JMS 3 PAPER - 2

PAPER-2
Maximum Marks: 80

Question paper format and Marking scheme: 1. In Section I (Total Marks: 24), for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. 2. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative marks in this section. 3. In Section III (Total Marks: 24), for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise There are no negative marks in this section. 4. In Section IV (Total Marks: 16), for each question you will be awarded 2 marks for each row in which you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. Thus each question in this section carries a maximum of 8 Marks. There are no negative marks in this section. http://www.chemistrycrest.com/ Page 1

JMS 3 PAPER - 2
SECTION I (Total Marks : 24) (Single Correct Answer Type) This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. The plot of compressibility factor (Z) versus pressure for the same gas given at different temperatures.
T4
T3 T2 T1

Z 1.0

Ideal gas

P(atm)

The correct order of temperatures is A) T4 > T3 > T2 > T1 C) T1 > T2 > T3 > T4 2. B) T2 > T3 > T1 > T4 D) T3 > T2 > T1 > T4

Dipole moment of the following molecules are in the order

CH

3
H

Cl
C = C

H C 3

Cl
C = C
NO
(2)

H
(1)

Cl
H

H C 3

Cl
C = C

Cl
C = C
H

Cl
(3)

Cl

Cl
(4)
(B) 2 > 3 > 1 > 4 (D) 2 > 4 > 1 > 3

(A) 1 > 4 > 2 > 3 (C) 3 > 2 > 4 > 1

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JMS 3 PAPER - 2

3.

Cl2 ( g ) + Ba ( OH )2 X ( aq ) + BaCl2 + H 2O
X + H 2 SO4 Y + BaSO4
Y Z + H 2O + O2 >365K

Y, Z respectively, and magnetic behavior exhibited by Z are B) HClO3 , ClO2 , paramagnetic D) HClO4 , Cl2O7 , paramagnetic

A) HClO4 , ClO2 , diamagnetic C) HClO3 , Cl2O , diamagnetic

4.

NH4Cl crystallizes in a body-centred cubic lattice with edge length of unit cell equal to 387 pm. If the radius of the Cl ion is 181 pm, radius for NH4+ ion is (A) 154.1 pm (B) 92.6 pm (C) 366.3 pm (D) none of these The isomers given are
CH3

5.

CH2 CH3
H Cl and

HO H

HO H
CH3

H Cl

CH2 CH3

(A) Identical (C) Enantiomers

560 K 470 K Z X Y inert atmosphere under pressure

(B) Diastereomers (D) none of the above

6.

The three allotropes ' X ', ' Y ' and ' Z ' of phosphorus in the above changes are respectively,

A) white, black and red C) red, black and white

7.

B) black, white and red D) red, violet and black

An optically active Aldose A upon treatment with NaBH 4 is converted into an optically inactive alditol (B). A on Ruff degradation gives C whose alditol (D) is optically inactive. Ruff degradation of C gives optically active D-glyceraldehyde A,B,C & D are A) B-D- Glucopyranose, D-glucitol, D-ribose, ribitol B) D- ribose, ribitol, D-erythrose, erythritol C) D glucopyranose, L-Dlucitol, L-ribose, ribitol D) D fructofuranose, D-Manitol, D-ribose, ribitol

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JMS 3 PAPER - 2

8.

Acidic hydrolysis is minimum in

O OCR
O OCR

O COR

O COR
| NO2
| OC2H5

(A)

(B)

NO2

(C)

(D)

SECTION II (Total Marks : 16)

(Multiple Correct Answer(s) Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE OR MORE may be correct. 9. The major products of following reaction sequence are :
H SO LiAlH 2 4 4 (I) (II) H (II) 1) ( ( 2) ( 3)

(A) I =

(B) I =

(C) III =

(D) III =

10.

Mg3B2

HCl ( aq )

[X] + MgCl [Y] + H2

[X] + H2O

HCl ( aq )

Regarding [X] and [Y], the correct option/s is/are (A) [X] is BCl3 and [Y] is H3BO3 (B) [X] is B2H6 and [Y] is H3BO3 (C) [X] on reaction with air and [Y] on strong heating (red heat) give same compound. (D) In [Y], B attains octet by accepting OH from water http://www.chemistrycrest.com/ Page 4

JMS 3 PAPER - 2

11.

Which one of the following is/are optically active? (A)

H C 3

(B)

Cl
NO

CH
2

H C 3

Cl

H C 3

(C)

(D)
H

H C 3
C=C=C
H

CH

3
H

CH

Br

3 CH 3

Br

12.

The true statements among the following are A) Magnesium with dil. HNO3 produces hydrogen B) Sodium nitrate on heating at 500C gives oxygen C) Sodium carbonate liberates CO2 on heating at 100oC D) Sodium when heated in excess of oxygen gives sodium monoxide. SECTION-III (Total Marks : 24) (Integer Answer Type)

This section contains 6 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS. 13. Amongst the following , no of molecules that are coloured due to charge transfer phenomenon are
CrO2 , Cr2 O72 , MnO , Cu2O, ZnO, CuSO4, MnS 4 4

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JMS 3 PAPER - 2
14. The standard reduction potential of H2O2 is 1.776V and standard oxidation potential of H2O2 is 0.682V. The overall cell potential for disproportionation of H2O2 is almost equal to Amongst the following , no of species having linear shape is
I3 , ICl2 , BeCl 2 , XeF2 , XeF6 , BrF5 , HC CH .

15.

16.

In 2HI(g) H2 (g) + I2 (g), 2 mole HI, 4 mole H2 and 4 mole of I2 are found at equilibrium. If some hydrogen is now introduced into the container such that at equilibrium concentration of HI and I2 become equal. Unit place of number of mole of H2 added is
C3 H 7 Br ( A ) gives C3 H 6 ( B ) with alcoholic potash. (B) on oxidation gives C2 H 4O2 ( C ) + carbon

17.

dioxide and water, (B) with hydrobromic acid gives (D), an isomer of (A). The difference in the positions of Br in (A) and (D) is 18. An electron is accelerated from rest and it has wavelength of 1.41 . By how much amount potential should be dropped so that wavelength associated with electron becomes 1.73 .

SECTION-IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given q and r, then for the particular question, against statement B, darken the bubbles corresponding to q and r in the ORS. 19. Column-I (A) (B) (C) (D)
Acetone + CHCl3 CS2 + Acetone Phenol and aniline

Column-II (P) (Q) (R) (S) (T)

P total < PA + PB

Vmix > 0

Toluene + Benzene

is not equal to 0 mix Maximum boiling azeotropes H A - B Interaction =A-A&B-B

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JMS 3 PAPER - 2

20.

Match the reactions in column I with appropriate types of steps/reactive intermediate involved in these reactions as given in column II. Column-I (A)
m CPBA
Br2 H 2O

Column-II (P) product contains one ring

(B)

aq NaOH

(Q)

product contains two rings

(C)

H3C CH = CH 2
CH 2 I 2 Zn / Cu ether

(R)

product is an epoxide

(D)

h H 2C = CH ( CH 2 )3 CHN 2

(S) (T)

product is a hydrocarbon A carbene (or) carbene like species participates

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