Chemistry Letters

http://www.csj.jp/journals/chem-lett/

Vol.36 No.9 September, 2007

Copyright 2007 The Chemical Society of Japan

CMLTAG ISSN 0366-7022

Highlight Review
1082
Asymmetric Catalytic Redox System: Tethered Bis(8-quinolinolato) (TBOx) Chromium(III/II) Complexes
Asymmetric Pinacol Coupling N Cl Cr O O N
t

Bu N O Cr N O cis- OH

Bu

2 RCHO

R dl:meso up to 98:2 dl: up to 98% ee OH Br

R OH

NozakiHiyama Allylation

RCHO

R'

Asymmetric Allenylation

RCHO

R * * anti:syn up to 10:1 R' up to 95% yield up to 99% ee OH Br up to 91% yield up to 97% ee R *

Hisashi Yamamoto and Guoyao Xia

TMS

TBOxCrIII Cl/TBOxCrII system is an ideal for catalytic asymmetric redox system. Because of the electron density of the TBOxH ligand, high turnover numbers are expected and hence allow decrease in the chromium catalyst loadings and acceleration of the reaction rate. Furthermore, high reactivity and high diastereo-/enantioselectivity are shown in asymmetric pinacol coupling reactions of aldehydes, asymmetric NH allylation reaction of aldehydes, asymmetric allenylation reactions of aldehydes, and some other reactions, which proceed exceedingly eciently catalyzed by the TBOxCrIII Cl redox system, due to the well-designed chiral environment of the ligands and the cis- conguration of the center Cr metal.

Letter
1088
Protective Agent-free Preparation of Gold Nanoplates and Nanorods in Aqueous HAuCl4 Solutions Using GasLiquid Interface Discharge

Triangular and hexagonal plates are clearly observed in the TEM image of gold nanoparticles obtained by a discharge-induced chemical reaction in a simple aqueous HAuCl4 solution.

Kenji Furuya, Yuko Hirowatari, Toshio Ishioka, and Akira Harata

200 nm

C-132

Chemistry Letters Vol.36, No.9 (2007)

1090

Preparation of Calcium Silicate Nanobelts and the In Vitro Behavior in a Simulated Body Fluid

Nanobelt-like single-crystalline calcium silicate, obtained via solvothermal routine, showed bioactive response in SBF solution, suggesting potential application in biomedical field.

Huiqin Ling, Qun Liu, Chengkang Chang, and Dali Mao

1092

Asymmetric Sulmidation with cis- Ru(salalen)(CO)2 Complexes as Catalyst

Ar S

4 (5 mol %) p -TolSO2N3 h, CH2Cl2, rt X

N S * Y 8590% ee

SO2Tol-p

t-Bu

N CO N Ru O CO O Bu-t 4 t-Bu

Hidekazu Fujita, Tatsuya Uchida, Ryo Irie, and Tsutomu Katsuki

1094

Room-temperature Formation of Alkoxidederived Anatase Nanoparticles by Peroxotitanic Acid Approach

C/C 0

1 TiO2 from inorganic salts 0.8 TiO2 from Ti alkoxide 0.6

Room-temperature titanium alkoxide-derived anatase nanoparticles by the peroxotitanic acid approach under a controlled procedure have excellent photocatalytic activity compared to those from ordinary procedures.

Yong-Jun Liu, Mami Aizawa, Wen-Qin Peng, Zheng-Ming Wang, Hiroaki Hatori, Naofumi Uekawa, and Hirofumi Kanoh

0.4

Dark 0 2

Light 4 6 Time / h 8 10

-24

1096

Organic Paramagnetic Ionic Liquids Based on Anion Containing 2,2,6,6-Tetramethyl-1piperidinyloxyl Radical Moiety

H2n+1C n

Me O N OSO3

n = 2,4,6,8

Yukihiro Yoshida, Hirofusa Tanaka, and Gunzi Saito

315

320

325

330

H / mT

1098

A Simple Route to Coat Multiwalled Carbon Nanotubes with Silica

Yong Zhu, Yubai Pan, Heng Xu, Changshu Xiang, Huamin Kou, and Jingkun Guo Electronic Supporting Information
The pristine multiwalled carbon nanotubes without oxidation or covalent decoration were homogeneously coated with silica through a simple modified solgel method.

