CHHATTISGARH SCIENCE

COLUMBIAD CLASS - XI

Hints & Solution (l a

dsr ,a
o gy )
13. Sodium has small value of ionisation enthalpy so it can act as a
PART-I (Chemistry) reducing agent. On dissolving in ammonia solution it give blue
color solution. (lks
fM;e vk;uu ,sUFksYih d h fuEu eku j[krk gSA vr%
h 6.62  10 34
1. = = = 10–33 m ;g ,d vipk;d d h rjg d k;Zd j ld rk gSA veksfu;k foy ;u esa
mv 6.62  10 3  100 fey kusij ;g uhy k jax nsrk gSA)

14. NNaOH = 3.6 ; V NaOH = 20 ; NH2SO 4 = 9 ;

2. (A) (B) VH2SO 4 = ?

3.6  20
VH2SO 4 = = 8 mL.
9

15. (C5H8O)  84
(C) (D)

3. Only the ionic product of CuS exceeds its Ksp and hence, it is
precipitated. (d s
oy CuS d svk;fud xq
.kkad d keku bld sKsp lsvf/kd
gSblfy ;s;g vo{ksfir gksxkA) 18.

5. Polarity depend on net dipole moment. If dipole moment  = 0 it is

nonpolar. 20. SN2 mechanism occurs as (SN2 fØ ;kfof/k fuEu izd kj izkIr gksrh gSA)
(/kq
zoh;rk d qy f}/kqzo vk?kw.kZij fuHkZj d jrh gS;fn f}/kqzo vk?kw.kZ = 0 gS
rks;g v/kqzoh; gSA )
In XeF4 =0 non polar (v/kq zoh;) ; OH– +
SO3  0 non polar (v/kq zoh;)
XeOF4   0 polar (/kq
zoh;) ;
Cl4–  0 non polar (v/kq zoh;)
6. SnCl2 – sp2 ; XeF4 – sp3d2
3– – sp3d ; NCl3 – sp3
HgCl2 – sp
7. If 1 mole neon gas is removed pressure will decrease and piston In SN2 reaction, in the transition state there will be five groups
will come down as V.P. remains unchanged therefore some water attached to the carbon atom at which reaction occure. Thus
vapour will be condensed and amount of water will increase. there will be crowding in the transition state. and bulkier the
(;fn 1 eks
y fu;kWu xSl gVk;kt krkgSrksnkc d e gksxkrFkkfiLVu uhps group, the more the reaction will be hindered sterically. Hence
d hvksj t k;sxkD;ksafd ok"i ?kuRo vifjofrZr jgsxkblfy , d qN t y ok"i SN2 reaction is favoured by small groups on the carbon atom
attached to halogens. So the decreasing order of reactivity of
la?kfur gksxk rFkk t y d h ek=kk c<+t k;sxhA) halide is :
8. pH + pOH = pKW = 15 – log (5)2 (SN2 vfHkfØ ;kes
alaØ e.kvoLFkkesad kcZu]ijek.kqd slkFkik¡p lewg t qM+s
= 15 – 2 × .699 = 13.6 jgrsgSA t gk¡vfHkfØ ;k gksrh gS] bl izd kj laØ e.k voLFkk esavkl ikl
10. (1) 10–pH × 10–pOH = 10–Kw d kQ h lewg jgrk gSrFkk lewg ft ruk Hkkjh gksxk mruk gh f=kfoe Nn~e
(2) as [H+] increases, pH decreases, ([H+] c<+ rk gS] pH ?kVrk gSSA) gksrk gSA vr% gSy kst u ij t qM +sd kcZu ijek.kqij NksVslewg }kjk SN2
(3) since ionization of water is endothermic in nature hence vfHkfØ ;k izkIr gksrh gSA blfy , gSy kbM d sfy , fØ ;k'khy rk d k vojksgh
increase in temperature increases Kw. (D;ks fad t y d k vk;uu Ø e fuEu gS%)
Å "ek'kks"kh izÑ fr d k gSA blfy , rki c<+rk gSrksKw Hkh c<+rk gSA) RCH2X > R2CHX > R3CX
(primary) (secondary) (tertiary)
10 14
 –
[H ] [OH ]
(4) Ka of H2O = = = 1.8 × 10–16 21. Ground state binding energy (vk| voLFkk es acU/ku Å t kZ) = 13.6 Z2
[H2O] 55.55
= 122.4 eV.  Z = 3.
Hence only (1) is incorrect. (vr% d s
oy ¼1½ xy r gSA) 1st excitation energy (1st mÙks
t u Å t kZ) = 10.2 Z2 = 91.8 eV.
11. E = q + w = 300 + (–200) = 100 cal.  an 80 eV electron cannot excite it to a higher state. (,d 80
eV d k by sDVªkWu mPp voLFkk esamÙksft r ughagksld rk gSA)
(0) (–3) ( 1)
12. P4 + 6NaOH  PH3 + 3Na2HPO2 . 22. HCOOH HCOO– + H+
Disproportionation reaction. In this reaction, P element present 0.02 0 0
in intermediate oxidation state and P udergoes both oxidation 0.02(1 – ) 0.02 0.02
and reduction. (fo"kekuq
ikrhd j.kvfHkfØ ;kA bl vfHkfØ ;kes
aQ kWLQ ks
jl (0.02 )(0.02)
rRo ek/;fed vkDWlhd j.kvoLFkkesamifLFkr gS
A vr%Q kLWQ kjsl vkDWlhd j.k Ka = ( < < 1)
0.02
o vip;u nksuksad j ld rk gSA ) 2 × 10–4 = 0.02 2
 = 0.1

