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Oleochemicals should
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Page 1Oleochemicals
of 6 is a trading name of Croda Chemicals Ltd, Croda Leek Ltd and Croda Universal Ltd07/01 V121/0
1.0 Introduction
Many commonly used sequestering agents such as NTA, EDTA and phosphorus derivatives
are becoming increasingly undesirable in industrial formulations due to safety and
environmental issues. NTA is non-biodegradable and difficult to handle. EDTA is a
suspected carcinogen and banned from use in certain countries eg Germany. The use of
phosphates and phosphonates is also of concern due to their accumulation in the
environment.
They were tested at pH 7 upwards and at different caustic concentrations for Iron
sequestration and at different caustic concentrations for Calcium sequestration.
2.0 Results
400
350
300
250
'As is'
200
'100% basis'
150
100
50
0
A300 AB85 B95 EDTA NTA SH PPA DPA
3+
Comparison of Fe sequestration power at 2% NaOH
250
200
150
'As is'
'100% basis'
100
50
0
A300 AB85 B95 EDTA NTA SH PPA DPA
120
100
80
'As is'
60
'100% basis'
40
20
0
A300 AB85 B95 EDTA NTA SH PPA DPA
3+
Comparison of Fe sequestration power at pH7
70
60
50
40
'As is'
'100% basis'
30
20
10
0
A300 AB85 B95 EDTA NTA SH PPA DPA
Calcium sequestration is measured as the amount (in grams) of CaCO3 sequestered per
100g test compound.
140
120
100
80
'As is'
'100% basis'
60
40
20
0
A300 AB85 B95 EDTA NTA SH PPA DPA
80
70
60
50
'As is'
40
'100% basis'
30
20
10
0
A300 AB85 B95 EDTA NTA SH PPA DPA
60
50
40
'As is'
30
'100% basis'
20
10
0
A300 AB85 B95 EDTA NTA SH PPA DPA