Professional Documents
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Carl Hoeger
Section: C01 TA: Matthew Snedaker msnedake@ucsd.edu
OH: Monday 8-10pm @ York 4020B
If you need help, then visit the CHEM Help Room in YORK 4020.
Midterm 2: 5/25/07 (7-8:50pm) @ PETER 108
Quiz 3: 6/4/07
Final Exam: 6/11/07 (11:30am -2:30pm) @ a top secret location (TBA).
Problem Notebook
Bring your problem notebook to every discussion section and come prepared with the necessary problems completed.
This study guide will highlight some of the main concepts from lecture. Do not use it as your only study
tool. The material featured is representative of the material covered up to the lecture from the previous week
(the Friday before our discussion).
WEEK 6- Nuclear Chemistry: the study of radioactivity, the changes that nuclei undergo, and the chemical consequences of
those changes.
Nuclear decay is the process of partial break up of the nucleus towards a more stable one.
Parent daughter nuclei
•It is a nuclear transmutation if the daughter is a different element.
Take a minute to think about each of these decays and how they would affect a parent nuclei. Do you understand how to write
nuclear equations and where each of the above particles belongs?
What does it mean to bombard a nucleus with a particle (e.g. alpha, beta, neutron, etc.)? What does it mean if a particle is
ejected? In a nuclear equation, where would an ejected particle go (i.e. left or right side)?
Make sure that you understand the language used in the homework problems and that you can interpret the language into
nuclear equations.
Spontaneous fission: For atoms with more protons than 92, the nucleus splits into two separate nuclei.
•A variety of product nuclei may be formed.
Nuclear Kinetics
•Activity: rate at which radioactive decay occur (SI unit: 1Bq = 1 decay/sec) (Traditional unit: 1 Ci = 3.7*1010 Bq).
•Radionuclides undergo 1st order kinetics; thus, t1/2 =.693/k.
•The Law of Radioactive Decay states that Activity = rate of decay = kN where N is the # of radiocuclide atoms.
•1/k is average lifetime of radionuclide.
•Radioactive decay is not temperature dependent.
•Don’t forget units!!
− kt
• N t = N 0e use this equation to determine the amount of radioactive nuclei there was initially (N0), the amount of
radioactive nuclei there is at time t (Nt), the rate constant, or the time it takes for a certain fraction to remain.
--Make sure that you use the same units for both N’s.
Radiation is detected by counts per second (or counts/time). This is the same as disintegrations per second (or dis/time).
Nuclear Energetics
ΔE = Δmc2 = Nuclear Binding Energy (BE)
Can energy be created or destroyed? NO. But it can be transformed into mass and mass can be transformed into energy.
•Look at Einstein’s famous equation. What is it saying? It is saying that a small amount of matter relates to a large amount of
energy.
•Remember that the theoretical mass is the sum of proton, neutron, and electron masses and it is greater than the actual mass
because some mass is converted to energy.
•Refer to Dr. Hoeger’s slides to get a better understanding of this concept.
In addition, make sure you understand the difference between binding energy and binding energy per nucleon.
Binding energy per nucleon is the binding energy divided by the number of protons plus neutrons.
BE/nucleon = BE/(#p+#n).
This concludes the synopsis of the material covered in the 5/7/07 to 5/11/07 lectures.