RESONANCE Sol. - XI - 1
 H+ = C 29. (x + 2)(x + 3)(x + 8)(x + 12) = 4x2
H+ = 0.02 × 0.1 = 2 × 10–3 (x2 + 14x + 24)(x2 + 11x + 24) = 4x2
pH = 3 – log2 = 2.7.
 24   24 
  x  14    x  11   =4
23. 2P + Q  R  x   x 
Initial mole 8 mole 5 mole
(izkjfEHkd eksy ) 24
(y + 14)(y + 11) = 4 where (t gk¡
) y=x+
x
8 5
=4 =5 y2 + 25y + 150 = 0 y = – 15, – 10
2 1
24
So Limiting reagent is P. (blfy , P lhekd kjh vfHkd eZ
d gSA)  x  = – 15 or (;k) – 10 x = –4, – 6
x
8–8 5–4 4 mole
30. f [g(x)] = x f (g(x)). g (x) = 1
24. Factual according to Fajan's Rule. (Q t +
ku fu;e d svuql kjA)
1 –1
 f (g(x)) = g( x )  f (g(x)).g (x) = g(x)
25. [g( x )]2

– g( x )
 f (g(x)) =
[g( x )]3

31. Required ways (vHkh"V rjhd s) = (34 –1)(23 – 1) = 560

32. Distance between AB and CD = distance between AD and BC
AB vkSj CD d se/; nwjh = AD vkSj BC d se/; nwjh

* All are positional isomers of each other.

* Total number of isomers including stereoisomer are four.
* Total optically active isomers are two.

PART-II (Mathematics)
f ( x )  g( x )
26. =a  f(x) + g(x) = 2a 2 – 2 2  10
2  =   = 0, 5/2
2 50
 h(x) = 2a which is many one into. (t ksfd cgq,d vUr%{ksih gSA)
33. (1 + ) x2 + (1 + ) y2 + (1 – 2) x + (1 + 2) y + 5 = 0
2x
27. y2 – 5y + 3 < xR (1 – 2 ) (1  2 ) 5
x2  x  1  x2 + y2 + x+ y+ =0
1  1  1 
 2x  2 Radius(f=kT;k)  0
 y2 – 5y + 3 < – 2  2   – 2,    (1 – 2)2 + (1 + 2)2 – 5(1 + )  0
 x  x 1  3
 32 –5 + 2  0  (– 1)(3– 2)  0
 y2 – 5y + 5 < 0
 2
5– 5 5 5     – ,  [1, )
  3
 y   2 , 2  
  Also (rFkk)  –1
28. a, b, c are in H.P. (a, b, c gjkRed Js.kh esagS)
34. 2b = 2ae  b = ae
1 1 1 1 1 1
 , , are in A.P.. ( , , lekUrj Js.kh esagSA) 2b 2
a b c a b c  10  b2 = 5a
a
1 1 1
–2, –2, – 2 are in A.P..

