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IUPAC name[hide]
dihydrogen dioxide
Other names[hide]
Dioxidane
Identifiers
CAS number 7722-84-1
PubChem 784
ChemSpider 763
UNII BBX060AN9V
EC number 231-765-0
2015 (>60% soln.)
UN number 2014 (20–60% soln.)
2984 (8–20% soln.)
KEGG D00008
ChEMBL CHEMBL71595
IUPHAR ligand 2448
MX0900000 (>90% soln.)
RTECS number
MX0887000 (>30% soln.)
SMILES
[show]
InChI
[show]
Properties
Molecular formula H2O2
Molar mass 34.0147 g/mol
Very light blue color; colorless in
Appearance
solution
1.110 g/cm3 (20 °C, 30-percent)
Density
1.450 g/cm3 (20 °C, pure)
Melting point -0.43 °C, 273 K, 31 °F
Boiling point 150.2 °C, 423 K, 302 °F
Solubility in water Miscible
Solubility soluble in ether
Acidity (pKa) 11.62 [1]
Refractive index (nD) 1.34
Viscosity 1.245 cP (20 °C)
Dipole moment 2.26 D
Thermochemistry
Std enthalpy of
-4.007 kJ/g
formation ΔfHo298
Specific heat capacity, 1.267 J/g K (gas)
C 2.619 J/g K (liquid)
Hazards
MSDS ICSC 0164 (>60% soln.)
EU Index 008-003-00-9
Oxidant (O)
EU classification Corrosive (C)
Harmful (Xn)
R-phrases R5, R8, R20/22, R35
(S1/2), S17, S26, S28, S36/37/39,
S-phrases
S45
0
NFPA 704 3
2
OX
Flash point Non-flammable
LD50 1518 mg/kg
Related compounds
Water
Ozone
Related compounds
Hydrazine
Hydrogen disulfide
(what is this?) (verify)
Except where noted otherwise, data are given for materials in
their standard state (at 25 °C, 100 kPa)
Infobox references
Contents
[hide]
• 9 External links
Despite the fact that the O-O bond is a single bond, the molecule has a high barrier to
complete rotation of 29.45 kJ/mol (compared with 12.5 kJ/mol for the rotational barrier
of ethane). The increased barrier is attributed to repulsion between one lone pair and
other lone pairs. The bond angles are affected by hydrogen bonding, which is relevant to
the structural difference between gaseous and crystalline forms; indeed a wide range of
values is seen in crystals containing molecular H2O2.
[edit] Comparison with analogues
Analogues of hydrogen peroxide include the chemically identical deuterium peroxide and
hydrogen disulfide.[4] Hydrogen disulfide has a boiling point of only 70.7°C despite
having a higher molecular weight, indicating that hydrogen bonding increases the boiling
point of hydrogen peroxide.
The properties of aqueous solutions of hydrogen peroxide differ from those of the neat
material, reflecting the effects of hydrogen bonding between water and hydrogen
peroxide molecules. Hydrogen peroxide and water form a eutectic mixture, exhibiting
freezing-point depression. Whereas pure water melts and freezes at approximately 273K,
and pure hydrogen peroxide just 0.4K below that, a 50% (by volume) solution melts and
freezes at 221 K.[5]
[edit] pH of H2O2
Pure hydrogen peroxide has a pH of 6.2, making it a weak acid. The pH can be as low as
4.5 when diluted at approximately 60%.[6]
[edit] History
Hydrogen peroxide was first isolated in 1818 by Louis Jacques Thénard by reacting
barium peroxide with nitric acid.[7] An improved version of this process used
hydrochloric acid, followed by sulfuric acid to precipitate the barium sulfate byproduct.
Thénard's process was used from the end of the 19th century until the middle of the 20th
century.[8] Modern production methods are discussed below.
For a long time, pure hydrogen peroxide was believed to be unstable, because attempts to
separate the hydrogen peroxide from the water, which is present during synthesis, failed.
This instability was however due to traces of impurities (transition metals salts) that
catalyze the decomposition of the hydrogen peroxide. One hundred percent pure
hydrogen peroxide was first obtained through vacuum distillation by Richard
Wolffenstein in 1894.[9] At the end of 19th century, Petre Melikishvili and his pupil L.