Copyright 2007 The Chemical Society of Japan

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Chemistry Letters Vol.36, No.9 (2007)

C-133

1100

Regulated Formation of 2D Water Layers with Alternating Six-membered Quasi-planar and Chair Cluster Units by 1D Supramolecular Chain

4-Methylamino-6-oxopyrimidine (1) forms a self-complementary structure and regulates water molecule assembly into 2D water layers, which contain hexameric water clusters with quasi-planar and chair conformations, via hydrophilic and hydrophobic interactions.

CH3 N N N

O H

Self-assembly H2O - EtOH

Kenta Goto and Teruo Shinmyozu Electronic Supporting Information

1102

TTFCytosine Dyad as an Electron-donor Molecule Having Proton-accepting Ability: Formation of Hemiprotonated Cytosine Dimer in I3 Salt Eigo Miyazaki, Yasushi Morita, Yumi Yakiyama, Suguru Maki, Yoshikazu Umemoto, Makoto Ohmoto, and Kazuhiro Nakasuji Electronic Supporting Information

H2N S S S S TTF-C

O NBu

S H S S N H

O N H H O

Bu N

I2

+
N N Bu

S H

. (I3)3
S

Hemiprotonated cytosine dimer with radical cationic state of TTF moiety

1104

A Dimeric Cerium(III) Acetylacetonate Complex Containing Intramolecular and Intermolecular Hydrogen Bond

Fenghua Bai, Haiquan Su, and Fei Chang Electronic Supporting Information

An unexpected dimeric acetylacetonate complex linked by intermolecular hydrogen bonds was synthesized. Two neutral acacH molecules as unidentate ligands are coordinated to Ce through only carbonyl oxygen atoms.

1106

One-pot Ecient Synthesis of Cbz-protected -Amino Ketones: Three-component Coupling of Aldehydes, Ketones, and Benzyl Carbamate
R

O H

NHCbz R

NHCbz

CbzNH2 Me2S+BrBrMeCN rt., 1 h syn

+ anti

Biswanath Das, Anjoy Majhi, Nikhil Chowdhury, Kongara Ravinder Reddy, and Bommena Ravikanth Electronic Supporting Information

79 92%

1108

Novel Photoinduced Phase Transition Observed in Three-dimensional Liquid-crystalline Phase of Azobenzene Compound

Photochemical control of chirality-induced liquid-crystalline 3D structures.

Takahiro Yamamoto, Isa Nishiyama, and Hiroshi Yokoyama Electronic Supporting Information

Copyright 2007 The Chemical Society of Japan

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C-134

Chemistry Letters Vol.36, No.9 (2007)

1110

Lipase-catalyzed Separation of Geometrical Isomers: GeraniolNerol

The substrate/lipase ratio as well as pH of the buffer medium played important roles in the resolution of geometrical isomeric mixture of geraniolnerol.

CH2OR

Lipase

CH2OH

CH2OR

Pankaj Gupta, Subhash C. Taneja, Bhahwal A. Shah, Vijay K. Sethi, and Ghulam N. Qazi

E/Z

E > 99

E/Z

1112

Intramolecular Singlet Excited Energy Transfer in a Zinc PorphyrinFree-base Porphyrin Dyad Linked with an SiSi  Bond Yuki Shibano, Mikio Sasaki, Yutaka Kawanishi, Yasuyuki Araki, Hayato Tsuji, Osamu Ito, and Kohei Tamao Electronic Supporting Information

1114

Block Copolymerization of Methyl Methacrylate from Fluorine-contained Polyimide Macroinitiator by Atom-transfer Radical Polymerization

O HO N O

CF3 CF3

O N O O Cl Cl Polyimide CH3 O O CH3 Polyimide O

O N O Pyridine / THF

CF3 CF3

O N O OH

O Cl O O

O Cl

CuBr , (-)-Sparteine / Anisole

O

Cl

Sou Miyata and Kazukiyo Nagai

CH3 C CH2 C OCH3 O

O CH2 O O

CH2

MMA-b -PI-b -MMA

CH3 CH2 C Cl C OCH3 n O

1116

A Novel RutheniumQuinonoid Complex. Structural, Spectroscopic, and Electrochemical Characterization of Ruthenium(II) Bis(2,20 -bipyridine) Chloranilate

*(bpy)

Ryuta Ishikawa, Md. Khayrul Kabir, Keiichi Adachi, Koichi Nozaki, and Satoshi Kawata Electronic Supporting Information

