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4541/1
CONFIDENTIAL
4541/1
Chemistry
Paper 1
September
2007
1¼ hour
CHEMISTRY
Paper 1
3. Answer each question by blackening the correct space on the answer sheet.
Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan.
5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.
Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat. Kemudian hitamkan
jawapan yang baru.
6. The diagrams in the questions provided are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
A electrons only
elektron sahaja
B neutrons only
neutron sahaja
C both protons and neutrons
proton dan neutron
D both protons and electrons
proton dan electron
3 Which of the following substances has electrostatic forces between its particles?
Manakah antara bahan berikut mempunyai daya tarikan elektrostatik antara zarah?
A Naphthalene
Naftalena
B Carbon dioxide
Karbon dioksida
C Hydrogen chloride
Hidrogen klorida
D Magnesium oxide
Magnesium oksida
A lime
kapur
B sulphur
Sulfur
C zinc nitrate
zink nitrat
D ammonium sulphate
ammonium sulfat
5 Table 1 shows information about the ability of three substances to conduct electricity.
Jadual1 menunjukkan maklumat tentang kebolehan tiga bahan untuk mengalirkan elektrik.
Substance P Q R
Bahan
Electrical conductivity in solid state.
Kekonduksian elektrik dalam keadaan pepejal
√ X X
Electrical conductivity in molten state.
Kekonduksian elektrik dalam keadaan leburan
√ X √
TABLE 1
A Iron(II) sulphate
Ferum(II) sulfat
B Silver chloride
Argentum klorida
C Calcium carbonate
Kalsium karbonat
D Lead(II) bromide
Plumbum(II) bromida
8 Baking powder contains sodium hydrogen carbonate. It reacts with acidic substances
to release
Serbuk penaik mengandungi natrium hidrogen karbonat. Ia bertindak balas dengan bahan berasid
untuk membebaskan
A hydrogen
hidrogen
B nitrogen
nitrogen
C carbon dioxide
karbon dioksida
D nitrogen dioxide
nitrogen dioksida
DIAGRAM 1
A I
B II
C III
D IV
DIAGRAM 2
What is atom X?
Apakah atom X?
A Aluminium
Aluminium
B Zinc
Zink
C Tin
Stanum
D Carbon
Karbon
A Photosynthesis
Fotosintesis
B Rusting of iron
Pengaratan besi
C Combustion of hydrogen in oxygen
Pembakaran hidrogen dalam oksigen
D Combustion of magnesium in oxygen
Pembakaran magnesium dalam oksigen
DIAGRAM 3
DIAGRAM 4
Which of the following alcohol reacts with propanoic acid to produce the above
compound?
Manakah antara alkohol berikut bertindak balas dengan asid propanoik untuk menghasilkan sebatian
di atas?
A B
C D
A hydrogenation
penghidrogenan
B esterification
pengesteran
C neutralization
peneutralan
D fermentation
penapaian
DIAGRAM 5
Which of the following is the structural formula and name for an isomer of but-1-ene?
Manakah antara formula struktur dan nama berikut betul bagi satu isomer but-1-ena?
A B
C D
2-methylprop – 2 – ene
2-methylprop – 2 - ene
H OH OH H
Acidified KMnO4 │ │ │ │
G
H - C - C - C - C - H
KMnO4 berasid │ │ │ │
H H H H
DIAGRAM 6
A n- butane
n-butana
B But - 1 – ene
But-1-ena
C But - 2 – ene
But-2-ena
D Butan - 2 - ol
Butan-2-ol
17 Reaction between ferum(II) sulphate solution and bromine can be represented by the
following equation.
Tindak balas antara ferum(II) sulfat dengan bromin boleh diwakili oleh persamaan berikut.
A Fe2+ is reduced
Fe2+ diturunkan
B Br2 is a reducing agent
Br2 adalah agen penurunan
C Fe2+ is an oxidizing agent
Fe2+ adalah agen pengoksidaan
D Br2 accepts electrons
Br2 menerima elektron
Energy
Tenaga NaOH + HCl
Δ H = -57 kJ mol-1
NaCl + H2O
DIAGRAM 7
Based on Diagram 7 , it can be concluded that
Berdasarkan Rajah 7 dapat disimpulkan bahawa
Type Function
Jenis Fungsi
I Preservative Prevents growth of microorganism in foods
Pengawet Menghalang pembiakan mikroorganisma dalam makanan
II Antioxidant Prevents oxidation of the oil by oxygen
Antioksida Menghalang pengoksidaan minyak oleh oksigen
III Flavouring Enhances the flavour of foods
Perisa Menambahkan rasa dalam makanan
IV Colouring Gives and restores certain colour in foods
Pewarna Memberi dan mengekalkan warna dalam makanan
TABLE 2
Which of the following are correctly matched?