Pizarjevski showed that of the many proposed formulas of hydrogen peroxide, the correct
one was H-O-O-H.
The use of H2O2 sterilization in biological safety cabinets and barrier isolators is a
popular alternative to ethylene oxide (EtO) as a safer, more efficient decontamination
method. H2O2 has long been widely used in the pharmaceutical industry. In aerospace
research, H2O2 is used to sterilize artificial satellites and space probes.
The U.S. FDA has recently granted 510(k) clearance to use H2O2 in individual medical
device manufacturing applications. EtO criteria outlined in ANSI/AAMI/ISO 14937 may
be used as a validation guideline. Sanyo was the first manufacturer to use the H2O2
process in situ in a cell culture incubator, which is a faster and more efficient cell culture
sterilization process[citation needed].
[edit] Manufacture
Formerly, hydrogen peroxide was prepared by the electrolysis of an aqueous solution of
sulfuric acid or acidic ammonium bisulfate (NH4HSO4), followed by hydrolysis of the
peroxodisulfate ((SO4)2)2− that is formed. Today, hydrogen peroxide is manufactured
almost exclusively by the autoxidation of a 2-alkyl anthrahydroquinone (or 2-alkyl-9,10-
dihydroxyanthracene) to the corresponding 2-alkyl anthraquinone in the so called
anthraquinone process. Major producers commonly use either the 2-ethyl or the 2-amyl
derivative. The cyclic reaction depicted below shows the 2-ethyl derivative, where 2-
ethyl-9,10-dihydroxyanthracene (C16H14O2) is oxidized to the corresponding 2-
ethylanthraquinone (C16H12O2) and hydrogen peroxide. Most commercial processes
achieve this by bubbling compressed air through a solution of the anthracene, whereby
the oxygen present in the air reacts with the labile hydrogen atoms (of the hydroxy
group), giving hydrogen peroxide and regenerating the anthraquinone. Hydrogen
peroxide is then extracted and the anthraquinone derivative is reduced back to the
dihydroxy (anthracene) compound using hydrogen gas in the presence of a metal catalyst.
The cycle then repeats itself.[10][11]
This process is known as the Riedl-Pfleiderer process,[11] having been first discovered by
them in 1936. The overall equation for the process is deceptively simple:[10]
H2 + O2 → H2O2
The economics of the process depend heavily on effective recycling of the quinone
(which is expensive) and extraction solvents, and of the hydrogenation catalyst.
In 1994, world production of H2O2 was around 1.9 million tonnes and grew to 2.2 million
in 2006,[12] most of which was at a concentration of 70% or less[citation needed]. In that year
bulk 30% H2O2 sold for around US $0.54 per kg, equivalent to US $1.50 per kg (US
$0.68 per lb) on a "100% basis[citation needed]".
A novel electrochemical process for the production of alkaline hydrogen peroxide has
been developed by Dow. The process employs a monopolar cell to achieve an electrolytic
reduction of oxygen in a dilute sodium hydroxide solution.[13]
[edit] Availability
2 H2O2 → 2 H2O + O2
This process is thermodynamically favorable. It has a ΔHo of −98.2 kJ·mol−1 and a ΔGo of
−119.2 kJ·mol−1 and a ΔS of 70.5 J·mol−1·K−1. The rate of decomposition is dependent on
the temperature and concentration of the peroxide, as well as the pH and the presence of
impurities and stabilizers. Hydrogen peroxide is incompatible with many substances that
catalyse its decomposition, including most of the transition metals and their compounds.
Common catalysts include manganese dioxide, silver, and platinum.[17] The same reaction
is catalysed by the enzyme catalase, found in the liver, whose main function in the body
is the removal of toxic byproducts of metabolism and the reduction of oxidative stress.
The decomposition occurs more rapidly in alkali, so acid is often added as a stabilizer.
The liberation of oxygen and energy in the decomposition has dangerous side-effects.
