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and derivation of
A =
Since T is constant since there is no attraction between ideal molecules and speed of melocules are
unchanged and E is from 5.6 in zumdahl given both by :
And:
We have that kinetic energy are both function of v and T so if dT=0 then dv=0
So for ideal gas mixture T is constant and partial pressure for each component due to increase in V is
given like this:
Since
nRT
V
p
= and T is constant. We can say that in a mixture of ideal gases because of no
interaction each component get larger volume to travel in hence entropy increases. Also pressure
from each component decreases because of increase in V from ideal gas law we get entropy change
for each component to be:
1 2
2 1 1
2 2
1
ln ln ln
V V
nRT
p p nRT p
S nR nR nR
nRT
p nRT p
p
A = = = (a)
(a) Becomes from explanation above (a)
1 1
2 2,
ln ln
i
p p
nR nR
p p
= (b)
,2
2
i
i
n RT
p
V
= so that
,2
2
i
i
i
i
n RT
p
V
=
we know that this occurs at constant pressure therefore:
,2 1 i
i
p p =
so
1
2
nRT
p
V
=
And change in entropy given in (b) becomes:
1 2
1 2
,2
2
ln ln ln ln
V V i i i
i
i i i
nRT
p V nRT n
S nR n R n R n R
n RT
p n RT n
V
A = = = =
We use
log ( )
l
x
x A and l I = A = log ( )
m
x
x and m II = B B =
log ( )
n
x
x and n III
B B
A A
= =
m
n m l m
l
l
x
x
x x
x
x
B
= = =
A
= lo g g lo log
x x x
m n
B
l = = A
A
B
And also used
( )
ln ln ln ln ln ln
a b
a b b a
b a
= = =
And we get:
1 2
ln
i
V V i
n
S n R
n