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E – NOTES
(i)Physical impurities
(a) Suspended impurities
(b) Colloidal impurities
(ii) Chemical impurities
(a) Dissolved salts
(b)Dissolved gases
(iii) Bacterial impurities
Boiler feed water
The water fed into the boiler for the production of steam is called boiler
feed water.
Requirements
Boiler feed water should be free from turbidity, oil, dissolved gases,
alkali and hardness causing substances.
Hard water:
Which does not produce lather with soap soln,but produce white
ppt(scum) is called hard watetr.
Soft water:
Which produce lather readily with soap soln is called soft water.
Absence of Ca&Mg salts.
Types of hardness:
1.Temporary hardness
2.permanent hardness
Units of hardnss:
1ppm=1mg/lit=0.10Fr=0.070cl
Alkalinity determination:
PRINCIPLE
Potentiometric methods
Using pH meter
A known volume of water sample is titrated against std. HCl using first
phenolphthalein indicator till end-point (P) and the titration is
continued without break using methyl orange indicator till the
equivalence end-point (M).
(Mixture of OH- & HCO3-are not listed since they do not exist
together and are considered equivalent to CO32-).
PROCEDURE
TITRATION – I
STANDARDISATION OF HCl
TITRATION – II
(CH2COOH )2N-CH2-CH2-N(CH2COOH)2
Principle:
TITRATION – II
Pipette out 20ml of sample hard water into a clean conical flask.
Add 5ml of buffer solution and 4 -5 drop of eriochrome black T
indicator. Titrate the wine red coloured solution with EDTA from the
burette until the colour steel blue appears at the end point. Repeat
the titration for concordant values. Let the titre value be V2ml.
TITRATION – III
Take 250ml of hard water sample in a 250ml beaker and boil gently
for about 20 minutes. Cool, filter it into a 250ml standard flask and
make the volume upto the mark. Take 20ml of this solution and
proceed it in the same way as in titration (I). The volume of EDTA
consumed corresponds to the permanent hardness of the water
sample. Let the titre value be V3ml. Temporary hardness is
calculated by subtracting permanent hardness from total hardness.
=ppm
Screening:
Aeration:
Coagulation:
Al2(SO4)3+6H2O→Al(OH)3↓+3H2SO4
Filtration :
Sterilization(or)disinfection:
By boiling:
Water boiled for 10-15minitues all the harmful bacteria are
killed and the water becomes safe for use.
By ozonation
O3→O2+[O]
By using UV radiation
Cl2+H2O→HCl+HOCl
Cl2+NH3→ClNH2+HCl
ClNH2+H2O→HOCl+NH3
CaOCl2+H2O→Ca(OH)2+Cl2
Cl2+H2O→HCl+HOCl
1.bacterias
2.organic impurities
The water feed into the boiler fo the production of steam is called
boiler feed water
2.priming&foaming
3.caustic embrittlement
4.boiler corrosion
Sludge: if the ppt is loose and slimy it is called sludge .sludge are
formed by substances like mgcl2,mgso4,cacl2
Priming&foaming:
Caustic embrittlement:
Na2co3+H2O→2NaOH+CO2
Fe+2NaOH→Na2Feo2+H2↑
Boiler corrosion:
1.Dissolved o2
2.Dissolved CO2
3.Dissolved salts
4Fe+6H2O+3O2→4Fe(OH)3
2Na2SO3+O2→2Na2SO4
N2H4+O2→N2+2H2O
CO2+H2O→H2CO3
2NH4OH+CO2→ (NH4)2CO3+H2O
MgCl2+2H2O→Mg(OH)2+2HCl
Fe+2HCl→FeCl2+H2↑
Softening(or)conditioning method:
1.External conditioning
2.Internal conditioning
External conditioning:
Cation exchanger:
Anion exchanger
RH2+CaCl2→RCa+2HCl
RH2+mgso4→Rmg+H2SO4
RH+NaCl→RNa+HCl
Regeneration:
RCa+2HCl→RH2+CaCL2
RNa+HCl→RH+NaCl
R’Cl2+2NaOH→R’(OH)2+2NaCl
CaSO4+Na2CO3→CaCO3+Na2SO4
3CaSO4+2Na3po4→Ca3(po4)2
2Caso4+Na2[Na4(po3)6+→Na2[Ca2(PO3)6]+2Na2SO4
Zeolite process:
Hard water contains Ca2+&Mg2+ ions this ions form hard soap
(in soluble)with soap which does not produce lather with soap soln.