Spilling high concentrations of hydrogen peroxide on a flammable substance can cause
an immediate fire, which is further fueled by the oxygen released by the decomposing
hydrogen peroxide. High test peroxide, or HTP (also called high-strength peroxide) must
be stored in a suitable,[citation needed] vented container to prevent the buildup of oxygen gas,
which would otherwise lead to the eventual rupture of the container.
In the presence of certain catalysts, such as Fe2+ or Ti3+, the decomposition may take a
different path, with free radicals such as HO· (hydroxyl) and HOO· being formed. A
combination of H2O2 and Fe2+ is known as Fenton's reagent.
A common concentration for hydrogen peroxide is 20-volume, which means that, when 1
volume of hydrogen peroxide is decomposed, it produces 20 volumes of oxygen. A 20-
volume concentration of hydrogen peroxide is equivalent to 1.667 mol/dm3 (Molar
solution) or about 6%.
In acidic solutions, H2O2 is one of the most powerful oxidizers known—stronger than
chlorine, chlorine dioxide, and potassium permanganate. Also, through catalysis, H2O2
can be converted into hydroxyl radicals (.OH), which are highly reactive.
Other examples of hydrogen peroxide's action as a reducing agent are reaction with
sodium hypochlorite or potassium permanganate, which is a convenient method for
preparing oxygen in the laboratory.
Hydrogen peroxide is a weak acid, and it can form hydroperoxide or peroxide salts or
derivatives of many metals.
It can also produce peroxoanions by reaction with anions; for example, reaction with
borax leads to sodium perborate, a bleach used in laundry detergents:
H2O2 converts carboxylic acids (RCOOH) into peroxy acids (RCOOOH), which are
themselves used as oxidizing agents. Hydrogen peroxide reacts with acetone to form
acetone peroxide, and it interacts with ozone to form hydrogen trioxide, also known as
trioxidane. Reaction with urea produces carbamide peroxide, used for whitening teeth.
An acid-base adduct with triphenylphosphine oxide is a useful "carrier" for H2O2 in some
reactions.
[edit] Alkalinity
Hydrogen peroxide can still form adducts with very strong acids. The superacid HF/SbF5
forms unstable compounds containing the [H3O2]+ ion.
[edit] Uses
[edit] Industrial applications
ISO tank container for hydrogen peroxide transportation.
About 50% of the world's production of hydrogen peroxide in 1994 was used for pulp-
and paper-bleaching.[12] Other bleaching applications are becoming more important as
hydrogen peroxide is seen as an environmentally benign alternative to chlorine-based
bleaches.
Other major industrial applications for hydrogen peroxide include the manufacture of
sodium percarbonate and sodium perborate, used as mild bleaches in laundry detergents.
It is used in the production of certain organic peroxides such as dibenzoyl peroxide, used
in polymerisations and other chemical processes. Hydrogen peroxide is also used in the
production of epoxides such as propylene oxide. Reaction with carboxylic acids produces
a corresponding peroxy acid. Peracetic acid and meta-chloroperoxybenzoic acid
(commonly abbreviated mCPBA) are prepared from acetic acid and meta-chlorobenzoic
acid, respectively. The latter is commonly reacted with alkenes to give the corresponding
epoxide.
In the PCB manufacturing process, hydrogen peroxide mixed with sulfuric acid was used
as the microetch chemical for copper surface roughening preparation.
Recently, there has been increased use of vaporized hydrogen peroxide in the validation
and bio-decontamination of half-suit and glove-port isolators in pharmaceutical
production.
Nuclear pressurized water reactors (PWRs) use hydrogen peroxide during the plant
shutdown to force the oxidation and dissolution of activated corrosion products deposited
on the fuel. The corrosion products are then removed with the cleanup systems before the
reactor is disassembled.
Hydrogen peroxide is also used in the oil and gas exploration industry to oxidize rock
matrix in preparation for micro-fossil analysis.
A method of producing propylene oxide from hydrogen peroxide has been developed.
