006

MSDS FOR AMMONIA (ANHYDROUS)

Rev 5 (11/2005)
1. Identification of the Substance/ Preparation and of the Company Ammonia (Anhydrous) NH3 Energas Limited Westmorland Street Hull HU2 0HX instilled to control severe pain and prevent spasms of the lids, thus facilitating irrigation. Ingestion: Ingestion is not considered a potential route of exposure. 5. Fire Fighting Measures Suitable Extinguishing Media: All known extinguishants can be used. Specific Hazards: Exposure to fire may cause containers to rupture/ explode. Specific Methods: If possible stop flow of product. Move container away or cool with water from a protected position. Hazard Combustion Products: If involved in a fire the following toxic and/ or corrosive fumes may be produced by thermal decomposition:Nitric Oxide and Nitrogen Dioxide. Special Protective Equipment for Fire Fighters: In confined spaces use self-contained breathing apparatus. 6. Accidental Release Measures

Product Name:

Chemical Formula: Company Identification:

Emergency Telephone No: 01482 329333 2. Composition/ Information on Ingredients Substance/ Preparation: Components/ Impurities: Substance Contains no other components or impurities which will influence the classification of the product. 07664-41-7 2316353 (from EINECS)

CAS Number: EEC Number: 3. Hazardous Properties

Liquefied gas. Corrosive (C) to eyes, respiratory system and skin. Toxic (T) by inhalation. 4. First Aid Measures Inhalation: Treat with oxygen and bronchodilators if there is evidence of bronchospasm. Respiration may have to be supported in the unconscious individual. Bronchospasm can be treated by responding emergency teams with a bronchodilator, such as albuterol, and an anticholinergic inhalant, such as Atrovent. Skin Contact: If skin contact is extensive and emergency showers are available, the victim should get under the shower immediately. Contaminated clothing and shoes should be removed under the shower. In other cases, the affected areas should be washed thoroughly with large amounts of water for at least 15 minutes. Do not apply salves or ointments to skin during the 24 hours following the injury. Subsequent medical treatment is otherwise the same as for thermal burns. Eye Contact: Immediately begin irrigation of the eyes with copious amounts of tap water while holding the eyelids apart. Continue irrigation for 30 60 minutes. Prompt and thorough eye irrigation is of primary importance. Any standard anaesthetic solution for ophthalmic use may be

Personal Precautions Evacuate area. Ensure adequate air ventilation. Wear self-contained breathing apparatus when entering area, unless atmosphere is proved to be safe. Environmental Precautions Try to stop release. Reduce vapour with fog or fine water spray. Clean Up Methods Ventilate area. Wash contaminated equipment or sites of leaks with copious quantities of water, hose down area with water. Keep evacuated and free from ignition sources until any spilled liquid has evaporated (ground free from frost). 7. Handling and Storage

Suck back of water into container must be prevented. Do not allow backfeed into the container. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact Energas Limited if in doubt. Keep away from ignition sources (including static discharges). Segregate from oxidant gases and other oxidant materials in store. Refer to supplier's container handling instructions. Keep container below 50C in a well-ventilated place.

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MSDS FOR AMMONIA (ANHYDROUS)

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Purge air from system before introducing gas.

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MSDS FOR AMMONIA (ANHYDROUS)

