ml in DURAN® glass bottle
L 4304 430 mV 470 mV 250 ml in DURAN® glass bottle

Cleaning solution for combination electrodes and reference electrodes

type no. description content


L 510 pepsin/hydrochloric acid solution 1000 ml in DURAN® glass bottle
L 5104 pepsin/hydrochloric acid solution 250 ml in DURAN® glass bottle

59
Index
type no. order no. page type no. order no. page type no. order no. page type no. order no. page

Electrodes AgS 1101 28 511 5959 18 H 8381 28 511 0976 13 PETR 10-170 HD 28 512 7816 42

9006/25 28 511 1159 18 AgS 6181 28 511 8811 14 H 8481 HD 28 511 1072 13 PETR 20-120 28 512 7857 42

9006/35 28 511 1553 18 AgS 8281 28 511 8836 14 H 9080 28 511 0795 10 PETR 20-200 28 512 7865 42

9006/95 28 511 1253 18 AL 63 LFT 28 511 3016 34 H 9090 28 511 0602 10 PETR 26-120 28 512 7927 42

9008/15 28 511 1356 18 AL 70 pH 28 511 3049 34 H 9180 28 511 0591 10 PETR 26-200 28 512 7919 42
9009/22 28 511 1623 50 AL 79 Pt 28 511 3073 34 L 1181 HD 28 511 1475 16 PETR 30-120 28 512 8426 42

9010/25 28 511 9351 30 AL 80 pH 28 511 3098 34 L 6191 28 511 7967 8 PETR 30-200 28 512 8475 42

9010/85 28 511 1759 30 AL 81 pHT 28 511 3102 34 L 7781 28 511 8088 13 PETR 36-120 28 512 8491 42

9011/25 28 511 1853 30 AL 82 pHT 28 511 3119 34 L 8281 HD 28 511 1418 13 PETR 36-200 28 512 8512 42

9101/85 28 511 5752 16 AL 83 pHT 28 511 3127 34 L 9080 28 511 8158 10 PETR 50-120 HD 28 511 2209 42

9117/85 28 511 2558 16 AL 89 Pt 28 511 3143 34 L 9090 28 511 8174 10 PETR 50-225 HD 28 512 7935 42

9182/85 28 511 2755 12 AL 90 pH 28 511 3176 34 L 9180 28 511 8166 10 PETR 60-170 28 512 7881 42
9182/95 28 511 3024 12 AL 93 pHT 28 511 3205 34 LF 1051 28 511 9808 32 PETR 80-120 28 512 7898 42

9183/85 28 511 2952 12 Au 1101 28 511 1031 18 LF 1101 28 511 9816 32 PETR 80-225 28 512 7873 42

9501/75 28 511 4756 16 Au 9080 28 511 0787 14 LF 1101T 28 511 9832 32 Pt 1801 HD 28 511 2233 18

9501/85 28 511 4859 16 B 1181 HD 28 511 1701 20 LF 1101T HD 28 511 2188 32 Pt 22120 28 512 8364 38

9504/85 28 511 5058 16 B 1391 HD 28 511 1491 20 LF 1201 28 511 9824 32 Pt 22150 28 512 8372 38

9517/85 28 511 5255 16 B 1491 HD 28 511 1504 20 LF 5101 28 511 9849 32 Pt 22200 28 512 8389 38

9582/85 28 511 8655 12 B 1591 28 511 6165 20 LF 5101T 28 511 9857 32 Pt 23128 28 512 8956 38

9582/95 28 511 8844 12 B 1881 HD 28 511 1767 20 LF4TH 10-120 28 512 6717 48 Pt 23158 28 512 8964 38

9583/85 28 511 8758 12 B 1981 HD 28 511 1915 20 LF4TH 60-120 28 512 6725 48 Pt 23208 28 512 8972 38

9601/85 28 511 5358 16 B 4411 28 511 8203 26 LF 71T 28 511 9713 32 Pt 26120 28 512 8434 38

9701/85 28 511 8955 16 B 4441 28 511 8211 26 N 2981 28 511 0208 16 Pt 26150 28 512 8442 38