Antara pasangan berikut manakah benar?
A 62
2
B 21
-41
C 190
140
D 130
75
Element
V W X Y Z
Unsur
Number of protons
3 8 10 11 20
Bilangan proton
TABLE 3
Which of the following elements have the same number of valence electrons?
Manakah antara unsur-unsur berikut mempunyai elektron valens yang sama?
A V and Z
B W and X
C V and Y
D W and Z
Element P Q R S
Unsur
Proton number 11 13 16 19
Nombor proton
TABLE 4
The sequence of the elements in the order of increasing atomic size is
Susunan unsur-unsur mengikut pertambahan saiz atom ialah
A S, R, Q, P
B R, Q, P, S
C P, Q, R, S
D S, P, Q, R
DIAGRAM 8
Which of the following equations represents the reaction that occurs in the test tube
containing lime water?
Manakah antara persamaan berikut mewakili tindak balas yang berlaku dalam tabung uji
mengandungi air kapur?
A Silicon dioxide
Silikon dioksida
B Silver chloride
Argentum klorida
C Mercury
Merkuri
D Zinc Sulphate
Zink sulfat
Reaction Formula
Tindak balas Formula
Element X and carbon CX4
Unsur X dan karbon
Element X and sodium NaX
Unsur X dan natrium
TABLE 5
Which of the following represents the electron arrangement for a compound formed
between magnesium and element X?
Manakah antara berikut mewakili susunan elektron bagi sebatian yang terbentuk antara magnesium
dan unsur X?
DIAGRAM 9
DIAGRAM 10
Arrange the steps in the correct order of preparing a standard solution.
Susunkan langkah-langkah mengikut urutan yang betul.
A S, Q, R and P
B S, R, P,and Q
C Q, P, R and S
D P, R, S and Q
Rubber X Rubber Y
DIAGRAM 11
S
Time / s
Masa
DIAGRAM 12
Which of the following solution will produce curve S?
Manakah antara larutan berikut menghasilkan lengkung S?
Molecule A Process II
Molekul A Proses II
A Ethanol Esterification
Etanol Pengesteran
B Ethanol Oxidation
Etanol Pengoksidaan
C Ethene Dehydration
Etena Pendehidratan
D Ethanoic acid Esterification
Asid etanoik Pengesteran
32 Diagram 14 shows the set-up of apparatus to study factors affecting corrosion of iron.
Rajah 14 menunjukkan susunan radas untuk mengkaji faktor mempengaruhi kakisan besi.
DIAGRAM 14
In which of the following test tube will the iron nail rust?
Manakah antara tabung uji berikut akan berlakunya pengaratan paku besi?
A X only
X sahaja
B Y only
Y sahaja
C X and Z only
X dan Z sahaja
D Y and Z only
Y dan Z sahaja
A 2
B 7
C 9
D 14
DIAGRAM 15
The heat of combustion of ethanol was found less than the theoretical value. What can
be done to improve the experimental value?
Haba pembakaran etanol didapati kurang dari nilai teori. Apa yang perlu dilakukan untuk
memperbaiki nilai eksperimen tersebut?
36 Table 6 shows the number of neutrons, protons and electrons of particles R and S.
Jadual 6 menunjukkan bilangan neutron , proton dan elektron bagi zarah R dan S.
37 Metal M forms a chloride compound with the formula MCl3. Given the formula of
chromate (IV) ions is CrO42-, then the formula of M chromate is
Logam M membentuk sebatian klorida yang mempunyai formula MCl3. Diberi formula bagi ion
kromat(IV) adalah CrO4-2, maka formula bagi sebatian M kromat ialah
A MCrO4
B M2CrO4
C M(CrO4)3
D M2(CrO4)3
38 The equation represents the displacement of copper from aqueous copper (II) sulphate
using metal Q.
