Lesson Plan

I. Lesson Identity Name of subject Educational Unit Class/semester Time allocation II. III. IV. V. Competency Standard Basic Competence Indicators Objective 5.1 Students are able to balance the redox reaction by ion-electron method 5.2 Students are able to read the name of ions such as Fe2+ (ferro ion), Fe3+ (ferri ion), Cr2O72- (dichromate ion), Cr3+ (chromate ion) : Chemistry : Senior High School : XII/1 : 30 minutes

VI.

Learning Materials In ion-electron method, the overall reaction is divided into two half reactions, one for oxidation and one for reduction. The equations for two half-reactions are balanced separately and then added together to give the overall balanced equation. This way is especially used for the reaction that the condition is already known whether in acidic or basic condition. The steps that used for balancing the reaction in ion-electron method are: Step 1: Write the unbalanced equation for the reaction in ionic form Example: Fe2+ + Cr2O72Oxidation: Fe2+ Reduction: Cr2O72reaction separately. For oxidation half-reaction is already balanced for Fe atoms. For the reduction half- reaction multiply the Cr3+ by 2 to balance the Cr atoms. Fe3+ + Cr3+ (acidic condition) Fe3+ Cr3+

Step 2: Separate the equation into two half reactions

Step 3: Balance the atom that undergoes the redox reaction in each half-

Fe2+ Cr2O72-

Fe3+ 2 Cr3+

Step 4: Balance the oxygen atom. For the reaction in acidic condition, add H2O to the one side that has no oxygen atom. For the reaction in basic condition, add H2O to the one side that has oxygen atom. Fe2+ Cr2O72Fe3+ 2 Cr3+ + 7 H2O

Step 5: Balance the hydrogen atom by adding H+ ion in acidic condition or OH- ion in basic condition. Fe2+ 14 H+ + Cr2O72Fe3+ 2 Cr3+ + 7 H2O

Step 6: Add electrons to one side of each half-reaction to balance the charges. If necessary, equalize the number of electrons in the two half- reactions by multiplying one or both half- reactions by appropriate coefficients. Fe2+ Fe3+ + e- (multiplied by 6) 2 Cr3+ + 7 H2O 14 H+ + Cr2O72- + 6e6 Fe2+ 6Fe3+ + 6e2 Cr3+ + 7 H2O

14 H+ + Cr2O72- + 6e-

Step 7: Add the two-half reactions together and balance the final equation by cancelling the electrons on both sides. * 14 H+ + Cr2O72- + 6 Fe2+ + 6eH2O + 6e*

2 Cr3+ + 6Fe3+ + 7 2 Cr3+ + 6Fe3+ + 7 H2O

14 H+ + Cr2O72- + 6 Fe2+

Step 8: Verify that the equation contains the same types and numbers of atoms and the same charges on both sides of the equation (Chang,2002)

VII. VIII.

Learning Method Teaching Learning Process Steps Step 1 Entering Classroom Activities Saying greeting Checking the classroom. e.g. respond to the situation Step 2 Opening Classroom Giving motivation to learn to the students Focusing learning activities, e.g. introduce learning objective Step 3 Conducting Lesson Asking students about the definition of reduction and oxidation Giving information about the steps in balancing redox reaction ( ion-electron method) by using puzzle as media Giving practice to students in reading the name of ions for example Fe2+ (ferro ion), Fe3+ (ferri ion), Cr2O72- (dichromate ion), Cr3+ (chromate ion) Asking students to solve a problem in balancing redox reaction by ion electron method Step 4 Ending Lesson Summarizing lesson Giving task for home works (Worksheet 1) Step 5 Leaving Classroom Saying goodbye 1 3 12 3 Time 1

IX. X.

Evaluation Learning Resource

XI.

Evaluation (task home work) Worksheet 1 Balance the redox reactions bellow by ion-electron method! a. Cr2O72- + C2O42b. Cl2 + IO2c. Br2 + KIO3 + KOH Key answer: a. Cr2O72- + C2O42Step 1: Reduction: Cr2O72Oxidation: C2O42Step 2: Cr2O72C2O42Step 3: Cr2O72C2O42Step 4: Cr2O72- + 14 H+ C2O42Step 5: Cr2O72- + 14 H+ + 6eC2O42Step 6: Cr2O72- + 14 H+ + 6eC2O422Cr3+ + 7H2O 2CO2 + 2e- (multiplied by 3) 2Cr3+ + 7H2O 2CO2 + 2e2Cr3+ + 7H2O 2CO2 2Cr3+ + 7H2O 2Cr3+ + 7H2O 2CO2 2Cr3+ 2CO2 Cr3+ CO2 Cr3+ + CO2+ (acidic condition) Cr3+ + CO2 (acidic condition) Cl- + IO4- (basic condition) KIO4 + KBr + H2O (basic condition)

Cr2O72- + 14 H+ + 6e3C2O42Step 7:
4

6CO2 + 6e-

Cr2O72- + 14 H+ + 6e3C2O42b. Cl2 + IO2Step 1: Reduction: Cl2 Oxidation: IO2Step 2: Cl2 IO2Step 3: Cl2 IO2Step 4: Cl2 IO2- + 4OHStep 5: Cl2 + 2eIO2- + 4OHStep 6: Cl2 + 2eIO2- + 4OH2Cl2 + 4eIO2- + 4OHStep 7: 2Cl2 + 4eIO2- + 4OH2Cl2 + IO2- + 4OHc. Br2 + KIO3 + KOH Br2 + K+ + IO3- + K+ + OHStep 1: Reduction: Br2 Oxidation: IO3BrIO45

2Cr3+ + 7H2O 2Cr3+ + 7H2O + 6CO2

6CO2 + 6eCl- + IO4- (basic condition) ClIO42ClIO42ClIO4- + 2H2O 2ClIO4- + 2H2O 2ClIO4- + 2H2O + 4e2Cl- (multiplied by 2) IO4- + 2H2O + 4e4ClIO4- + 2H2O + 4e4ClIO4- + 2H2O + 4eIO4- + 4Cl- + 2H2O KIO4 + KBr + H2O (basic condition) K+ + IO4- + K+ + Br- + H2O

Cr2O72- + 14 H+ + 3C2O42-

Step 2: Br2 IO3Step 3: Br2 IO3Step 4: Br2 IO3- + 2OHStep 5: Br2 + 2eIO3- + 2OHStep 6: Br2 + 2eIO3- + 2OHBr2 + IO3- + 2OHBr2 + KIO3 + 2KOH 2BrIO4- + H2O + 2e2Br- + IO4- + H2O 2KBr + KIO4 + H2O 2BrIO4- + H2O + 2e2BrIO4- + H2O 2BrIO4- + H2O 2BrIO4-