9801/85 28 511 7856 20 B 4451 28 511 8228 26 OX 1101 28 511 9705 50 Pt 26200 28 512 8459 38

9828/95 28 511 6851 20 B 4471 28 511 8236 26 PET 10-170 HD 28 512 7405 40 Pt 6881 28 511 1101 14

9834/95 28 511 6954 20 B 4491 28 511 8244 26 PET 20-120 28 512 7557 40 Pt 6981 HD 28 511 1442 14

9844/01 28 511 8006 26 DPET 10-170 HD 28 511 2509 46 PET 20-200 28 512 7573 40 Pt 7781 28 511 0754 14

9844/02 28 511 8014 26 DPET 20-120 28 512 6996 46 PET 20-250 28 512 7565 40 Pt 8181 28 511 0992 14

9844/03 28 511 8022 26 DPET 20-200 28 512 6877 46 PET 26-120 28 512 7602 40 Pt 8281 HD 28 511 2414 14

9844/04 28 511 8039 26 DPET 26-200 28 512 6885 46 PET 26-200 28 512 7619 40 Pt 9080 28 511 1089 14

9844/05 28 511 8047 26 DPET 30-120 28 512 8689 46 PET 30-120 28 512 8007 40 S 1181 HD 28 511 1483 16

9844/07 28 511 8055 26 DPET 30-200 28 512 8697 46 PET 30-200 28 512 8023 40 S 1191 HD 28 511 2085 16

9844/11 28 511 8109 26 DPET 36-200 28 512 8701 46 PET 30-250 28 512 8245 40 S 22120 28 512 8056 38

9844/14 28 511 8117 26 DPET 50-120 HD 28 511 2471 46 PET 36-120 28 512 8253 40 S 22125 28 512 8553 38

9844/15 28 511 8125 26 DPET 50-225 HD 28 512 8586 46 PET 36-200 28 512 8261 40 S 22150 28 512 8064 38

9844/21 28 511 8141 26 E 1651 28 511 9754 31 PET 50-120 HD 28 511 2455 40 S 22155 28 512 8561 38

9844/26 28 511 8199 26 H 1171 28 511 2114 16 PET 50-225 HD 28 511 2496 40 S 22200 28 512 8072 38

9863/01 28 511 8409 24 H 1181 HD 28 511 1467 16 PET 60-170 28 512 7651 40 S 22205 28 512 8578 38

9863/03 28 511 8417 24 H 1191 HD 28 511 1931 16 PET 80-120 28 512 7668 40 S 23128 28 512 8607 38

9863/04 28 511 8425 24 H 1481 HD 28 511 1948 16 PET 80-225 28 512 7676 40 S 23158 28 512 8623 38

9863/05 28 511 8433 24 H 2781 HD 28 511 1956 16 PETL 10-170 HD 28 511 2488 44 S 23208 28 512 8648 38

9864/01 28 511 8306 24 H 6181 HD 28 511 1426 8 PETL 20-200 28 512 7746 44 S 26120 28 512 8348 38

9864/02 28 511 8314 24 H 6191 HD 28 511 1434 8 PETL 26-200 28 512 7762 44 S 26125 28 512 8878 38

