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(1). q 
" - 330 '" D %  " C7 (1-3
( 1). ."'D %  " E q (t ) = q m cos( 0 .t + ) ; & 30 (2-3
(0,75) 'G 8#E C L "12) o '0 I( 3- 3
( 1). .'G 8#E 67. LC ")4)4 2 TO M 2' 0 K( 4-3
0, 5 P4 #0  R4 #0 6) (5-3
( 1) . q m 2E (6-3
(0,75 ) .
 ))'& )( u c (t ) 0' 0 K( 7-3

:
''
S 4 O6

 +' 7  ) + Sn

2+

+23 + ( S 2 O3  +  ' + W Sn

4+

 +  %0

+23
:"' ;  "
Sn 4+ + 2 S 2 O3
( aq )

Sn 2+ + S 4 O6
( aq )

( aq )

[Sn ]
[Sn ]
4+

2+

S 2 O3

 + & n3 = 2,1m.mol Sn

2+

( aq )

:  2 "'? ''

 Z R4'[ 0
2
2
= 10 mol / L
S 2 O3 q = 0,10mol / L

= 0,1mol / L

[ ]
[S O ]
2

= 0,11mol / L

(1) . %"  " 3 K )" 7 8#E( 1-1
 + & n2 = 2m.mol Sn 4+  + & n1 = 1,2m.mol # (2-1
2

. V = 200mL \E ?  ^' S 4 O6  + & n4 = 1m.mol

(1) ."\( 0  2E 67  % ` 8#E(
( 2). x 23" 12)  % ` K  % %c 23 29 ( *
1). xq = 0,087 m.mol :  2 23'" G ( )'&
n3 = 0,21m.mol n2 = 2m.mol : & 
+ V = 200mL \E ?2) I'` " E  ? 3  ( 2E(3-1
(2). n1 = 1,2m.mol n4 = 10m.mol
d '
: +['%
q 25.10 5 0
c=
=
= 16.10 6 F = 16 F
t
15 0

( 1-1 (1

-----------------------------------------------------------------------------------------------."# f'%M0 8' 4 & 2? % c1 = 2c = 32F

1 1 1
1 1
2
= +
= + =
c c1 c 2 c1 c1 c1

( 2-.1-

-----------------------------------------------------------------------------------------------q = c.u =

c1
.u = 1,92.10 4 C
2

( 3-1

-----------------------------------------------------------------------------------------------R=

u BM (20)
=
= 100
I
0,2

u BM = R.I :  G 8#E

(1-2(2

-----------------------------------------------------------------------------------------------2

[0,10ms] :  \
( 2-2
i (t ) = 0,05 A :
[10,20ms] :  \
i (t ) = 5t + 0,15 [20,40ms ] :  \
-----------------------------------------------------------------------------------------------i (t ) = 10t 0,05 :

L=

u AM
di
dt

u AM = L

di
dt

r = 0 ) u AM = ri + L

u AM = 0,35V : \ $%  &+2

di
:"'- )'& )( 0( 3-2
dt

di
= 5 i (t ) = 5t + 0,15 [20,40ms ] :  \
dt
0,35
L=
= 0,07 H = 70mH :  )
5

----------------------------------------------------------------------------------------------d 2q
1
+
q=0
2
LC
dt

( 1-3(3

-----------------------------------------------------------------------------------------------. "'D %    " 67 q & h (2-3

----------------------------------------------------------------------------------------------0 =
TO =

2.

1
=
LC

1
= 945rad / s
0,07.16.10 6

( 3-3

= 2 LC = 6,65.10 3 s = 6,65ms

( 4-3

----------------------------------------------------------------------------------------------. '+\0 3'30 8+   - 4" 2 "'- " 3 Z. "'  2( 5-3

----------------------------------------------------------------------------------------------q m = c.u m = c.E = 16.10 6.6 = 96.10 6 C

=0

( 6-3

----------------------------------------------------------------------------------------------u (t ) = 6 cos 945t

q = 96.10 6 cos 945t

(7-3

-----------------------------------------------------------------------------------------:
''
: )" 7 (1-1
2

k=

[ S 4 O6 ]eq [ Sn 2+ ]eq
2

[ S 2 O3 ] 2 eq [ Sn 4+ ]eq

= 110

------------------------------------------------------------------------------------------------((2-1
3

2.10
10
[ S 4 O6 ] [ Sn ]
0,2
0,2
Qr , i =
=

= 75,58
2 2
3
4+
2,1.10 3 2
[ S 2 O3 ] [ Sn ] 1,2.10
)
(
0,2
0,2
2

2+

Qr< k
3

- \" (  

-----------------------------------------------------------------------------------------
: +   23 29
 % "

n1 = 1,2

m.mol ' 
n3 = 0,21
n2 = 2

n4 = 10

23
0

1,2 x f

0,21 2 x f

10 + x f

xf

2+ xf

" 
"'?2
"'? 

m.l : 6\(" ' & +- m.mol : & ' 

2
[ S O ] [ Sn 2+ ]
(2 + x)(1 + x)
Qr ,i = 4 62 2
=
V
[ S 2 O3 ] [ Sn 4+ ] (1,2 x).(2,1 2 x)

"  " 92    " & "+2\ 'k "3+l) x f = 0,087 m.mol   " E  0 1 ;3

.(  c0 &


. K = ; & 3 Qr '0  23'" G 67

Qr =

(2 + 0,087) (1 + 0,087)
200 = 109,89 110. = K
(1,2 0,087) (2,1 0,174) 2
. x f = 0,087 m.mol : 2 23'" G

-----------------------------------------------------------------------------------------------(3-1
.- ' k ( \"  0
SBIRO ABDELKRIM

E-MAIL sbiabdou@yahoo.fr

msn :

sbiabdou@hotmail.fr

C 0 "  ") ' "+ 0 1o) * %* p 2 "''o" + '" Eq%" +  ) +['% '   6+
2