The process is claimed to be environmentally friendly, since the only significant
byproduct is water. It is also claimed the process has significantly lower investment and
operating costs. Two of these "HPPO" (hydrogen peroxide to propylene oxide) plants
came onstream in 2008: One of them located in Belgium is a Solvay, Dow-BASF joint
venture, and the other in Korea is a EvonikHeadwaters, SK Chemicals joint venture. A
caprolactam application for hydrogen peroxide has been commercialized. Potential routes
to phenol and epichlorohydrin utilizing hydrogen peroxide have been postulated.[13]
[edit] Biological function
Hydrogen peroxide is also one of the two chief chemicals in the defense system of the
bombardier beetle, reacting with hydroquinone to discourage predators.
A study published in Nature found that hydrogen peroxide plays a role in the immune
system. Scientists found that hydrogen peroxide is released after tissues are damaged in
zebra fish, which is thought to act as a signal to white blood cells to converge on the site
and initiate the healing process. When the genes required to produce hydrogen peroxide
were disabled, white blood cells did not accumulate at the site of damage. The
experiments were conducted on fish; however, because fish are genetically similar to
humans, the same process is speculated to occur in humans. The study in Nature
suggested asthma sufferers have higher levels of hydrogen peroxide in their lungs than
healthy people, which could explain why asthma sufferers have inappropriate levels of
white blood cells in their lungs.[19][20]
• Diluted H2O2 (between 3% and 8%) is used to bleach human hair when mixed
with ammonium hydroxide, hence the phrase "peroxide blonde".
• It is absorbed by skin upon contact and creates a local skin capillary embolism
that appears as a temporary whitening of the skin.
• It is used to whiten bones that are to be put on display.
• 3% H2O2 is used medically for cleaning wounds, removing dead tissue, and as an
oral debriding agent. Peroxide stops slow (small vessel) wound bleeding/oozing,
as well. However, recent studies have suggested that hydrogen peroxide impedes
scarless healing as it destroys newly formed skin cells.[21] Most over-the-counter
peroxide solutions are not suitable for ingestion.
• If a dog has swallowed a harmful substance (e.g., rat poison), small amounts of
hydrogen peroxide can be given to induce vomiting.[22]
• 35% hydrogen peroxide is used to prevent infection transmission in the hospital
environment, hydrogen peroxide vapor is registered with the US EPA as a
sporicidal sterilant.
• 3% H2O2 is effective at treating fresh (red) blood-stains in clothing and on other
items. It must be applied to clothing before blood stains can be accidentally "set"
with heated water. Cold water and soap are then used to remove the peroxide
treated blood.
• The United States Food and Drug Administration (FDA) has classified hydrogen
peroxide as a Low Regulatory Priority (LRP) drug for use in controlling fungus
on fish and fish eggs. (See ectoparasite.)
• Some horticulturalists and users of hydroponics advocate the use of weak
hydrogen peroxide solution in watering solutions. Its spontaneous decomposition
releases oxygen that enhances a plant's root development and helps to treat root
rot (cellular root death due to lack of oxygen) and a variety of other pests.[23][24]
There is some peer-reviewed academic research to back up some of the claims.[25]
• Laboratory tests conducted by fish culturists in recent years have demonstrated
that common household hydrogen peroxide can be used safely to provide oxygen
for small fish.[26][27] Hydrogen peroxide releases oxygen by decomposition when it
is exposed to catalysts such as manganese dioxide.
• Hydrogen peroxide is a strong oxidizer effective in controlling sulfide and
organic-related odors in wastewater collection and treatment systems. It is
typically applied to a wastewater system where there is a retention time of 30
minutes to 5 hours before hydrogen sulfide is released. Hydrogen peroxide
oxidizes the hydrogen sulfide and promotes bio-oxidation of organic odors.
Hydrogen peroxide decomposes to oxygen and water, adding dissolved oxygen to
the system, thereby negating some Biochemical Oxygen Demand (BOD).
• Mixed with baking soda and a small amount of hand soap, hydrogen peroxide is
effective at removing skunk odor.[28]
• Hydrogen peroxide is used with phenyl oxalate ester and an appropriate dye in
glow sticks as an oxidizing agent. It reacts with the ester to form an unstable CO2
dimer, which excites the dye to an excited state; the dye emits a photon (light)
when it spontaneously relaxes back to the ground state.
