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CONTENTS
INTRODUCTION ........................................................................................................
1-1
1-1
1-2
1-3
1-4
1-4
Product Upgrading......................................................................................................
1-4
1-5
Reactors .....................................................................................................................
1-6
1-7
1-7
1-8
1-10
SUMMARY .................................................................................................................
2-1
2-1
2-3
2-6
2-8
2-10
Sasol...........................................................................................................................
2-11
Shell............................................................................................................................
2-11
ExxonMobil .................................................................................................................
2-11
Syntoleum...................................................................................................................
2-12
2-12
2-15
iii
CONTENTS (Continued)
3-1
3-1
3-2
3-2
3-3
3-4
3-5
Pipelines ...............................................................................................................
3-6
3-6
3-7
3-7
3-9
3-9
3-11
Conclusions ..........................................................................................................
3-11
3-12
3-12
Western Europe....................................................................................................
3-12
Japan ....................................................................................................................
3-13
China ....................................................................................................................
3-13
3-14
3-18
3-20
3-21
3-21
Steam Reforming..................................................................................................
3-22
3-23
Compact Reforming..............................................................................................
3-24
iv
CONTENTS (Continued)
Autothermal Reforming.........................................................................................
3-24
3-25
3-27
3-27
3-28
3-28
3-29
3-29
3-31
3-31
3-32
3-33
3-34
3-34
3-35
3-35
3-36
3-37
3-38
3-39
3-39
3-40
3-41
3-41
3-42
Formaldehyde ..................................................................................................
3-42
3-43
3-43
3-44
3-45
CONTENTS (Continued)
3-45
3-46
3-48
3-49
3-51
3-51
3-52
3-54
3-54
3.4.5 Ammonia...........................................................................................................
3-54
3-55
3-56
3-56
3-57
3-57
3-57
3-57
3-58
3-58
3-58
3-60
3-61
3-61
3-62
3-63
3-65
3-66
3-67
3-67
vi
CONTENTS (Continued)
3-70
Transportation Requirements.....................................................................................
3-70
LNG Regasification.....................................................................................................
3-71
3-71
3-72
3-73
INDUSTRY STATUS..................................................................................................
4-1
4-1
4-4
Sasol Process.............................................................................................................
4-9
4-12
ExxonMobil Advanced Gas Conversation For The 21st Century (AGC-21) ...............
4-13
4-13
4-14
4-15
4-16
4-16
4-18
4-23
4-25
4-27
4-28
4-28
Water Treatment.........................................................................................................
4-28
4-29
4-29
vii
CONTENTS (Continued)
4-33
4-34
4-34
4-37
4-39
4-41
TECHNOLOGY REVIEW`..........................................................................................
5-1
5-1
5-2
5-4
5-5
5-5
5-7
Autothermal Reforming...............................................................................................
5-8
5-10
5-11
5-13
5-14
5-15
5-16
5-19
5-20
5-22
5-22
5-23
5-25
5-27
viii
CONTENTS (Continued)
5-28
5-28
Catalyst Rejuvenation.................................................................................................
5-29
5-32
5-35
5-36
5-38
6-1
6-1
Sasol/Chevron ............................................................................................................
6-2
Shell............................................................................................................................
6-2
ExxonMobil .................................................................................................................
6-3
Syntroleum..................................................................................................................
6-4
ConocoPhillips ............................................................................................................
6-5
BP ...............................................................................................................................
6-5
6-11
6-12
6-13
6-18
6-18
7-1
7.1 REFORMING.......................................................................................................
7-2
Steam Reforming........................................................................................................
7-2
7-2
Catalyst Deactivation............................................................................................
7-3
Promoters .............................................................................................................
7-4
Autothermal Reforming...............................................................................................
7-4
ix
CONTENTS (Continued)
Dry Reforming.............................................................................................................
7-6
7-6
7-7
Catalyst Composition..................................................................................................
7-9
7-9
Support .................................................................................................................
7-9
Promoters .............................................................................................................
7-11
7-12
7-12
Temperature .........................................................................................................
7-13
Pressure ...............................................................................................................
7-13
Space Velocity......................................................................................................
7-13
7.3 HYDROPROCESSING........................................................................................
7-14
7-14
Catalyst Carriers.........................................................................................................
7-15
Hydroisomerization.....................................................................................................
7-15
8-1
8.1 BACKGROUND...................................................................................................
8-1
8-7
8-8
8-9
Cobalt Kinetics......................................................................................................
8-10
8-11
8-12
8-13
8-13
8-14
Regeneration Approaches....................................................................................
8-19
CONTENTS (Continued)
8-19
Particle Size..........................................................................................................
8-19
8-20
8-20
8-21
8-21
8-22
8.2.3 Patent And Literature Review By Topic For New Catalyst Systems................
8-25
8-25
8-26
8-28
8-29
8-29
8-30
8-31
8-32
8-33
8-34
8-34
8-35
8-35
8-36
8-36
8-37
8-37
8-40
8-41
Zirconia (Shell).................................................................................................
8-43
xi
CONTENTS (Continued)
8-43
8-44
8-45
8-45
8-48
8-49
8-50
8-50
8-51
8-52
8-53
8-55
8-55
8-56
8-57
8-59
8-60
8-60
8-61
8-61
8-61
8-62
Tantalum .....................................................................................................
8-62
Rhenium......................................................................................................
8-63
8-64
8-65
8-66
8-68
8-69
8-69
xii
CONTENTS (Continued)
8-70
8-75
8-75
8-77
8-77
8-77
8-78
8-78
8-78
8-78
8-78
8-79
8-80
8-80
8-81
8-82
8-83
8-83
8-83
8-83
8-84
8-84
8-84
8-85
8-85
8-85
8-86
xiii
CONTENTS (Concluded)
8-87
Separation Of Fines..............................................................................................
8-87
8-88
8-88
8-88
8-90
A-1
B-1
C-1
D-1
xiv
ILLUSTRATIONS
3.1
3.2
3.3
Concept Map Of Natural Gas Based Energy Transport Technologies ................. 3-18
3.4
3.5
4.1
4.2
4.3
4.4
4.5
4.6
4.7
5.1
7.1
8.1
8.2
8.3
Light And Heavy Fuel Cuts From The Co/Ta Catalyst For F-T And
Hydrocracking (EP 0967262) ................................................................................ 8-74
xv
TABLES
2.1
2.2
2.3
2.4
2.5
3.1
3.2
3.3
3.4
3.5
GTL Diesel Fuel Compared To Swedens Class I Diesel Fuel ............................. 3-73
4.1
4.2a
4.2b
4.3
4.4
4.5
5.1
5.2
5.3
Typical Operating Conditions For A Gas Fired POx Unit ....................................... 5-7
5.4
5.5
5.6
5.7
5.8
6.1
xvi
TABLES (Continued)
6.2
6.3
6.4
6.5
6.6
6.7
6.8
6.9
6.10
6.11
6.12
6.13
6.14
6.15
6.16
6.17
6.18
6.19
6.20
xvii
TABLES (Concluded)
8.1
8.2
8.3
A.1
AGIP, AGIP Petroli, Eni, Enitecnologie, IFP: F-T Catalyst Patents....................... A-6
A.2
A.3
A.4
A.5
A.6
A.7
xviii