Process:
Sodium ions with Ca2+ and Mg 2+ ions present in the water to form Ca
and Mg ions present in the water.
Ca(HCO3)+Na2Ze→ CaZe+2NaHCO3
Mg (HCO3)+Na2Ze→ MgZe+2NaHCO3
Regeneration:
CaZe+2Na+Cl-→Na2Ze+CaCi2
Reverse osmosis(RO)
Advantages:
POLYMER
Monomers:
nCH2=CH2→ …(-CH2-CH2-) n
Ethylene Polyethylene
Monomer:
EX:
Polymerization
Degree of polymerization:
3CH2=CH2→-CH2-CH2-CH2-CH2-CH2-CH2-
Tacticity:
Functionality:
1.bifunctional monomer
2.Trifunctional monomer
3.polyfunctional monomer
…..-M-M-M-M-M-M-M-M-M-M-M….
Copolymer (Heteropolymer) :
-M1-M2-M1-M2-M1-M2-M1
ethylene polyethylene
cl
Bifunctional monomer
|
CN
Condensation polymerization
It is a reaction between simple polar groups containing
monomer with the formation of polymer and elimination of small
molecule like H2O
copolymerization:
| |
C6 H5 C6 H 5
Plastics
Classification of plastics:
Thermoplastic resin:
Thermosetting resin
Ex;Bakelite,polyester.
Ex:pvc,Teflon,PET,Nylon 6:6
Cl
Vinylchloride polyvinylchloride
Uses:
Teflon:
n CF2=CF2 → ( -CF2-CF2-) n
Tetrafluroethylene Teflon
Properties:
Uses:
Perlon-U:
O=C=N-(CH2)-N=C=O + HO-(CH2)4-OH
↓polymerisation
n [-O=C-HN-(CH2)6-NH-COO-(CH2)4-OH ]
( perlon-U)
Properties:
It is less stable than polyamide.
Uses:
Nylon 6:6
n H2N-(CH2)-NH2 + nHOOC-(CH2)4-COOH
[-HN-(CH2)6-NHCO-(CH2)4-CO-]n
Nylon6:6
Properties:
Uses:
1.Nylon 6:6 are used for making filaments for ropes ,bristles for
tooth b rushes etc.
2.Nylon 6:6 is used for fibres,which is used in making
socks,carpets.etc
Preparation
Properties
The fibres posses high stretch resistance ,high –crease and wrinkle
resistance.
Uses
It is used for blending with wool,to provide better crease and wrinkle
resistance.
Bakelite
Step 1
Methylolation
Stepii
Further heating of A stage resin (or)B stage resin (or) both in the
presence of a curing agent produces hard ,rigd ,cross –linked
polymer called Bakelite.
Properties
Uses
Bakelite is used as an adhesive in plywood lamination and in grinding
wheelsw ,etc.
Preparation
Properties
Uses
Compounding of plastics:
Moulding process:
Injection moulding:
This method is mainly applicable to thermoplastic .the powdered
plastic material is fed into the heated cylinder through the hopper .the
plastic material melts under the influence of heat and becomes fluid.
The mould is kept cold to allow the hot plasic to cure and
The most primitive composite materials were straw and mud combined
to form bricks for building construction; the Biblical Book of Exodus
speaks of the Israelites being oppressed by Pharaoh, by being forced to
make bricks without straw being provided. The ancient brick-making
process can still be seen on Egyptian tomb paintings in the Metropolitan
Museum of Art. The most advanced examples perform routinely on
spacecraft in demanding environments. The most visible applications
pave our roadways in the form of either steel and aggregate reinforced
portland cement or asphalt concrete. Those composites closest to our
personal hygiene form our shower stalls and bath tubs made of
fiberglass. Solid surface, imitation granite and cultured marble sinks and
counter tops are widely used to enhance our living experiences.