1118

Oxidative Removal of Heterocyclic Alkyl or Sugar Side Chain by Microwave: A Simple Step to Xanthopterin, 6-Formylpterin, and 3-Hydroxymethyl-2(1H)-quinoxalinone

One-step microwave-assisted oxidative removal of 3-methyl and 3-sugar side chain in 2(1H )quinoxalinone system by selenium dioxide and sodium periodate respectively resulting 2oxoquinoxaline has been reported. Similarly xanthopterin (as acetyl derivative 2) is isolated from selenium dioxide oxidation of 7-methylxanthopterin.
SeO2

HO H N N H CH3 O SeO2 450 W, 18 min N N H H O NaIO4 300 W, 4 min N N H

H OH

Shyamaprosad Goswami and Annada C. Maity Electronic Supporting Information

HO H O

OH

NaIO4 450 W, 20 min

Copyright 2007 The Chemical Society of Japan

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Chemistry Letters Vol.36, No.9 (2007)

C-135

1120

Energy / kcal mol-1

Theoretical Determination of Hypervalent Bond Energy of 10S3 Sulfurane Derivatives

20 15 10 5 0 0 30 60 Angle / degree 90
The energy of a 10S3 hypervalent, i.e., NSN, bond determined theoretically using bond energy density analysis with the density functional theory at the B3LYP/cc-pVDZ computational level.

Yusuke Yamauchi, Kin-ya Akiba, and Hiromi Nakai Electronic Supporting Information

1122

Synthesis of a Donor Molecule with Metal Coordination Sites toward Multifunctional Complexes

S S S

Keiichi Katoh, Takahiro Sasamori, Norihiro Tokitoh, and Naoki Sato Electronic Supporting Information

N N

A novel N,N,N-tridentate ligand with a donor ability.

1124

A Simple Route to Preparation and Characterization of Er2 O3 Microspheres

Er2O3 microspheres have been successfully obtained by a simple route using CO(NH2)2 as the precipitant without any surfactant and template. The microspheres are composed of nanoparticles, and the diameter is in the range of 200300 nm.

Kaidong Han, Youjin Zhang, Zhiyong Fang, Tao Cheng, and Minrui Gao Electronic Supporting Information

1126

G / kJ mol

-1

Conformation Equilibrium of 1,2-Dichloroethane as a Probe for Solvent Properties of Liquid and Supercritical CO2

6 DCE gas 4 C2H6 Liq. C6H12 (C4H9)2O 2 SC-CO2 CHF3 Liq. DCE 0 THF (CH3)2CO CH3CN 0 0.1 0.2 0.3 0.4 0.5

CO2 Liq. C6H6

Gibbs-energy difference G between the gauche and trans isomers of 1,2-dichloroethane (DCE) in liquid and supercritical CO2 was investigated using Raman spectroscopy. G of DCE was suggested to be useful as a probe for studying solvent properties of SC fluids.

Mariko Tono-oka, Hideyuki Nakayama, and Kikujiro Ishii

-2

( 1) / (2 +1)

1128

Oxidative Degradation of Nylon-6 and Nylon-6,6 with Nitrogen Dioxide in Supercritical Carbon Dioxide

nylon-6

nylon-6,6 NH (CH2)6 NH C (CH2)4 C O O n

or NH (CH2)5 C n O

NO2 / scCO2 140 C, 10 MPa, 1 h

Naohisa Yanagihara, Naoto Abe, Hironori Takama, Yuichiro Shimamura, and Masaaki Yoshida

HO C (CH2)n C OH O O
n = 2, 3, 4

Copyright 2007 The Chemical Society of Japan

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C-136

Chemistry Letters Vol.36, No.9 (2007)

1130

Preparation of Gold Nanoparticles by the Laser Ablation in Room-temperature Ionic Liquids

Absorption spectra of the solutions of gold nanoparticles prepared by the laser ablation of a gold plate at 532 nm in imidazolium-based ionic liquids with different alkly-chain lengths ([OMIm][BF4], [BMIm][BF4], and [EMIm][BF4]). The TEM image is for the solution after the laser ablation in [OMIm][BF4].
[OMIm] + [OMIm] after 7 days
+

OD/arb unit

Yoshifumi Kimura, Hiroshi Takata, Masahide Terazima, Tetsuo Ogawa, and Seiji Isoda

[BMIm] + [EMIm] 0
400 500 600 700 800

Wavelength/nm

1132

Synthesis of Tetragonal ZrO2 Nanocrystals with a High Proton Conductivity

Phase-pure t-ZrO2 nanocrystals with large surface areas were prepared at 85 C, which exhibitsed a high proton conductivity.