Persamaan berikut mewakili penyesaran kuprum daripada larutan kuprum(II) sulfat menggunakan
logam Q.
Q + CuSO4 QSO4 + Cu
What is the volume of aqueous 1 mol dm-3 of copper (II) sulphate that reacts
completely with 0.96 g of metal Q?
[Relative atomic mass Q: 24]
Apakah isipadu larutan kuprum(II) sulfat 1 mol dm-3 bertindak balas lengkap dengan 0.96 g logam Q?
[Jisim atom relatif Q : 24]
A 60 cm3
B 40 cm3
C 25 cm3
D 23 cm3
A 23.7%
B 21.9 %
C 21.2 %
D 10.6 %
40 Element X is placed on the right of element Y in the same Period of the Periodic
Table. If the proton number of Y is 12, then the electron arrangement of X is
Unsur X berada di kanan unsur Y pada kala yang sama dalam Jadual Berkala.Unsur.
Jika nombor proton Y adalah 12, maka susunan elektron bagi unsur X ialah
A 2.8.2
B 2.8.6
C 2.8.8.2
D 2.8.8.6
height of precipitate/cm
Tinggi mendakan
5.5
4.4
3.3
2.2
1.1
. . . . . . . .
1 2 3 4 5 6 7 volume of K2SO4 /cm3
isipadu K2SO4
DIAGRAM 16
Diagram 16 shows the graph for height of precipitate against volume of 0.1 mol dm-3
potassium sulphate used.
What is the formula for M sulphate?
Rajah 16 menunjukkan graf tinggi mendakan melawan isipadu larutan kalium sulfat 0.1 mol dm-3.
Apakah formula bagi M sulfat?
A MSO4
B M2SO4
C M2(SO4)3
D M3(SO4)2
M N O
Tendency to lose electron decreases
Kecenderungan melepaskan elektron berkurang
44 Which of the following solutions reacts completely with 40 cm3 of 1.0 mol dm-3
sulphuric acid, H2SO4.
Manakah antara larutan berikut bertindak balas lengkap dengan 40 cm3 asid sulfurik 1.0 mol dm-3?
A I and II only
B I and III only
C II and IV only
D IV only
Diagram 17
Which of the following is solution X?
Manakah antara berikut larutan X?
A Silver nitrate
Argentum nitrat
B Ammonium hydroxide
Ammonium hidroksida
C Zinc chloride
Zink klorida
D Barium hydroxide
Barium hidroksida
46 The following information shows the effect of a particular factor on the rate of
reaction.
Maklumat berikut menunjukkan kesan suatu faktor yang mempengaruhi kadar tindak balas.
DIAGRAM 18
Which of the following graph is possible if the experiment is repeated using 25 cm3 of
0.2 mol dm-3 hydrochloric acid?
Manakah antara graf berikut yang mungkin jika eksperimen diulang menggunakan 25 cm3 asid
hidroklorik 0.2 mol dm-3 ?
A B
C D
DIAGRAM 19
After a few hours, there is no deflection of the galvanometer’s needle. This is because
Selepas beberapa jam, tiada pesongan pada jarum galvanometer. Ini disebabkan
49 The burning of 0.6 g of X causes the temperature of 100 cm3 water to increase by
12oC.
What is the heat of combustion of X?
[ relative molecular mass of X = 60; specific heat capacity of water = 4.2 J g-1 oC-1]
Pembakaran 0.6 gram bahan X menyebabkan suhu 100 cm3 air naik sebanyak 12oC.
Apakah haba pembakaran bagi bahan X?
A 50.4 kJ mol-1
B 72.0 kJ mol-1
C 302.4 kJ mol-1
D 504.0 kJ mol-1
C 100 cm 3 of 1.0 mol dm-3 of sodium hydroxide and 100 cm 3 of 4.0 mol dm-3
hydrochloric acid
3 3
100 cm natrium hidroksida 1.0 mol dm-3 dan 100 cm asid hidrokorik 4.0 mol dm-3
D 200 cm 3 of 1.0 mol dm-3 sodium hydroxide and 200 cm 3 of 1.0 mol dm-3
hydrochloric acid
3 3
200 cm natrium hidroksida 1.0 mol dm-3 dan 200 cm asid hidrokorik 1.0 mol dm-3