Isotropic shrinkage,
Inorganic Semicrystalline
abrasion, compression
Particulates Thermoplastics, UP
strength
UNIT II
PART A
1. Define co - polymerization.
2. What are plastics?
3. Difference between thermosetting and thermoplastics. (any four)
4. Write notes on Epoxides.
5. Give any two properties of PC, Polyamide.
6. What is elastomer?
7. Define SBR (or) BUNA – S. and explain the preparation of the same.
8. Define polymer. Give examples.
9. Define monomer. Give examples.
10.What is dead polymer?
11.What are engineering plastics?
12.What is fluon? Mention its uses.
13.What is vulcanization of rubbers?
14.Mention some important uses of SBR.
15.What is the role of fillers in plastics?
16.Draw the structure of Bakelite.
17.What is the function of plasticizers in plastics?
18.Define degree of polymerization.
19.Define oligomers and high polymers.
20.How PVC is prepared?
PART B
1. Differences between addition and condensation polymerization?
The substance which is held on the surface of the solid is called the
adsorbate.
The solid that takes up a gas or a solute from the solution is called
the adsorbent.
Adsorption:
Types of adsorption:
1.physical adsorption
2.chemical adsorption
Physisorption chemisorption
1. spontaneous.
4. Selective process.
Physical adsorption:
1.Naure of gases.
3.pressure of gas
4.Temparature of gas
Nature of gases
Easily liquefiable gases like HCL,NH3 adsorbed more easily than
the permanent gases like H2,O2, etc.,
This is due to (i) Critical temperature (ii) Vander waal’s foreces.
Reversible character
It is a reversible process. The gas adsorbed on a solid can be
removes under reverse conditions of temperature and pressure.
Effect of pressure
Since dynamic equilibrium exists between the adsorbed gas and
the gas in contact with the solid, increases of pressure increases
adsorption and decrease of pressure causes desorption.
Effect of temperature
Physical adsorption:It occurs rapidly at lower temperature and
decreases with increase in temperature.
adsorption increases.
This equation may be derived from the result observed from the above
graph. Thus,
3.The constants K and ‘n’ are not temperature independents, they vary
with temperature.
2.The adsorbed gas layer on the solid surface is only one molecule
thick.
ka
A(g) + M(surface) AM
kd
Let,
At euilibrium
=kaP-ka P
kd +ka P=kaP
(kd+kaP)=kaP
= kaP ------------------------(1)
(kd=kaP)
= (ka/kd)P
1+ (ka/kd)P
= KP ……………….(2)
1+KP
x KP
1+KP
x = K’ KP …………………(4)
1+KP
The equation (4) gives the relation between the amount of gas
adsorbed to the pressure of the gas at constant temperature is known
as Langmuir Adsorption isotherm.
1+KP = K’KP
x
1 + KP = P
K’K K’K x
1 + K P = P
K’K K’K x
Case (I): At low pressure : If the pressure (P) is very low K P term
is negligible, k’k
i.e., 1 K P
K’K K’K
K P 1
K’K K’K
K P = P
(or) x = K’ P0 ……………..(7)
X=K’Pn ………………(8)
APPLICATIONS OF ADSORPTION
1. Activated Charcoal
(a) Gas-Masks - absorb toxic gases.
(b) Remove coloring matter from the sugar solution and the
decoloration in vinegar
exchange resins.
4. Chromatographic analysis
Step :1
Step:2
Step:iii Decomposition of activated complex
Free valencies=12
Desorption of products
The products are desorbed (or) released from the surface. They are
stable.
4.Action of promoters
Creates a porous structure and large internal surface area in the char
due to the removal of adsorbed hydrocarbons and some of the carbon.
These carbons have a diameter of less than 200mesh and are generally
used in purification of liquids.
Properties of Activated Carbon
Eg. Coconut shells, fruit pits, briquette coal yield carbon of this kind.
A fixed – bed column is often used for contacting polluted water or air
with GAC.It can be operated singly, in series or in parallel.Among the
various type two are important.
The water or air is applied to the top of the column and withdrawn
at the bottom. The AC is held in place with an under drain system at the
bottom of the column. Provision for back washing and surface washing
is usually necessary to limit the headless build up due to the removal of
particle material with the carbon column.