Hui Wang, Xiaoqing Qiu, Liping Li, and Guangshe Li

1134

Diversication of Nonionic Amphiphilic Poly(N-vinylacetamide) Hydrogels by a Double Network Approach

NH O CH3

O H3C N

CH2 CH NH

CH2 CH N

y
CH3 O

NH CH3 NVA

O CH3

radical initiator
H3C O 5ON-bis-NVA N

5ON-bis-NVA O N CH3 CH2 CH

Hiroharu Ajiro, Junji Watanabe, and Mitsuru Akashi Electronic Supporting Information

NVA

water, 37C

radical initiator water, 37C Double Network Poly(NVA) Hydrogel

1136

H 2 gravimetric uptake /mg g-1

Hydrogen-adsorption Properties of a Novel Lantern-type Dinuclear Co(BDC)(DABCO)1=2

25 20 15
Co(BDC)(DABCO)1/2 Zn(BDC)(DABCO)1/2 IRMOF-1

10 5

Tohru Takei, Takato Ii, Jiro Kawashima, Tetsushi Ohmura, Masao Ichikawa, Mitsuya Hosoe, Yoshiaki Shinya, Izuru Kanoya, and Wasuke Mori

The highest measured reversible hydrogen uptake was 2.28 wt % at 77 K and 0.1 MPa on the Co(BDC)(DABCO)1/2. This value is higher in terms of the quantity of hydrogen adsorption than that of IRMOF-1(Zn4O(BDC)3) and Zn(BDC)(DABCO)1/2 under the same conditions.

0.02

0.04 0.06 Pressure / MPa

0.08

0.1

1138

Novel Fluorene-based Biphenolic Monomer: 9,9-Bis(4-hydroxyphenyl)-9-silauorene

A 9-silafluorene-containing biphenolic monomer, 9,9-bis(4-hydroxyphenyl)-9-silafluorene, was prepared and was used for the synthesis of polyesters by the polycondensation with a diacid dichloride.

O HO OH O O O Si O

Si

Surasak Takata

Seesukphronrarak

and

Toshikazu
Si Fluorene Diol Si Fluorene Diol-based Polyester

Copyright 2007 The Chemical Society of Japan

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Chemistry Letters Vol.36, No.9 (2007)

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1140

Green Tea Solution Individually Solubilizes Single-walled Carbon Nanotubes

Green tea solutions were found to be good carbon nanotube solubilizers.

Genki Nakamura, Kaori Narimatsu, Yasuro Niidome, and Naotoshi Nakashima Electronic Supporting Information

1142

Facile Derivatization of Pyridyloxazole-type Fluorophore via Click Chemistry

R1 R2 O N difficult to derivatize expensive to make a library R1 R3 N R1

R2 N NN R2 N NN

R3 N

click

R2 R1

N3

R3 N

R3 N click

R2 R1

N3

R3 N

Jing Shi, Lei Liu, Jing He, Xiangming Meng, and Qingxiang Guo

easy to synthesize for combinatorial screening

cheap building blocks good for a large library

1144

Phosphine-free Fabrication of CdSe Quantum Dots with Good Thermal Stability and Promising Application in Multiplexed Bioassay

The declining PL intensity degree of as-prepared CdSe QDs is less than that of the water-soluble CdSe@ZnS coreshell QDs, whose PL intensity declined by nearly 90% when the temperature increases from 12 to 55 C.

Bin Xing, Wan-wan Li, Hong-jing Dou, Peng-fei Zhang, and Kang Sun

1146

Circular Arrangement of Mesogens Induced in Bragg-type Polarization Holograms of Thick Azobenzene Copolymer Films with a Tolane Moiety

Atsushi Shishido, Makoto Ishiguro, and Tomiki Ikeda

H2O2
E Enzyme / OsII/III - layer OsIII E Electrode

H2O
E OsIII E OsII E E OsII

Fumio Mizutani, Eiji Ohta, Yasuhiro Mie, and Osamu Niwa

e-

Copyright 2007 The Chemical Society of Japan

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1148

Determination of Hydrogen Peroxide Based on the Charge Accumulation and Electrochemical Reduction at an Osmium Complex/Peroxidase-coated Electrode

accumulation of OsIII

measurement of reduction OsII current for OsIII

e-

C-138

Chemistry Letters Vol.36, No.9 (2007)

