Name ____Mr. Perfect_____________________________ Date ____F 10___________ 1. Calculate the molarity and osmolarity of a solution containing 9.

82 g of magnesium phosphate dissolved into 1.75 L of water. (10 pts)

Mg3(PO4)2 3Mg2+ + 2PO43- (5 particles)

2. Fill in the missing information in the following table: (12 pts) Symbol 11 +3 B
24

Protons 5 12 18 29

Neutrons 6 12 22 35

Electrons 2 10 18 28

Charge +3 +2 0 +1

Mg+2 Ar

40

64

Cu+

3. Write the molecular formula for the following compounds: (8 pts) a. Sodium Phosphate Na3PO4 c. Ammonium Chlorate NH4ClO2 d. b. Iron (II) Hydroxide Fe(OH)2 Phosphorus Pentabromide PBr5

4. An element has four naturally occurring isotopes with the following masses and abundances: Isotopic Mass (Amu) Fractional Abundance 53.940 0.058 55.935 0.917 56.935 0.022 57.933 0.003 What is the atomic weight of this element? Report answer to 5 significant figures. (2 pts) Atomic Weight = (53.940 x 0.058) + (55.935 x 0.917) + (56.935 x 0.022) + (57.933 x 0.003) = 55.847 Amu

Chemistry 101 Exam 1

Name ____Mr. Perfect_____________________________ Date ____F 10___________ 5. For each of the following pairs of ions, write the formula of the corresponding compound. (6 pts) a. K+ and NO3KNO3 b. Fe2+ and PO4-3 Fe3(PO4)2 c. Al+3 and OH-

Al(OH)3

Soluble Na+, K+, Li+, NH4+ NO3Cl-, Br-, ISO42-

Except None None Ag+, Pb2+, Hg22+ Ca2+, Ag+, Pb2+, Ba2+

Insoluble CO32PO43S2OH-

Except Group 1A, NH4+ Group 1A, NH4+ Group 1A, NH4+ Group 1A, Ca2+, Ba2+

6. Write the balance molecular equation, complete ionic equation, and net ionic equation for each of the following aqueous reactions and include phase labels. If no reaction occurs (no precipitate), just write NR after the arrow: (18 pts) a. Pb(NO3)2(aq) + 2KCl(aq) PbCl2(s) + 2KNO3(aq)

Pb2+(aq) + 2NO3(aq) + 2K+(aq) + 2Cl-(aq) PbCl2(s) + 2K+(aq) + 2NO3(aq) Pb2+(aq) + 2Cl-(aq) PbCl2(s)

b.

NiCl2(aq)

(NH4)2S(aq)

NiS(s)

2NH4Cl(aq)

Ni2+(aq) + 2Cl-(aq) + 2NH4+(aq) + S2-(aq) NiS(s) + 2NH4+(aq) + 2Cl-(aq) Ni2+(aq) + S2-(aq) NiS(s) 2Na3PO4(aq)

c.

3Mn(NO3)2(aq)

6NaNO3(aq)

Mn3(PO4)2(s)

3Mn2+(aq) + 6NO3-(aq) + 6Na+(aq) + 2PO43-(aq) 6Na+(aq) + 6NO3-(aq) + Mn3(PO4)2(s) 3Mn2+(aq) + 2PO43-(aq) Mn3(PO4)2(s)

Chemistry 101 Exam 1

Name ____Mr. Perfect_____________________________ Date ____F 10___________ 7. Balance the following redox reactions using the half-reaction method and clearly label the oxidation and reduction steps. (14 pts) a) Cr2O72+ Fe2+ Cr3+ + Fe3+ [Acidic] (Reduction) (Oxidation)

6e- + 14H+ + Cr2O72- 2Cr3+ + 7H2O 6 x (Fe2+ Fe3+ + e-)

14H+ + Cr2O72- + 6Fe2+ 2Cr3+ + 6Fe3+ + 7H2O

b)

HS-

ClO3-

Cl-

[Basic] (Reduction) (Oxidation)

6H+ + 6e- + ClO3- Cl- + 3H2O 3 x (HS- S + 2e- + H+)

3OH- + 3H+ + 3HS- + ClO3- Cl- + 3S + 3H2O + 3OH-

8. Nicotine, a poisonous compound found in tobacco leaves yields the following percent composition upon elemental analysis: 74% C, 8.65% H, and 17.35% N. Its molecular mass was determined to be 162 g/mol. Write both the empirical formula and molecular formula for this compound. (10 pts) Assume a 100 gram sample:

Empirical Formula:

C5H7N

empirical mass = 81 g/mol

Molecular Formula:

C10H14N2

Chemistry 101 Exam 1

Name ____Mr. Perfect_____________________________ Date ____F 10___________ 9. When 2.50 g of potassium superoxide, KO2, is reacted with 4.50 g of carbon dioxide, CO2, 1.784 g of potassium carbonate, K2CO3, was obtained. Calculate both the theoretical yield and percent yield for this reaction. (10 pts) 4KO2 + 2CO2 2K2CO3 + 3O2

0.01736 mol K2CO3 x 140 g/mol = 2.4304 g K2CO3 Theoretical Yield

10. Baking soda (NaHCO3) is often used as an antacid. It neutralizes excess hydrochloric acid secreted by the stomach shown in the reaction below: NaHCO3(s) + HCl(aq) NaCl(aq) + H2O(l) + CO2(aq) Milk of magnesia, which is an aqueous suspension of magnesium hydroxide, is also used as an actacid: Mg(OH)2(s) + 2HCl(aq) 2H2O(l) + MgCl2(aq) Calculate the moles of acid that each is capable of neutralizing when 1 gram of the antacid is used. Which is the more effective antacid per gram, NaHCO3 or Mg(OH)2? (10 pts)

Milk of magnesia is more effective per gram. 11. Extra Credit. Clearly indicate which reagent is the oxidizing agent and which is the reducing agent in the following redox reaction. (5 pts) Ag+ + Cu Ag + Cu2+ Silver is the oxidizing agent and copper is the reducing agent.

Chemistry 101 Exam 1