Advantage
Disadvantages
Down flow filters may require more frequent back washing because
of the accumulation of suspended materials on the surface of the
contactor.
Plugging of carbon pores may require premature removal of the
carbon for regeneration, thereby decreasing the useful life of the
carbon.
In the upflow columns, the polluted water or air moves upward from
the base of the column .
Advantage:
As the carbon adsorbs organic materials, the apparent density of
the carbon particles increases and encourages migration of the heavier
or spent carbon downward.
Disadvantage
upflow columns may have more carbon fines in the effluent than
downflow columns, because upflow tends to expand, not compress, the
carbon.
Bed expansion allows the fines to escape through passage ways
created by the expanded bed.
2.Using Powdered Activated Carbon (PAC)
In this method PAC is added directly to the effluent coming out from
the various biological treatment processes. In the case of biological-
treatment plant effluent, PAC is added to the effluent in a contacting
basin. After some time, the carbon is allowed to settle at the bottom of
the tank, and the treated water is then removed from the tank.
As a decolourant
In solution purification
In gas masks-to adsorb poisoning gases.
In Air Conditioning-to control odour.
In industrial recovery
Activated carbon adsorbs practically any organic solvent at
about 35 oC and releases it when heated to 120 oC or higher for solvent
recovery.
In odour control :
In soln purification
In gas masks
1.cation exchanger
2.Anion exchanger
Softening(or)conditioning method:
The process of removing hardness producing salts from
water is known as softening(or)conditioning of water.
1.External conditioning
2.Internal conditioning
External conditioning:
Cation exchanger:
1.sulphonated coals.
Anion exchanger:
RH2+CaCl2→RCa+2HCl
RH2+mgso4→Rmg+H2SO4
RH+NaCl→RNa+HCl
Regeneration:
RCa+2HCl→RH2+CaCL2
RNa+HCl→RH+NaCl
R’Cl2+2NaOH→R’(OH)2+2NaCl
CaSO4+Na2CO3→CaCO3+Na2SO4
3CaSO4+2Na3po4→Ca3(po4)2
2Caso4+Na2[Na4(po3)6+→Na2[Ca2(PO3)6]+2Na2SO4
Zeolite process:
Hard water contains Ca2+&Mg2+ ions this ions form hard soap
(in soluble)with soap which does not produce lather with soap soln.
Process:
Sodium ions with Ca2+ and Mg 2+ ions present in the water to form Ca
and Mg ions present in the water.
Ca(HCO3)+Na2Ze→ CaZe+2NaHCO3
Mg (HCO3)+Na2Ze→ MgZe+2NaHCO3
Regeneration:
CaZe+2Na+Cl-→Na2Ze
RH2+CaCl2→RCa+2HCl
Regeneration:
Medical uses:
PART B
2
1H + 1H2 2 He4 + Energy
Nuclear fusion reaction occurs in sun.
Differences between fission and fusion reaction
E = mc2
Where,
C = velocity
m= mass lose
E= energy
BREEDER REACTOR:
A breeder reactor is a nuclear reactor that generates
new fissile or fissionable material at a greater rate than it
consumes such material. These reactors were initially (1940s
and 1960s) considered appealing due to their superior fuel
economy; a normal reactor is able to consume less than 1% of
the natural uranium that begins the fuel cycle, whereas a breeder
can utilize a much greater percentage of the initial fissionable
material, and with re-processing, can use almost all of the initial
fissionable material. Breeders can be designed to utilize thorium,
which is more abundant than uranium. Currently, there is
renewed interest in breeders because they would consume less
natural uranium (less than 3% compared to conventional light-
water reactors), and generate less waste, for equal amounts of
energy, by converting non-fissile isotopes of uranium into
nuclear fuel.
Production of fissile material in a reactor occurs by
neutron irradiation of fertile material, particularly uranium-238
and thorium-232. In a breeder reactor, these materials are
deliberately provided, either in the fuel or in a breeder blanket
surrounding the core, or most commonly in both. Production of
fissile material takes place to some extent in the fuel of all
current commercial nuclear power reactors. Towards the end of
its life, a uranium (not MOX, just uranium) PWR fuel element is
producing more power from the fissioning of plutonium than
from the remaining uranium-235. Historically, in order to be
called a breeder, a reactor must be specifically designed to
create more fissile material than it consumes.