a b c b2
e2 = 1 –
a2
1 1 1
( –2, –2, –2 lekUrj Js.kh esagS) 1
a b c
e2 = 1 – e2  e=
2
1 – 2a 1 – 2b 1 – 2c
 , , are in A.P.. b 1
a b c 
a 2
1 – 2a 1 – 2b 1 – 2c
( , , lekUrj Js.kh esagSS) b 5 1
a b c  
a b 2
 b= 5 2
a, b, c are in H.P. (a, b, c gjkRed Js.kh esagS)
b 1
b b b  a = 10
 a – , b– , c– are in G.P.
.P. a 2

2 2 2
Ellipse (nh?kZ
oÙ̀k)
b b b
(a– , b– , c– xq.kksÙkj Js.kh esagSA ) x2 y2
2 2 2   1  x2 + 2y2 = 100
Also a, b, c are in H.P. (a, b, c gjkRed Js.kh esagSA) 100 50

1 1 1 1 1 1 35. R1 is not reflexive, because (q, q), (r, r)  R1.

 , , are in A.P.. ( , , lekUrj Js.kh esagSA) (R1 LorqY; ughagSD;ksafd (q, q), (r, r)  R1.)
a b c a b c
 R1 is not an equivalence relation.
e1/a, e1/b, e1/c are in G.P. (e1/a, e1/b, e1/c xq
.kksÙkj Js.kh esagS) (R1 rq
Y;rk lEcU/k ughagS)

RESONANCE Sol. - XI - 2
 R2 is not symmetric because (q, r)(p, r)  R2.
(R2 lefer ughagSD;ks afd (q, r)(p, r)  R2.) x2 x
on integrating (l ekd y u d jusij) + y +c=0
 R2 is not an equivalence relation 2
(R2 rqY;rk lEcU/k ughagS)
R3 is not symmetric, because (p, q)  R3 but (q, p)  R3.
 1  1  48 1 7 2 1
(R3 lefer ugh gSD;ks afd (p, q)  R3 y sfd u (q, p)  R3.) 44. sinx = = =– ,
12 12 3 2
36. The tangents intersects on the directrix
(Li'kZjs[kk,afu;rk ij izfrPNsn d jrh gS)      3 
There is one solution in each of  0 ,  ,  ,   ,   , ,
 the triangle is right angled isosceles. (f=kHkqt led ks.k lef}ckgqgS)  2 2   2 

37. KRISHNAGIRI or (;k) DHARMAPURI  11 

....,  5 , 
A = RI is visible (iBuh; gS A)  2 
B 1 = its from KRISHNAGIRI (;g KRISHNAGIRI l sgS
A)
     3   11 
B 2 = its from DHARMAPURI (;g DHARMAPURI l sgS A) (  0 ,  ,  ,   ,   ,  , ....,  5 ,  esal sizR;sd esa,d
 2 2   2   2 
P( A / B1) P(B1)
P(B 1/A) = P( A / B ) P(B )  P( A / B ) P(B ) gy gSA)
1 1 2 2
 There are 11 solutions (11 gy gSaA )
1 2

