Write the net ionic equation of the non-ionized equation stated below balance the equation showing the

complete solution. 1. AgN + ZnC AgC + ZnN

2. NaOH + HN

O + NaN

3. BaS

+N C

BaC

+N S

4. CaC

+ HCl CaC +

O+C

5. PbNO3 + HCI PbCI2 + HNO3

Complete the equation and write the total and net ionic equation of the following equation 6. AI(NO3)3 + NaOH

7. HF + KOH

8. (NH4)2S + Fe(NO3)2

9. NaHCO3 + HNO3

10. CaF2 + MgSO4

11. Which of the following quantum numbers is erroneous? Explain (n=4,1=3,m1=-4,ms= + ,- )

12. What element has the 4f14 as the highest energy electron ? Show the complete electron configuration.

13. What element has the 7p4 as the highest energy electron ? Show the complete electron configuration.

14. Indicate all the possible values for the second quantum number given n=4

15. Indicate all the possible values for the third quantum number given 1=3.

16. Give all the quantum numbers for 4d10 .

17. Give all the quantum numbers for n=5

18. What is the [OH-] if the pH is 3.67?

19. What is the [H4] if the [OH-] = 6.98 x 10-3 ?

20. Calculate the pH of a solution with [H+]= 9.8 x 10-8.

21. Calculate the pOH of a solution with [H+] = 4.97 x 10-6.

22. What is the [OH-] if the [H+] = 4.5 x 10-5?

23. What is the [H+] if the pOH of the solution is 9.12?

24. Illustrate at least one possible Lewis structure for C8H8.

25. Illustrate the Lewis structure for COO and OCO. Compute for the formal charges. Determine which one is the more stable and explain.

26. Given Ksp= 3.2 x 10-40 of Bi(OH)3 , calculate the molar solubility , concentration of the constituent ions and solubility in g/L

27. Given Ksp= 2.4 x 10-23 of CrPO4, calculate the molar solubility, concentration of the constituent ions and solubility in g/L.

28. Given Ksp= 4.0 x 10-36 of AuBr3, calculate the molar solubility, concentration of the constituent ions and solubility in g/L.

29. Given Ksp==3.5 x 10-11 of FeCO3 , calculate the molar solubility ,concentration of the constituent ions and solubility in g/L .

30. Given Ksp= 2.0 x 10-26 of the of Sn(OH)2 ,calculate the molar solubility,concentration of the constituent ions and solubility in g/L.

31. Given Ksp= 1.5 x 10-11 of ZnCO3, calculate the molar solubility , concentration of the constituent ions ad solubility in g/L.

32. Calculate the Ho of the underlined compound in the thermochemical equation HI(g) + NaOH(S) NaI(S) + H2O(1) Hrxn= -172.9 kJ

33. Calculate the Hf of the underlined compound in the thermochemical equation KBr (s) + NaCl (s) NaBr(s) + KCl(s) Hrxn = 7.2 kJ

34. Write the thermochemical equation C4 H10(g) + O2(g) CO2(g) + H2O(l) in at least three ways. Hrx = -2897.3 kJ.

35. Write the thermochemical equation C5H12(g) + O2(g) CO2(g) + H2O(l) in at least three ways, where Hrxn = -3510.4 kJ.

41. 0.035 moles of SO, 0.500 moles of SOCL, AND 0.080 moles of Cl are combined in an evacuated 5.00 L flask and heated to 100C. What is Q before the reaction begins? Which direction will the reaction proceed in order to establish equilibrium? SOCl(g) SO2(g) + Cl2(g) Kc = 0.078 at 100

42. Calculate the Kc of Hl(g) H2(g) + I2(g) with the following concentrations: [HI] = 0.777; [H2] = 0.233 ; [I2] = 0.233

43. Calculate the pH of a 0.05 M HBr solution.

44. Calculate the [H30+] and the pH for a 0.10 M solution of acetic acid. (Ka = 1.8 x 10-5)

45. Calculate the equilibrium concentration of H3O+, HClO2, and ClO2- for a 0.10 M HClO2 Solution ( Ka = 1.1 x 10 -2)

46. Calculate the pH of a 0.10 M NH3 solution. ( Kb = 1.8 x 10 -5)

47. Calculate the Ksp of the equation Cd3(AsO4)2 (Refer to periodic table for the molar mass)

Cd2+ + AsO43- with 1.12g of Cd3(AsO4)2.

48. Calculate the Ksp of the equation NaCl Na+9(aq) + Cl- (aq) with 0.5g of NaCl. Ka = 1.8 x 10-5 (Refer to periodic table for the molar mass).

49. Consider the process by which we would calculate the H3O+, OAc-, and HOAc concentrations at equilibrium in an 0.10 M solution of acetic acid in water. Calculate the equilibrium concentrations of H3O+, OAc-, and HOAc.