• Hydrogen peroxide can be combined with vinegar and table salt to form a
substitute for industrial chemicals such as ferric chloride, ammonium persulfate,
or hydrochloric acid as a hobbyist's printed circuit board etchant.[29]
High concentration H2O2 is referred to as HTP or High test peroxide. It can be used either
as a monopropellant (not mixed with fuel) or as the oxidizer component of a bipropellant
rocket. Use as a monopropellant takes advantage of the decomposition of 70–98+%
concentration hydrogen peroxide into steam and oxygen. The propellant is pumped into a
reaction chamber where a catalyst, usually a silver or platinum screen, triggers
decomposition, producing steam at over 600 °C, which is expelled through a nozzle,
generating thrust. H2O2 monopropellant produces a maximum specific impulse (Isp) of
161 s (1.6 kN·s/kg), which makes it a low-performance monopropellant. Peroxide
generates much less thrust than hydrazine, but is not toxic. The Bell Rocket Belt used
hydrogen peroxide monopropellant.
In the 1940s and 1950s, the Walter turbine used hydrogen peroxide for use in submarines
while submerged; it was found to be too noisy and require too much maintenance
compared to diesel-electric power systems. Some torpedoes used hydrogen peroxide as
oxidizer or propellant, but this was dangerous and has been discontinued by most navies.
Hydrogen peroxide leaks were blamed for the sinkings of HMS Sidon and the Russian
submarine Kursk. It was discovered, for example, by the Japanese Navy in torpedo trials,
that the concentration of H2O2 in right-angle bends in HTP pipework can often lead to
explosions in submarines and torpedoes. SAAB Underwater Systems is manufacturing
the Torpedo 2000. This torpedo, used by the Swedish navy, is powered by a piston engine
propelled by HTP as an oxidizer and kerosene as a fuel in a bipropellant system.[30]
While rarely used now as a monopropellant for large engines, small hydrogen peroxide
attitude control thrusters are still in use on some satellites. They are easy to throttle, and
safer to fuel and handle before launch than hydrazine thrusters. However, hydrazine is
more often used in spacecraft because of its higher specific impulse and lower rate of
decomposition.
Hydrogen peroxide has been used as an antiseptic and anti-bacterial agent for many years
due to its oxidizing effect. While its use has decreased in recent years with the popularity
of readily available over the counter products, it is still used by many hospitals, doctors
and dentists.
• Like many oxidative antiseptics, hydrogen peroxide causes mild damage to tissue
in open wounds, but it also is effective at rapidly stopping capillary bleeding
(slow blood oozing from small vessels in abrasions), and is sometimes used
sparingly for this purpose, as well as cleaning.
• Hydrogen peroxide can be used as a toothpaste when mixed with correct
quantities of baking soda and salt.[32]
• Hydrogen peroxide and benzoyl peroxide are sometimes used to treat acne.[33]
• Hydrogen peroxide is used as an emetic in veterinary practice.[34]
Alternative uses
• The American Cancer Society states that "there is no scientific evidence that
hydrogen peroxide is a safe, effective or useful cancer treatment", and advises
cancer patients to "remain in the care of qualified doctors who use proven
methods of treatment and approved clinical trials of promising new treatments."
[35]
• Another controversial alternative medical procedure is inhalation of hydrogen
peroxide at a concentration of about 1%. Intravenous usage of hydrogen peroxide
has been linked to several deaths.[36][37]
• See also Liquid Oxygen (supplement)
Hydrogen peroxide was the main ingredient in the 7 July 2005 London bombings that
killed 52 London Underground and bus passengers. The bomb-making ingredients are
reported to be easier to buy than large numbers of aspirin pills.[38]
[edit] Safety
Regulations vary, but low concentrations, such as 3%, are widely available and legal to
buy for medical use. Higher concentrations may be considered hazardous and are
typically accompanied by a Material Safety Data Sheet (MSDS). In high concentrations,
hydrogen peroxide is an aggressive oxidizer and will corrode many materials, including
human skin. In the presence of a reducing agent, high concentrations of H2O2 will react
violently.