2 10 9
= 1 2 1 1 = 45. Since angles of  ABC are in AP
14
  
2 10 2 9 (pw
¡fd ABC d sd ks.k lekUrj Js<+h esagS)
 2
38. Sailors required for each side = 8/2 = 4  B = and (rFkk) A + C =
3 3
Since 5(= 3 + 2) sailors can work only on specified sides, the
remaining 3 (= 8 – 5) sailors would work on the boat so that
b sin B
there are 4 sailors on each side. Now (vc ) =
No. of such selections = 3C1 = 3 c sin C
(cpsgq, rhu ukfod ksaesals,d d kspquusd sizd kj = 3C1 = 3)
1
 No. of ways of arranging all sailors = 3 × 4 ! × 4 ! = 1728.  sin C =
(vr%d qy izd kj = 3 × 4 ! × 4 ! = 1728.) 2
 C = 45º hence (vr%)  A = 75º
3 6 3 6 3 1/ 3
39. I= x ( x  x  1)(2x  3x  6) dx
46. Let equation be x2 + y2 + 2gx + 2fy + g2 = 0 (ekukfd l ehd j.k
x2 + y2 + 2gx + 2fy + g2 = 0)
2
= x ( x 6  x 3  1)(2x 9  3x 6  6x 3 )1/ 3 dx Which passes through (1, –2) & (3, –4) (t ksfd fcUnq(1, –2) o
(3, –4) l sxq
t jrk gS)
Let (ekuk) 2x9 + 3x6 + 6x3 = t
 g = –3, f = 2
18(x8 + x5 + x2) dx = dt
49. The lines will pass through (4, 5) & parallel to the bisectors
1 1 t4 / 3 1
I= t1 / 3dt  . +c= (2x9 + 3x6 + 6x3)4/3 + c between them
18  18 4 / 3 24
(js
[kk,sa(4,5) l sxqt jsaxh rFkk mud sd ks.k v /kZd ksad sl ekUrj gkasxh)
/2 /2 3x – 4y – 7 12x – 5 y  6
1  2 cos x cos ec 2 x  2 cos ecx. cot x = 
40. I=  (2  cos x) 2
dx
=  dx 5 13
(2 cos ecx  cot x )2
0 0 by taking+ sign, we get 21x + 27y + 121 = 0
Now by taking – sign, we get 99x – 77y – 61 = 0
/2 so slopes of bisectors are (v r% d ks
.k v /kZd ksad ks<ky gksaxs)
 1  1
=   =
 2 cos ecx  cot x 0 2 7 9
– ,
9 7
41. The expression 2 + x – x2 is non-negative in [–1, 2]
Equation of lines are (js
[kkv ksad sl ehd j.k gksaxs)
(O;a
t d 2 + x – x2 ] [–1, 2] esav_ .kkRed gS)
Thus [a, b] should be [–1, 2] –7 9
y–5= (x – 4) and (rFkk) y–5= (x – 4)
(vr% [a, b] , [–1, 2] lsgks
uk pkfg,) 9 7
 7x + 9y = 73 and (rFkk) 9x – 7y = 1

50. D of x2 + 4x + 5 = 0 is less than zero

42. b2 – 4ac < 0  b2 < 4ac (x2 + 4x + 5 = 0 d sfy ;sD < 0 )

also (rFkk) (a – c)2  0  a2 + c2  2ac 2ac  a2 + c2  both the roots are imaginary  both the roots of quadratic
Adding the two inequalities, (nks
uksavlfed kvksad kst ksM +usij) are same
b2 + 2ac < a2 + c2 + 4ac  b2 < (a + c)2 x2 + 4x + 5 = 0 d snks
uks
aew
y d kYifud gS vr%nhx;hf}?kkr lehd j.kks
a
d snksuksaewy leku gSA
y 2 xdx  ydx – xdy
43. =0  b2 – 4ac < 0
y2
a b c
x = = =k
xdx + d  y  = 0 1 4 5
 
 a = k, b = 4k, c = 5k.