Rev 5 (11/2005)
8. Exposure Controls/ Personal Protection Exposure Limit Value for Country: OES Values for Ammonia: LTEL : 25 ppm (8 hr TWA ref. period) STEL : 35 ppm (15 min. ref. period) Personal Protection: Ensure adequate ventilation. Do not smoke while handling product. Keep suitable chemically resistant clothing readily available for emergency use. Keep self-contained breathing apparatus readily available for emergency use. Protect eyes, face and skin from liquid splashes. 9. Physical and Chemical Properties Colourless gas. Ammonical 17 -33.3C -77.7C 630C 132C 0.6 (air = 1) 0.7 (water = 1) 1134 mg/l 8.23 bar @ 20C 15 30% in air permanent anosmia. Nose irritation becomes evident at concentration levels of 130 ppm. Skin: NH3 at concentrations of 1%, is irritating to moist skin and will cause superficial blistering at concentrations of 3% or greater after a few minutes of contact. Such burns tend to be painless and heal rapidly. Eye: 50 ppm NH3 will cause conjunctival irritation in most workers. Eye contact with 5000 ppm for 30 minutes, 20000 ppm for 5 minutes, or with 9% NH3 in an aqueous solution can cause permanent blindness. At lower concentrations the irritant properties of NH3 result in protective tearing and reflex closure of the eye preventing permanent injury. NH3 has a greater tendency to penetrate the globe, than other alkalis, and cause damage to the iris and lens. Such penetration occurs in seconds. When eyes that have come into contact with NH3 are irrigated, NH3 is released for more than 15 minutes. Immediately after a toxic exposure to NH3 there is corneal oedema, loss of corneal epithelium, loss of corneal reflexes and release of collagenase. This latter can result in damage with the occurrence of corneal ulceration, opacity and vasculisation after a delay of 1 3 weeks. Damage to the iris results in loss of pupillary reflexes, oedema and release of pigment and tissue proteins. This oedema can cause an acute open angle glaucoma. The released iris material as well as scarring can lead to a secondary glaucoma, which becomes evident after a delay of 1 3 weeks. Lens opacification can develop, also after a delay of 1 3 weeks. After NH3 eye burns, there is an increased frequency of dry eye syndrome (sicca). Respiratory System: Respiratory tract irritation, as manifested by cough, occurs after a 1-hour exposure to 110 ppm of NH3 or a 2-hour exposure to 80 ppm NH3. Acute damage to the respiratory system, with residual effects, can result after a 10-minute exposure to 1000 ppm NH3. Upper airway damage is more likely than lower airway damage with symptoms of inspiratory stridor and bronchospasm. Endoscopy can demonstrate findings of laryngeal oedema, mucosal necrosis and pseudomembrane formation. Damage to the lower airways and lung parenchyma can result in pulmonary oedema and haemorrhage, interstitial emphysema and lung collapse. With such damage there is collage breakdown as evidenced by an increase in the excretion of hydroxylsine metabolites in the urine. Bronchiolitis obliterans can develop after a period of 1 4 weeks. Acute damage to the airways results in an increased susceptibility to infection and chronic bronchitis can develop. Evidence of reversible bronchospasm (reactive airways dysfunction syndrome) has been found for as long as five years after an episode of acute NH3 damage to the airways. Other residual effects have included bullous emphysema, a decreased diffusion capacity, chronic airways obstruction, bronchiectasis and

Appearance/ Colour: Odour:

Molecular Weight: Boiling Point: Sublimation Point: Auto ignition temperature: Critical Temperature: Relative Density (Gas): Relative Density (Liquid): Solubility (mg/l Water): Vapour Pressure: Flammability Range: Other Data:

Although this gas has flammability data it is difficult to ignite in air and is classified as non-flammable.

10. Stability and Reactivity Reacts with water to form corrosive alkalis. Can form explosive mixtures in air. May react violently with oxidants. 11. Toxicological Information May cause inflammation of the respiratory system and skin. Inhalation of large amounts may lead to bronchospasm, laryngeal oedema and pseudomembrane formation. LC50 (1 hour): Acute Toxicity Nose: Ammonia acts principally on the upper respiratory tract, where it exerts and alkaline, caustic action. With nose breathing (concentrations up to 2000 ppm) greater than 90% of NH3 is absorbed by the nose. Acute exposure can cause burns to the nasal mucosa and complete and 7338 ppm

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MSDS FOR AMMONIA (ANHYDROUS)

Rev 5 (11/2005)
chronic respiratory insufficiency with hypoxemia and carbon dioxide retention. Central Nervous System: Exposure to NH3 levels of 310 ppm and greater can result in elevated blood and brain NH3 levels. Where there is a marked increase in brain NH3 levels there is interference with cerebral oxygen energy metabolism with CNS effects. Such effects include unconsciousness, increase in intercranial pressure, convulsions, ataxia and spasticity and can be seen after a 5 15 minute exposure to NH3 at levels greater than 4000 ppm. There effects are rapidly reversible, except in individuals with pre-existing liver disease. 12. Ecological Information May cause pH changes in aqueous ecological systems. Marine pollutant very toxic (T+) to aquatic organisms. 13. Disposal Considerations Avoid discharge to atmosphere. Do not discharge into any place where its accumulation could be dangerous. Contact Energas Limited if guidance is required. Gas may be scrubbed with sulphuric acid solution or water. 14. Transport Information UN No. Class/ Division Subsidiary Hazard ADR/RID item Emergency Action Code Hazard Identification No. CEFIC Tremcard No. Labelling ADR : : : : : : : : 1005 2.3 8 2TC 2RE App AB 268 1/20g44 Label 2.3 Toxic Gas Label 8 Corrosive Substance. Safety Phrases S9 Keep container in a well ventilated place. S16 Keep away from sources of ignition No smoking. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 Wear suitable protective clothing. S37 Wear suitable gloves. S39 Wear suitable eye/ face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/ safety data sheet. 15. Regulatory Information Number in Annexe 1 of Directive 67/548: 007-001-00-5 EC Classification : R10; R23; R34; R50; Symbols - road transport symbols are used and selected to the most stringent product classification. Label 2.3: Toxic Gas EC or ADR Label 8: Corrosive Substance Risk Phrases R10 Flammable R23 Toxic by inhalation R34 Causes burns R50 Very toxic to aquatic organisms.