Hydrogen peroxide should be stored in a cool, dry, well-ventilated area and away from
any flammable or combustible substances.[39] It should be stored in a container composed
of non-reactive materials such as stainless steel or glass (other materials including some
plastics and aluminium alloys may also be suitable).[40] Because it breaks down quickly
when exposed to light, it should be stored in an opaque container, and pharmaceutical
formulations typically come in brown bottles that filter out light.[41]
Hydrogen peroxide, either in pure or diluted form, can pose several risks:
[edit] References
[edit] Notes
[edit] Bibliography
Sodium hydroxide
From Wikipedia, the free encyclopedia
Sodium hydroxide
IUPAC name[hide]
Sodium hydroxide
Systematic name[hide]
Sodium oxidanide
Other names[hide]
Caustic soda
Lye
Identifiers
PubChem 14798
ChemSpider 14114
UNII 55X04QC32I
EC number 215-185-5
UN number 1823
KEGG C12569
MeSH Sodium+hydroxide
ChEBI CHEBI:32145
SMILES
[show]
InChI
[show]
Properties
Boiling point
1388 °C, 1661 K, 2530 °F
Solubility in water 1110 g dm−3 (at 20 °C)
Acidity (pKa) 13
Hazards
EU Index 011-002-00-6
EU classification
C
R-phrases R35
NFPA 704
0
3
1
COR
Related compounds
Lithium hydroxide
Potassium hydroxide
Rubidium hydroxide
Except where noted otherwise, data are given for materials in their standard
Pure sodium hydroxide is a white solid available in pellets, flakes, granules, and as a
50% saturated solution. It is hygroscopic and readily absorbs water from the air, so it
should be stored in an airtight container. It is very soluble in water with liberation of
heat. It also dissolves in ethanol and methanol, though it exhibits lower solubility in
these solvents than doespotassium hydroxide. Molten sodium hydroxide is also a
strong base, but the high temperature required limits applications. It is insoluble
in ether and other non-polar solvents. A sodium hydroxide solution will leave a
yellow stain on fabric and paper.
Contents
[hide]
• 1 Properties
• 2 Reactions
• 3 Production
• 4 Uses
o 4.1 pH regulation
• 5 Safety
• 6 See also
• 7 References
• 8 Bibliography
• 9 External links
[edit]Properties
ΔH°dissolution for aqueous dilution is −44.45 kJ / mol; from aqueous solutions at 12.3–
61.8 °C, it crystallizes in monohydrate, with a melting point 65.1 °C and density of
1.829 g/cm3. The standard enthalpy change of formation (ΔH°form) is −734.95 kJ /
mol.
[edit]Reactions
With acids
Sodium hydroxide reacts with protic acids to give water and the corresponding salts.
For example, with hydrochloric acid, sodium chloride is formed:
Sodium hydroxide reacts readily with carboxylic acids to form their salts
and is even a strong enough base to form salts with phenols. It is not,
however, strong enough the quantitatively produce enolates from carbonyl
compounds or deprotonate amines; this would require asuperbase.
[edit]Production
[edit]Uses
[edit]pH regulation
Sodium hydroxide is used in all sorts of
scenarios where it is desirable to increase
the alkalinity of a mixture, or to neutralize
acids.
[edit]Tissue digestion
In a similar fashion, sodium hydroxide is
used to digest tissues, such as in a
process that was used with farm animals
at one time. This process involves the
placing of a carcass into a sealed
chamber, which then puts the carcass in a
mixture of sodium hydroxide and water,
which breaks chemical bonds keeping the
body intact. This eventually turns the body
into a coffee-like[10][11] liquid, and the only
solid that remains are bone hulls, which
could be crushed between one's
fingertips.[12] Sodium hydroxide is
frequently used in the process of
decomposing roadkill dumped in landfills
by animal disposal contractors.[11] Sodium
hydroxide has also been used by
criminals to dispose of their victims'
bodies.[13]
[edit]Dissolving
amphoteric metals
and compounds
Strong bases attack aluminium. Sodium
hydroxide reacts with aluminium and
water to release hydrogen gas. The
aluminium takes the oxygen atom from
sodium hydroxide (NaOH), which in turn
takes the oxygen atom from the water,
and releases the two hydrogen atoms. In
this reaction, sodium hydroxide acts as an
agent to make the solution alkaline, which
aluminium can dissolve in. This reaction
can be useful in etching, removing
anodizing, or converting a polished
surface to a satin-like finish, but without
further passivation such
as anodizing oralodining the surface may
become degraded, either under normal
use or in severe atmospheric conditions.