1150

Double Thienylation of Alkynes in the Platinum(II)-catalyzed Reaction of Thiophenes with Propiolic Acids

Mory Laye Keita, Tomohiro Mizuhara, Juzo Oyamada, and Tsugio Kitamura

1152

A Novel One-pot Synthesis of Pyrroloquinoline and Pyrroloisoquinoline Derivatives in Ionic Liquid

A Sonogashira coupling1,3-dipolar cycloaddition sequence of a (hetero)arenecarbonyl chloride, a terminal alkyne, and a suitable quinolinium bromide or isoquinolinium bromide was carried out in ionic liquid on the basis of a consecutive one-pot three-component process.

O R1 Cl R2

Pd/Cu, ionic liquid then: 1,3-dipole compounds O

O N R R2 R3
1

O R3

or
O R1 R2

Chen Ma, Yan Ren, Qun Zhang, Kai Ding, Jun Zhao, and Dongju Zhang

1154

Alkoxo-bridged Cobalt(II) Cube and Its Radical Adduct

Kiyotaka Mitsumoto, Satoshi Koizumi, Takuya Shiga, Hiroyuki Nishikawa, Yun Chi, and Hiroki Oshio Electronic Supporting Information

1156

Bipolar Host Materials for Green Triplet Emitter in Organic Light-emitting Diodes
Red and green host materials for phosphorescent OLEDs.

Ji Young Jeon, Tae Jin Park, Woo Sik Jeon, Jung Joo Park, Jin Jang, Jang Hyuk Kwon, and Jae Yeol Lee

1158

1,2,5,6-Tetrasilabenzobenzvalene: A Valence Isomer of 1,2,3,4-Tetrasilanaphthalene

SiR3 Si Si Si Si SiR3 SiR3 SiR3 Si

Si Si Si Si Si Si

Kazunori Takanashi, Vladimir Ya. Masaaki Ichinohe, and Akira Sekiguchi

Lee,

R3Si = SiMet Bu2

Si

Copyright 2007 The Chemical Society of Japan

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Chemistry Letters Vol.36, No.9 (2007)

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1160

Fullerene (C60) Nanostructures Having Interpenetrating Surfaces Prepared by Electrophoretic Deposition of C60 Nanoparticles in Water

Interpenetrating network structure having prcolating pathways of charges utilizing C60 nanoparticle film and P3HT.

Hyeon-Gu Jeon, Sen-ichi Ryo, Teruki Sugiyama, Isamu Oh, Hiroshi Masuhara, and Tsuyoshi Asahi

500 nm

1162

Rhenium-catalyzed [2 2] Cycloadditions of Norbornenes with Internal and Terminal Acetylenes

+ R cat. [ReBr(CO)3(thf)]2 cat. 2,6-iPr2C6H3NC R' [2+2] Cycloaddition R' R

Yoichiro Kuninobu, Peng Yu, and Kazuhiko Takai Electronic Supporting Information

1164

Electrochemistry of D-Gluconate 2-Dehydrogenase from Gluconobacter frateurii on Indium Tin Oxide Electrode Surface

Seiya Tsujimura, Tomohiko Abo, Yoshitaka Ano, Kazunobu Matsushita, and Kenji Kano

1166

Wide Polarized Potential Windows at the Interface between Water and an Ionic Liquid, Tetraheptylammonium Tetrakis[3,5bis(triuoromethyl)phenyl]borate

The widest polarized potential window for ion transfer across the ionic liquid/water interface.

[C14Iq+][C2C2N]

[THpA+][C2C2N]

[C14Iq+][TFPB] [THpA+][TFPB]

Ryoichi Ishimatsu, Naoya Nishi, and Takashi Kakiuchi

-1.2

-1.0

-0.8

-0.6

-0.4

-0.2

0.0

0.2

+ const.