50. Calculate the pH of ).10 M solution of hypochlorous acid, HOCl, Ka = 2.9 x 10-8.

Key to Correction 1. 2Ag+(aq) +2Cl(aq)2AgCl(s)

2. H+(aq) + OH-(aq) H2O(l)

3. BaSo4(s) + Co32-(aq) BaCO3(s) + So4-2-(aq)

4. CaCO3(s) + 2H-(aq) Ca2+(aq) + H2O(l) + Co2(aq)

5. Pb2+(aq) + 2Cl(aq) PbCl2(s)

6. Al(No3)3(aq) + 3NaOH(aq) Al(OH)3(s) + 3NaNO3(aq) Al3+(aq) + 3OH-(aq) Al(OH)3(s)

7. HF + KOH (aq) KF(aq) + H2O(l) H+(aq) + OH-(aq) H2O(l)

8. (NH4)2S(aq) + Fe(NO3)2(aq) NH4NO3(aq) + FeS(s) Fe2+(aq) + S2-(aq) FeS(s)

9. NaHCO3(aq) + HNO3(aq) NaNO3(aq) + H2CO3(s) H+(aq) + HCO3-(aq) H2CO3(s)

10. Ca2+(aq) + SO42-(aq) CaSO4(s)

11. ml = -4 is the erroneous quantum number since the only allowed values for ml are -3, -2, -1, 0, 1, 2 , and 3 12. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 Yb 13. 1s2 2s2 2p6 3s2 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p4 Uuh

14. n = 4 1 = 0, 1, 2, 3 15. l= 3 Me = -3, -2, -1, 0, 1, 2, 3 16. 4d10 N= 4 L= 2 Me= 2 -1/2

Ms=

17. n = 5 L= 0, 1, 2, 3,4 Me = -4, -3, -2, -1, 0, 1, 2, 3, 4 Ms = 1/2

18. 4.667 x 10 -11 19. 1.433 x 10-12 20. 7.01 21. 8.7 22. 2.22 x 10-10 23. 1.32 x 10-5 24. H H H

H C C C H | H | H | H

25.

-2 |

2 0 |
COO is the more stable of the 2 since it bears the lowest formal charges

C = O= O | |

O=C=O | o o | o

26. Ms = 5.867 x 10 -11 [Bi3+] = 5.867 x 10 -11 M [OH-] = 1.760 x 10-11 M Solubility = 1.5 x 10-8 g/l

27. Ms = 4.899 x 10-12 M [ Cr 3+] = 4.899 x 10-12 M [PO43-] 4.899 X 10-12 M Solubility = 7. 201 x 10 -10 g/L

28. Ms = 6.204 x 10-10M [ Au3+] = 6.204 x 10-10 M [ Br- ] = 1.10 x 10-9 M Solubility = 2.71 x 10 -7 g/L

29. Ms = 5.916 x 10-6 M [ Fe2+] = 5.916 x 10 -6 [ CO32-] = 5.916 x 10-6 Solubility = 6.836 x 10 -4 g/L 30. Ms = 1 x 10-9 M [Sn2+] = 1 x 10-9 M [ OH-] = 3X 10-9 M Solubility = 1.53 x 10-7 g/L

31. Ms = 3.872 x 10-6 [Sn 2+] = 3.872 x 10-6 M [CO32-] = 3.872 x 10 -6 M Solubility = 4.84 x 10-4 g/L 32. -172.9kJ - 172.9 x x = = = = (-288+ -286) (-427 + x) -574 + 427 x -574 + 427 + 172.9 25.9 kJ

33. 7.3kJ 7.2 x x

= (-360 + =436) (-411 + x) = = = -796 + 411 x -796 = 411 = 7.2 -392.2 kJ

34. C4H1O(g) + C4H10(g) +

O2(g) CO2(g) + 5/4H2O(l) O2(g) 2CO2(g) +

H20(l)

2C4H10(g) + 26O2(g) 8CO2(g) + 10 H2O(l)

35. C5H12(g) + 8 O2

CO2(g) + 3H2O(l)

2C5H12(g) + 32O2(g) 10CO2(g) + 12H2O(l) 3C5H12(g) + 48O2(g) 15CO2(g) + 18H2O(l)

36. 4Ca(s) + 4CuSO4(aq) 4CuSO4(aq) + 4Cu(s) 2Ca(s) + 2CuSO4(aq) 2CuSO4(aq) + 2Cu(s)

5Ca(s) + 5CuSO4 5CuSO4(aq) + 5Cu(s)

37.

= -575.5 kJ/mol

38.

= -6.5kJ/mol

39. Cr2O72-(aq) + 3HNO2(aq) + 5H+(aq) 2Cr3+ + 3NO3-(aq) + 4H2O(l)

40. Mn(s) + 2HNO3(aq) + 2H+(aq) Mn2+ + 2NO2(g) + 2H2O(l)

41. Qc = 0.0056 Qc < Kc reaction will proceed forward to establish equilibrium

42. [0.233] [ 0.233] [ 0.777]2 Kc = 8.99 x 10-2

43. pH = 1.3

44. HC2H3O2 + H2O [ H3O+} = 1.34 x 10-3 pH = 2.87

H3O+ + C2H302

45. [H3O+] [ClO2-] [ HClO2]

= = =

0.033 M 0.033 M 0.10M

46. pH = 13

47. Ksp = 2.2 x 10-12

48. Ksp

7.43 x 10-5

49. [H3O+] [Ac]

= 1.34 x 10-3 = 1.34 x 10-3

[HAc] = 0.10 = 7.43 x 10-5

50. [H+] [OCl] 0.10

5.39 x 10-5 0.10 pH = 3.27

36. Write the thermochemical equation Ca(s) + CuSO4(aq) CuSO4(s) + Cu(s) in at least three ways, where Hrxn = -663.1 kJ.

37. Calculate the Hrxn of the equation C3H8(g) + O2(g) CO2(g) + H2O(l).

38. Calculate the H rxn of the equation C3H8(g) + O2(g) CO(g) + H2(g).

39. Balance the redox equation: Cr2

(aq)

+ HNO2(aq) Cr3+ + NO3-.

40. Balance the redox equation: Mn(s) + HNO3(aq) Mn2+(aq) + NO2(g).