[edit]Cleaning agent
Main article: Cleaning agent
Sodium hydroxide is frequently used as
an industrial cleaning agent where it is
often called "caustic". It is added to water,
heated, and then used to clean the
process equipment, storage tanks, etc. It
can
dissolve grease, oils, fats and protein bas
ed deposits. The sodium hydroxide
solution can also be added surfactants to
stabilize dissolved substances to prevent
redeposition. A sodium hydroxide soak
solution is used as a powerful degreaser
on stainless and glass bakeware. It is also
a common ingredient in oven cleaners.
[edit]Food preparation
Food uses of sodium hydroxide include
washing or chemical peeling
of fruits and vegetables, chocolate and co
coa processing, caramel
coloring production, poultry scalding, soft
drink processing, and thickening ice
cream. Olives are often soaked in sodium
hydroxide to soften them,
while pretzels and German lye rolls are
glazed with a sodium hydroxide solution
before baking to make them crisp. Owing
to the difficulty in obtaining food grade
sodium hydroxide in small quantities for
home use, sodium carbonate is often
used in place of sodium hydroxide.[15]
[edit]Domestic uses
Sodium hydroxide is used in the home as
a drain cleaning agent for clearing
clogged drains. It is distributed as a dry
crystal or as a thick liquid gel. The
chemical mechanism employed is the
conversion of grease to a form of soap.
Soap is water-soluble, and can be
dissolved by flushing with water. This
conversion occurs far more rapidly at high
temperatures, so commercial drain
cleaners may also contain chemicals that
react with water to generate heat. Sodium
hydroxide also decomposes complex
molecules such as the protein that
composeshair. Such drain cleaners (and
their acidic versions) are highly caustic
and should be handled with care.
[edit]Safety
Sub Topics
Chlorine can be prepared by the action of hot concentrated sulphuric acid on a mixture of a chloride salt and
an oxidising agent. Sodium chloride, being the cheapest and the most easily available chloride salt, is used
along with manganese dioxide as the oxidising agent.
A mixture of almost equal quantity of sodium chloride and manganese dioxide is taken in a round bottomed
flask. Concentrated sulphuric acid is then poured through the thistle funnel. The reaction takes place in two
stages. In the first stage sulphuric acid reacts with the chloride to form hydrochloric acid. In the second stage
the hydrochloric acid so formed combines with the oxidising agent to liberate chlorine.
(1)
(2) Manganese (II) chloride, formed during the reaction, reacts with sulphuric acid to form manganese (II)
sulphate and hydrochloric acid as under:
From Bleaching Powder [Ca(OCl)Cl]
Back to Top
Chlorine can be prepared by removing the hydrogen from hydrochloric acid using an oxidizing agent. Any
oxidising agent such as manganese dioxide, lead dioxide, trilead tetroxide, potassium permanganate or
potassium dichromate can be used. Firstly, the oxidising agents are taken in the round bottomed flask.
Concentrated hydrochloric acid is then added through a thistle funnel. This mixture is then heated. The
oxygen of the oxidizing agents combines with the hydrogen of the hydrochloric acid leaving behind chlorine
i.e. hydrogen is removed from hydrochloric acid. The metallic ions of the oxidising agents combine with part
of chlorine to form the respective chlorides.
Remember:-
No heating is required in when potassium permanganate is used as an oxidizing agent in the above method
of preparing chlorine.
The chorine produced from hydrochloric acid by the above method, is passed through two wash
bottles. The first wash bottle contains water, to remove traces of hydrogen chloride gas from
chlorine. The second wash bottle contains concentrated sulphuric acid to dry the gas.
Industrial Preparation of Chlorine
Back to Top
Chlorine is mostly obtained as a by-product during the manufacture of caustic soda, by the
electrolysis of brine or molten sodium chloride. Hence chlorine is rather prepared by cheap
methods. During this electrolysis, chlorine is liberated at the anode.
Remember:-