1168

Excited-state Property of 1-(4-Cyanophenyl)-2-(4-methoxyphenyl)-1,1,2,2-tetramethyldisilane

Me Me MeO Si Si CN Me Me

Hiroshi Hiratsuka, Hiroaki Horiuchi, Yuki Takanoha, Hiroshi Matsumoto, Takeo Yoshihara, Tetsuo Okutsu, Keisuke Negishi, Soichiro Kyushin, and Hideyuki Matsumoto

Copyright 2007 The Chemical Society of Japan

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C-140

Chemistry Letters Vol.36, No.9 (2007)

1170

Direct O2 Epoxidation of Propylene by the Membrane Reactor Loaded with AgSr Catalyst Kossi E. Bere, Yoshito Wakui, Shu-ichi Niwa, Hiroshi Shoji, Koichi Sato, Satoshi Hamakawa, Takaaki Hanaoka, Toshishige M. Suzuki, and Fujio Mizukami Electronic Supporting Information

O2

Membrane catalysis (Ag, Sr)

H2O

1172

Water-soluble Carbon Nanotube Chaintransfer Agents (CNT-CTAs)

Acyl chloride groups on carbon nanotubes are reacted with a magnesium chloride dithiopropanoate salt to create novel carbon nanotube chain-transfer agents (CNT-CTAs) for potential use in reversible additionfragmentation chain-transfer (RAFT) polymerizations.

+ C
O
+

+
C CH2 CH3

SMgCl C Cl

O S C

MgCl S CH2 CH3

Cl

Amanda V. Ellis, Mark R. Waterland, and Jamie Quinton Electronic Supporting Information

O C S C CH2 CH3 S

MgCl
+

MgCl2
S C CH2

+ SMgCl

S CH3

+ H3O+

C S C CH2 S C S CH2 CH3

S OH C S C CH2 S C S CH2 CH3

CH3 + MgCl2

CH3

1174

Dierent Magnetic Properties for Diastereomers of Alkoxide-bridged (-Diketonato)ruthenium(III) Binuclear Complexes Takeshi Hashimoto, Yuji Kawamoto, Yousuke Ishitobi, Tatsuya Sasaki, Yutaka Fukuda, Akihiko Yamagishi, Hisako Sato, Kunio Shimizu, and Takashi Hayashita Electronic Supporting Information

1176

Chemical Oxidation of SrCoO3

Lassi Karvonen, Samuli Rasanen, Hisao Yamauchi, and Maarit Karppinen

1178

A Detection Method for Oscillating Chemical Reactions by Resonance Light Scattering Technique
3 1

14 12 10
750

/10 s

8
IRLS

4 3 2 1
t/s

600 450 300 150

6 4 2 2 4

0 100 200 300 400 500 600

In this contribution, a resonance light scattering (RLS) detection method is proposed for the measurements of oscillating reaction with H2O2KSCNCuSO4NaOH close system as an example. The seasonal change of oscillating chemical reactions concerning the particle size is examined, and the qualitative analytical information could be obtained from this straightforward and expeditious approach.

8
-1

10

Ping Yan, Yuan Fang Li, and Cheng Zhi Huang

cCu/10 mol L

-5

Copyright 2007 The Chemical Society of Japan

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Chemistry Letters Vol.36, No.9 (2007)

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1180

Ring-closing Metathesis for the Synthesis of Phenylene-bridged Silamacrocycles

Me Si X

Me X Si
Grubbs' cat.

X Si Me

Son Thanh Phan, Wataru Setaka, and Mitsuo Kira Electronic Supporting Information

Si Me

1182

Ecient Conversion of Carbon Dioxide to Methanol Using Copper Catalyst by a New Low-temperature Hydrogenation Process

H2O

HCOOR

2H2

CO2 + H2

ROH

CH3OH

Yong Liu, Yi Zhang, Tiejun Wang, and Noritatsu Tsubaki

443 K, 5.0 MPa Cu/ZnO/Al2O3 catalysts with isomorphous substitution were prepared by oxalate-gel coprecipitation.
Two novel coordination polymers, [M(L)(MeOH)2]n (MII = Ni, Co; H2L = E,E-muconic acid) having 3-D pillared-layer structure based on 2-D grid sheet extended by synanti-type carboxylate-bridges were prepared and NiII compound showed a ferromagnetic ordering at 1.7 K.
7

1184

Three-dimensional Ferromagnetic Frameworks of SynAnti-type Carboxylatebridged NiII and CoII Coordination Polymers

M M
eff / B
6

anti

Ko Yoneda, Masaaki Ohba, Takuya Shiga, Hiroki Oshio, and Susumu Kitagawa Electronic Supporting Information

syn

M
3 0 100

T/K

200

300

Copyright 2007 The Chemical Society of Japan

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