RESONANCE Sol. - XI - 3
 PART-III (Physics) L cos  2 g
T = 2 g  =
1 1 T L cos 
51. S1 = 0 + a (2)2 = 2a  S2 = 0 + a (4)2 = 8a
2 2
Hence vr% vmax = (L sin)  = gL sin  tan 
1
S21 = S2 – S1 = 8a – 2a = 6a  S3 = 0 + a (6)2 = 18 a d
2 57. P = (mgh)
S31 = S3 – S2 = 18a – 8a = 10 a  S11 : S21 : S31 = 1 : 3 : 5 dt
  1000  10  100
Pact =
VA VB 0.5
52. A B
2000
Pact = 2000 kW Pconsumption = kW = 8000 kW.
0.25
In opposite direction foifjr fn'kk esa-
   3
58. f = mg
VAB  VA  VB 10
3
or;k
  W = – fS W=– mgS
9 = VA  VB ......... (1) 10
3
or ;k W=– × 200 × 10 J = – 600 J
10
59. In uniform circular motion resultant horizontal force on the
car must be towards the centre of circular path.
In same direction - leku fn'kk esa-
   ,d l eku oÙ̀kkd kj xfr esad kj ij ifj.kkeh {kSfrt cy oÙ̀kkd kj iFk
VAB  VA  VB d sd sUnzd h rjQ gksuk pkfg,A
 
1 = VA  VB ......... (2)
From equation (1) & (2) lehd j.k (1) o (2) ls
 
VA = 5 m/s  VB = 4 m/s
60. Surface tension is a property based on intermolecular force,
at critical temperature intermolecular force is zero, hence
53. So vr%, A > B surface tension is zero.
i`"B ruko vUrj vk.kfod cy ij vk/kkfjr xq.k gS]Ø kafrd rki ij vUrj
vk.kfod cy 'kwU; gS]vr%i`"B ruko 'kwU; gSA

61. VPmax = A = Y0 2f = 4V


54. The F.B.D. of block A and B are :
xqVd sA o B d seqDr oLrqjs[kkfp=k gSa- Y0
Y0 2f = 4f  =
2

62. X = A + B sin t ; x – A = B sin t

Hence, Amplitude vr%vk;ke = B

from constraint, the acceleration of A & B are ‘2a’ and ‘a’ l 1.21
63. T = 2 g So, T = 2 g
respectively. Applying Newton’s second law to blocks A and
B, we get
ckf/kr xfr d sd kj.k]A o B d sRoj.k Ø e'k%‘2a’ o ‘a’ gSaA xqVd sA o B l T'  T
T = 1.10 × 2 g = 1.10 T = T × 100 = 10%.
ij U;wVu d k f}rh; fu;e vkjksfir d jusij ge ikrsgSa,
4g – T = 4 (2a) ........(i)

2T – 5g = 5(1) ........(ii) 64. = 2 î + 3 ĵ – k̂ at point (2,–3,1)
F
2g g 
solving we get acceleration of A and B as downward, fcUnq(2,–3,1) ij F = 2 î + 3 ĵ – k̂
7 7
upward respectively. (bud ksgy d jusij ge ikrsgSaA o B d s torque about point (0, 0, 2) fcUnq(0, 0, 2) d slkis
{k cy k?kw.kZ
2g g 
Roj.k Ø e'k% uhpsd h vksj o Å ij d h vksj gSA)
7 7 r = 2 î – 3 ĵ  k̂ – 2 k̂
 
55. W 1 = work done by spring on first mass   
igy snzO;eku ij fLizax }kjk fd ;k x;k d k;Z = r ×F = ( 2 î – 3 ĵ – k̂ )  ( 2 î  3 ĵ – k̂ )
W 2 = work done by spring on second mass
 
nwl jsnzO;eku ij fLizax }kjk fd ;k x;k d k;Z
 = (6 î  12k̂ )   = (6 5 )
W 1 = W 2 = W (say)
W 1 + W 2 = Ui – Uf
67. path difference iFkkUrj = r – 2 r
1 Kx 2 S = r ( – 2) n = S
2W = 0 – Kx2  W= –
2 4 for constructive interference lEiks"kh O;frd j.k
56. At maximum velocity the mass will just loose contact with cone r (  – 2) V Vn
and will behave like free conical pendulum with time period n = r ( – 2) = n= =
n  r (  – 2)
vf/kd re osx ij nzO;eku 'kad qij Bhd lEid ZNksM +rk gSrFkk bl eqä
d ksfud y is.Mqy e d h rjg O;ogkj d jrk gSo mld k vkorZd ky