Photo galvanic cell or Solar cell
Definition
(Solar cell)
Uses:
Solar light
WIND ENERGY
Moving air is called wind. Energy recovered from the forces of
wind is called wind energy.
Wind power is the conversion of wind energy into a
useful form, such as electricity, using wind turbines. At the end
of 2008, worldwide nameplate capacity of wind-powered
generators was 121.2 gigawatts (GW). Wind power produces
about 1.5% of worldwide electricity use, and is growing rapidly,
having doubled in the three years between 2005 and 2008.
Large-scale wind farms are typically connected to the local
electric power transmission network; smaller turbines are used
to provide electricity to isolated locations. Utility companies
increasingly buy back surplus electricity produced by small
domestic turbines. Wind energy as a power source is attractive
as an alternative to fossil fuels, because it is plentiful,
renewable, widely distributed, clean, and produces no
greenhouse gas emissions; however, the construction of wind
farms (as with other forms of power generation) is not
universally welcomed due to their visual impact and other
effects on the environment.
Alkaline Battery
Overall reaction:
Lithium Battery
Description
Cell reactions
At anode: Li(s) → Li+ + e-
At cathode: TiS2 + e- → TiS2-
Overall reaction:
Li(s) + TiS2 → Li+ + TiS2-
Other types of secondary lithium batteries
(i) Li/ MnO2
(ii) Li/V2O5
(iii) Li/MoO2
(iv) Li/Cr3O8
Advantages of Li battery
It is the cell future. Why?
Disadvantages of Li battery
Li battery is more expensive than other batteries
Uses
Button sized batteries are used in calculators, watches,
cameras, mobile phones, laptop computers.
Lithium Sulphur Battery
Description
Cell reactions
At anode: Li(s) → Li+ + e-
At cathode: S + 2e- → S2-
Overall reaction:
2Li(s) + S → 2Li+ + S2-
The sulphide ions, formed, react with elemental sulphur to
form the polysulphide ion.
Uses
ABRASIVES
Abrasives are very hard substances used for grinding,
shaping and polishing other materials
PROPERTIES
Have very high melting point
Chemically inert
High abrasive power (ability to scratch away pr sharp other
materials)
Sometimes hard and brittle or soft and flexible
ABRASIVES - TYPES
natural abrasives – Eg. Diamond, corundum
synthetic abrasives – Eg. carborundum, norbide
Hardness is measured in terms of moh’s scale.
-diamond is taken as the reference and hardness of other
materials are determined
-abrasives with moh’s scale 1-4 are called soft abrasives
NATURAL ABRASIVES
Diamond:
o Purest crystalline carbon - Hardest natural substance
o Moh’s scale value is 10 -Superior chemical inertness
o Used in grinding wheels, drilling tools, cutting glasses,
etc
Corundum
Pure crystalline form of alumina - Moh’s scale value is 9 -
Used in grinding glass, gems etc.
Emery
55-75% alumina, 20-40% magnetite, 12% others - Black
and opaque
-Mho’s scale value is 8 - Used for making abrasive paper,
abrasive cloth, etc.
Quartz
Pure silicone - Moh’s scale value is 7 - Used in painting
industries
Garnet
Trisilicates of alumina, magnetite and Fe oxide
Used for the manufacture of abrasive paper and cloth
ARTIFICIAL ABRASIVES
Silicon Carbide (SiC)
Manufacture
Silicon Carbide is manufactured by heating sand (60%)and
coke (40%) with some saw dust and a little salt in an electric
furnace to about 1500°C
SiO2 + 3C SiC + 2CO
The silicon carbide removed from the furnaces, is then mixed
with bonding agent(clay, silicon nitride) and than shaped,
dried and fired.
Properties
1. Silicon carbide posseses a high thermal conductivity, low
expansion and high resistance to abrasion and spalling.