9864/03 28 511 8322 24 H 6281 28 511 0146 8 PETL 30-200 28 512 8537 44 S 26150 28 512 8331 38

9864/04 28 511 8339 24 H 6291 28 511 1964 8 PETL 36-200 28 512 8545 44 S 26155 28 512 8886 38

9864/05 28 511 8347 24 H 6381 28 511 0195 8 PETL 50-120 HD 28 511 2463 44 S 26200 28 512 8356 38

9864/07 28 511 8355 24 H 6391 28 511 1923 8 PETL 50-225 HD 28 512 7943 44 S 26205 28 512 8894 38

9871/95 28 511 7556 22 H 6481 28 511 0919 8 PETL 60-170 28 512 7787 44 S 2781 HD 28 511 2093 16

Ag 1101 28 511 1048 18 H 8181 HD 28 511 1007 13 PETL 80-120 28 512 7951 44 S 6181 HD 28 511 1972 8

Ag 9080 28 511 0721 14 H 8281 HD 28 511 1015 13 PETL 80-225 28 512 7902 44 S 6191 HD 28 511 1989 8

60
Index
type no. order no. page type no. order no. page type no. order no. page type no. order no. page

S 6281 28 511 0187 8 9903/00 28 512 6014 55 9955/00 28 505 1945 56 L 4697 28 513 8221 57

S 6291 28 511 1997 8 9903/01 28 512 4219 52 9961/09 28 505 1086 56 L 4698 28 513 8192 57

S 6381 28 511 2369 8 9903/05 28 512 4251 52 9980/00 28 505 2017 56 L 4790 28 513 8402 57

S 6391 28 511 2077 8 9904/02 28 512 4321 52 9980/10 28 505 2588 56 L 4794 28 513 8246 57

S 6481 28 511 2385 8 9904/05 28 512 4354 52 9980/21 28 505 3219 56 L 4796 28 513 8254 57
S 9080 28 511 2393 10 9905/00 28 512 6022 55 9980/51 28 505 1756 56 L 4798 28 513 8238 57

S 9090 28 511 2422 10 9905/01 28 512 4416 52 9980/52 28 505 1764 56 L 4799 28 513 8262 57

S 9180 28 511 2406 10 9905/010 28 512 4502 52 9980/55 28 505 1891 56 L 4804 28 513 9012 58

Sb 1101 28 511 1056 18 9905/05 28 512 4457 52 9980/65 28 512 6158 56 L 5014 28 513 8324 58

SL 80-120pH 28 511 3213 36 9906/00 28 512 6039 55 9980/66 28 512 6244 56 L 5024 28 513 8316 58

SL 80-225pH 28 511 3246 36 9906/05 28 512 4551 52 KA 01 28 512 3617 55 L 5034 28 513 8308 58

SL 80-325pH 28 511 3254 36 9907/00 28 512 6047 55 KA 02 28 512 3625 55 L 510 28 513 8538 59
SL 80-360pH 28 511 3468 36 9907/01 28 512 4613 53 KA 03 28 512 3633 55 L 5104 28 513 8295 59