RESONANCE Sol. - XI - 4
68. In an open pipe the ends are points of displacement antinodes
and hence pressure node. The midpoint (for fundamental mode)
is a point of displacement node and hence presure antinode.
(variation of presure is maximum at pressure antinode and zero 71.
at pressure - node).
[kqy svkxZu ikbZi esafljsfcUnqv ksd k foLFkkiu izLiUn vr% nkc fuLiUn F1 = mgsin  +  mg cos  .
gksrk gSA e/; fcUnq(ewy fo|k d sfy ,) foLFkkiu fuLiUn d k fcUnqgSvkSj F2 = mgsin  –  mg cos .
vr%nkc izLiUn gSA (nkc esaifjorZu]nkc izLiUn ij vf/kd re ,oankc But ijUrqmg = w
fuLiUn ij 'kwU; gksrk gSA  = tan 
69. There is no relative motion between source and observer so sin 
 F1 = w (sin  + cos)
V cos 
frequency remain constant n =   F1 = w sin( + )sec
0
;gkaL=kksr vkSj izs{kd d se/; lkis{kxfr ughgksjghgSvr%vkof̀r fu;r  Now v c F1 = 2 F2
V mg sin+  mg cos  = 2 (mg sin  –  mg cos)
jgs
xhA n=
0 sin+  cos = 2 sin – 2 cos
when wind start blowing in the direction of wave motion then  3cos = sin  tan = 3
velocity of sound = V + uw tan = 3tan.
t c gok rjax d h fn'kk esapy uk izkjEHk gksxh rc /ofu d k osx = V + uw 72. The spring pulls both the blocks with same force. Hence force
V  uw V  uw on both blocks is equal and opposite.
so apparent wave length  1 = = 0 since no net external force acts on system and its initial momen-
n V
tum is zero, therefore net momentum of system is always zero.
V  uw V  uw Hence momentum of blocks are equal and opposite.
vr%vkHkklhrjaxnS/;Z 1 = = 0 fLizax nksuksaCy kWd ksad ksl eku cy l s[khap rh gSA bl fy ;snksuksaCy kWd ks
n V
ij cy cjkcj rFkk foijhr gSA
70. Find the parameters and put in the general wave equation. pw¡fd fud k; ij d ksbZusV ckº; cy d k;Zugh d jrk gSv kSj bl d k
Here, A = 2 cm
izkjfEHkd l aosx 'kwU; gS] bl fy ;sfud k; d k usV l aosx ges'kk 'kwU;
direction = +ve x direction
v = 128 ms–1 and 5 = 4
gksxkA bl fy ;sCy kWd ksad k l aosx cjkcj rFkk foijhr gSA
2  2  5 73. In a static fluid, pressure remains same at the same level, ie,
Now, k= = = 7.85 pressure do not vary with x-coordinate.
 4
74. P = (2h)g

and v = = 128 ms–1   = v × k = 128 × 7.85 = 1005 F
k
A2 =  (2h) g
As, y = A sin (kx – t)
 y = 2sin (7.85 x – 1005 t) F = 2h g A 2
= (0.02)m sin (7.85 x – 1005 t)
ANSWER KEY
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans. 2 1 2 1 3 1 1 2 1 1

Q. No. 11 12 13 14 15 16 17 18 19 20

Ans. 1 3 2 2 1 3 3 2 1 3

Q. No. 21 22 23 24 25 26 27 28 29 30
Ans. 1,3 1,2,4 1 1,2,3,4 1,3,4 4 2 2 1 1
Q. No. 31 32 33 34 35 36 37 38 39 40

Ans. 2 2 4 4 4 3 3 3 3 1

Q. No. 41 42 43 44 45 46 47 48 49 50
Ans. 1 3 3 3 2 2, 3 1, 2 1,3,4 1, 3 3, 4

Q. No. 51 52 53 54 55 56 57 58 59 60

Ans. 3 1 3 1 4 3 2 3 2 1

Q. No. 61 62 63 64 65 66 67 68 69 70

Ans. 2 2 4 3 3 1 2 2 2 4

Q. No. 71 72 73 74 75
Ans. 1,4 3,4 1.3 1,3,4 1,2,3

RESONANCE Sol. - XI - 5