2. They are mechanically strong. Moh’s scale value is 9 .
3. Bear very high temp. 1650°C
4. Has thermal conductivity between metals and ceramics –
They are electrically intermediate between conductors and
insulators.
Uses
1. Silicon carbide are used as heating elements in furnaces
in the form of rods or bars.
2. They are also used for partition wall of chamber kilns,
coke ovens, muffle furnaces and floors of heat
treatment furnaces.
3. Sic bonded with tar are excellent for making high
conductivity crucible.
Uses
It is used as hard materials for making grinding dies, and
for cutting and sharpening hard high speed tools.
It is used to prepare scratch and wear resistant coating.
LUBRICANTS
Substances used to reduce friction between two moving
surfaces
Eg. Grease, oil etc
Lubrication
Lubrication is a process of reducing friction and wears
between two moving surfaces by adding lubricant in between
them.
Functions of a lubricant
Prevents the direct contact between the moving surfaces and
reduce wear, tear and surface deformation
Reduce wastage of energy
Prevents expansion of metals
Acts as coolant between moving surfaces
Acts as sealing agent
Minimizes corrosion
Classification
Liquid lubricants
L-U
V.I. = -------
L–H
U is the viscosity of the test oil at 100 F
L is the viscosity of the low grade oil at 100 F (The low grade oil
should have same viscosity as that of the test oil at 210 F)
H is the viscosity of the high grade oil at 100 F (The high grade
oil should have same viscosity as that of the test oil at 210 F)
Flash and Fire points
Flash point is the lowest temp. at which the oil gives
enough vapour that gets ignited for a moment when a
small flame is brought near it.
Fire point is the lowest temp. at which the vapor of the oil
burns continuously for atleast 5 seconds when a small flame is
brought near it.
A good lubricant should have high flash and fire points than the
operating temp.
Flash and Fire points can be determined by using Pensky
Martin’s apparatus or Cleve land’s apparatus.
Cloud and Pour points
When an oil is cooled, the temp. at which the oil becomes
cloudy is called cloud point
The temp. at which the oil ceases to flow or pour is called pour
point
A good lubricant should have low cloud and pour points
Pour point can be reduced by adding pour point depressant or
by dewaxing process
Oilness
Oilness is the ability of lubricating oil to stick on to the surface
of machinery parts under heavy load or pressure
A good lubricant should have high oilness so that it is not
squeezed out of the machinery parts.
Solid lubricants
Solid lubricants are used under
high operating temp.
contamination by impurities should be avoided
combustion of lubricants should be avoided
Graphite
Graphite consists of flat layers of hexagonal arrangement of
carbon atoms. The carbon atoms are bonded by covalent
bonds and the layers are attached held together by
Vanderwall’s force of attraction. The layers can slide one over
the other easily. This property of graphite makes it a good
lubricant.
(Structure of Graphite)
Graphite can be used up to a temp. of 3750 C. It can
be used as dry powder or colloidal dispersion. Graphite in
water is called aqua dag and that in oil is called oil dag.
Graphite is generally used in internal combustion engines, air
compressors and food processing units. It is also used in
railway tracks, lathes and gears.
Molybdenum di sulphide
Molybdenum di sulphide has a sandwiched structure.
Molybdenum layer is sandwiched between two sulphur layers.
The layers are held together by vanderwaals force of attraction.
The Mo layers slide on the sulphur layers. MoS2 is used under
heavy load and high temp. It can be used up to a temp. of
800 0 C.
Uses
1. Calculate the hardness of a water sample containing 2.4 mg of calcium chloride in 500 ml of
water?
10. What are nano materials? Mention any two of their characteristic properties.
Or
12.i.. What are ion exchange resins? How are they useful in removing hardness of water?
ii. What is desalination? With a neat diagram, describe the 'reverse osmosis' method for the
desalination of brackish water.
14.i. What is natural rubber? Explain why natural rubber needs vulcanization. How is it carried
out?
ii. What are composites? Give the preparation and uses of glass fiber reinforced composites
and carbon fiber reinforced composites.
Or
17.i. Explain with a neat diagram the parts and functions of a nuclear reactor.
ii. Write a note on photovoltaic cell.
Or
Or