16. Other Information Cylinder Identification: Valve Connection: Cylinder Colour(s): Either Shoulder: Body: Or Body: Shoulder: Shoulder: European Standard (EN1089-3) Yellow (RAL 1018) Not defined in current regulations Former Standard BS 349 Black Red Yellow BS 341 No. 10 or DIN477 No. 8

Only transport on vehicles where the load space is separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or emergency. Before transporting product containers check that they are firmly secured and ensure: Cylinder valve outlet is closed and not leaking. Valve outlet cap, nut or plug (where provided) is correctly fitted. Valve protection device (where provided) is correctly fitted). Adequate ventilation. Compliance with applicable regulations.

Ensure all national/ local regulations are observed. Ensure operator understands the toxicity hazard. Users of breathing apparatus must be trained. Contact with liquid may cause cold burns / frostbite. Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out. Details given in this document are believed correct at the time of going to press.

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MSDS FOR AMMONIA (ANHYDROUS)

Rev 5 (11/2005)
Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted. Refer to Energas Limited General Safety and Handling Data Sheet for further details.

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MSDS FOR AMMONIA (ANHYDROUS)

Rev 5 (11/2005)
CYLINDER IDENTIFICATION Colour to BS 349: Body : Black with Yellow and Red Band on Shoulder

ENERGAS GENERAL SAFETY AND HANDLING DATA

1. GENERAL Only trained persons should handle compressed gases. Observe all regulations and local requirements regarding the storage of containers. Do not remove or deface labels provided by the supplier for the identification of the container contents. Ascertain the identity of the gas before using it. Know and understand the properties and hazards associated with each gas before using it. When doubt exists as to the correct handling procedure for a particular gas contact the supplier. 2 HANDLING AND USE Keep container valve outlets clean and free from contaminants, particularly oil and water. Do not subject containers to abnormal mechanical shocks which may cause damage to their valves or safety devices. Never attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported immediately to the supplier. Close the container valve whenever gas is not required even if the container is still connected to the equipment. 3 STORAGE

Wear stout gloves. Never lift a container by the cap or guard unless the supplier states it is designed for that purpose. Use a trolley or other suitable device or technique for transporting heavy containers, even for a short distance. Where necessary wear suitable eye and face protection . The choice between safety glasses, chemical goggles, or full face shield will depend on the pressure and nature of the gas being used. Where necessary for toxic gases see that self-contained positive pressure breathing apparatus or full face air line respirator is available in the vicinity of the working area. Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with a lower pressure rating than that of the container. Assertain that all electrical systems in the area are suitable for service with each gas. Never use direct flame or electrical heating devices to raise the pressure of a container. Containers should not be subjected to temperatures above 45C. Never re-compress a gas mixture without consulting the supplier. Never attempt to transfer gases from one container to another. Do not use containers as rollers or supports, or for any other purpose than to contain the gas as supplied. Never permit oil, grease or other readily combustible substances to come into contact with valves of containers containing oxygen or other oxidants.

Containers should be stored in a well ventilated area. Some gases will require a purpose built area. Store containers in a location free from fire risk and away from sources of heat and ignition. Designation as a no smoking area may be desirable. Gas containers should be segregated in the storage area according to the various categories. The storage area should be kept clear and access should be restricted to authorized persons only , the area should be clearly marked as a storage area and appropriate hazard warning signs displayed (Flammable Toxic etc,). The amount of flammable or toxic gases should be kept to a minimum. Flammable gases should be stored away from other combustible materials. Containers held in storage should be periodically checked for general condition and leakage. Containers in storage should be properly secured to prevent toppling or rolling . Vertical storage is recommended where the container is designed for this. Container valves should be tightly closed and where appropriate, valve outlets should be capped or plugged. Protect containers stored in the open against rusting and extremes of weather. Containers should not be stored in conditions likely to encourage corrosion. Store full and empty containers separately and arrange full containers so that the oldest stock is used first.

Engineering and Welding Limited Westmorland Street Hull HU2 0HX Tel: Fax: 01482 329333 01482 212335

PRODUCTION SITE ADDRESSES Energas Limited Haslams Lane Alfreton Road Derby, DE22 1EB Tel: Fax: 01332 364121 01332 291590

Energas Limited Brownroyd Street Off Thornton Road, Bradford West Yorkshire, BD8 9AF Tel: 01274 549090 Fax: 01274 548181

FOR FURTHER INFORMATION CONTACT YOUR NEAREST DISTRIBUTION CENTRE