SL 80-425pH 28 511 3262 36 9907/05 28 512 4654 53 KA 04 28 512 3609 55 L 6708 28 513 8513 59

SL 81-120pHT 28 511 3221 36 9907/21 28 512 4716 53 KA 05 28 512 3641 55 L 6795 28 513 8681 57

SL 81-225pHT 28 511 3279 36 9908/00 28 512 6055 55 KA 06 28 512 3658 55 L 687 28 513 8102 57

SL 81-325pHT 28 511 3476 36 9908/05 28 512 4851 53 KA 07 28 512 3666 55 L 6874 28 513 8016 57

SL 81-425pHT 28 511 3295 36 9909/00 28 512 6063 55 KA 08 28 512 3674 55 L 700 28 513 8735 57

SL 82-120pHT 28 511 3238 36 9909/12 28 512 5129 53 KA 09 28 512 3682 55 L 7004 28 513 8049 57

SL 82-225pHT 28 511 3349 36 9909/15 28 512 5153 53 KA 10 28 512 3699 55 L 918 28 513 8119 57

SL 82-325pHT 28 511 3287 36 9909/21 28 512 5018 54 KA 18 28 512 5889 55 L 9184 28 513 8024 57

SL 82-360pHT 28 511 3484 36 9909/23 28 512 5034 54 KA 19 28 512 5897 55 LC 1004 K 28 513 9201 57

SL 82-425pHT 28 511 3357 36 9909/31 28 512 5618 53 KA 20 28 512 5934 55 LC 4004 K 28 513 9148 57

SL 89-120Pt 28 511 3402 36 9910/00 28 512 6071 55 L 100 28 513 8719 57 LC 7004 K 28 513 9172 57

SL 89-225Pt 28 511 3419 36 9910/11 28 512 5515 53 L 1004 28 513 8057 57 LF 906 28 513 8616 59

SL 89-325Pt 28 511 3427 36 9910/21 28 512 5215 54 L 200 28 513 8151 58 LF 990 28 512 6503 59

SL 89-425Pt 28 511 3443 36 9910/25 28 512 5248 54 L 2004 28 513 8365 58 LF 991 28 512 6511 59

W 1101 28 509 7216 18 9911/50 28 512 6088 55 L 2114 28 513 8349 58 LF 992 28 512 6528 59

W 2021 28 511 9113 28 9911/51 28 512 6096 55 L 300 28 513 8554 58 LF 995 28 512 6293 59

W 2021 HD 28 511 2011 28 9911/52 28 512 6109 55 L 3004 28 513 8427 58 LF 999/Set 28 512 6174 59

W 2041 28 511 9068 28 9911/53 28 512 6117 55 L 310 28 513 8468 58 LF 1000/Set 28 512 6166 59

W 2061 28 511 9027 28 9911/54 28 512 6125 55 L 3104 28 513 8484 58 LF 1024K 28 513 6907 59

W 2061 HD 28 511 2036 28 9911/55 28 512 6133 55 L 350 28 513 8143 58 OX 060 28 513 8287 59

W 2081 28 511 9162 28 9911/56 28 512 6141 55 L 3504 28 513 8127 58 OX 928 28 512 6285 56

W 2081 HD 28 511 2044 28 9912/01 28 512 3855 52 L 400 28 513 8727 57 OX 929 28 512 6277 56

W 2121 28 511 9187 28 9915/00 28 512 5983 55 L 4004 28 513 8032 57 SMEK-18/05 28 512 9739 54

W 2161 28 511 9208 28 9915/01 28 512 5712 52 L 401 28 513 8098 57 SMEK-18/10 28 512 9755 54

W 2181 28 511 9179 28 9915/05 28 512 5753 52 L 4014 28 513 8008 57 SMEK-19/05 28 512 9747 54

W 4011 28 511 9619 28 9917/00 28 512 6203 55 L 420 28 513 8587 58 SMEK-19/10 28 512 9763 54

W 4081 28 511 9627 28 9917/01 28 512 5318 52 L 4204 28 513 8608 58 SMEK-20/05 28 512 9899 54

W 4111 28 511 9635 28 9917/02 28 512 5326 52 L 430 28 513 8184 59 SMEK-B 28 512 9677 55

9917/05 28 512 5359 52 L 4304 28 513 8168 59 SMEK-GB 28 512 3317 55

Accessories 9918/05 28 512 5453 52 L 4619 28 513 8373 59 SMEK-S 28 512 9685 55

9901/00 28 512 6006 55 9921/25 28 505 1345 56 L 4643 28 513 8357 59 VP6-18/05 28 512 9833 54

9901/01 28 512 4013 52 9921/51 HD 28 505 1604 56 L 4648 28 513 8784 59 VP6-19/05 28 512 9841 54

9901/010 28 512 4108 52 9921/62 28 505 2309 56 L 4655 28 513 8673 57 VP6-B 28 512 9644 55

9901/05 28 512 4054 52 9932/05 28 505 1526 56 L 4660 28 513 8381 59 Z 501 28 512 3193 56

9902/01 28 512 4116 52 9932/06 28 505 1534 56 L 4690 28 513 8398 57 Z 515 28 512 3271 55

9902/010 28 512 4202 52 9932/07 28 505 1542 56 L 4691 28 513 8205 57

9902/05 28 512 4157 52 9940/03 28 512 3736 56 L 4694 28 513 8213 57

61

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