Set I

Multiple choice 1. Which of the following is not true about soap? A. Soap is a mixture of sodium and sulphonic acid with 12 to 18 carbon atoms. B. Soap is made from animal fats or vegetable oils. C. The process of making soap is called saponification. D. Glycerol is one of the products of saponification. 2. The soap molecule has the following properties except A. its hydrophobic end is covalently bonded B. its effectiveness decreases in heated water C. its hydrophobic end dissolves in grease D. it reduces the surface tension of water. 3. Which of the following are correct about soap and detergent? I Soap is ineffective in hard water as it forms scum II Dehydrated zinc carbonate overcomes the problem of hard and acidic water III Soap is more soluble in water as compared to detergent. IV Detergent is less biodegradable compared to soap A. I and II only B. I, II, and III only C. I and IV only

D. IV only

4. The following are the advantages of using food additives except A. delays food decay B. increases mineral and vitamin content C. reduces health risks in the case of sorbitol D. prevents heart related diseases. 5. Food packaging labels should contain I mass of product II expiry date III address of manufacturer IV added vitamins and minerals A. I, II, and III only B. I, II, and IV only D. I, II, III, and IV only

C. II, III, and IV only

6. Mangesium nitrate solution reacts with sodium carbonate solution under room conditions. The reaction is exothermic. Which of the following statements is true of the reaction? A. Activation energy of the reaction is zero. B. Heat of reaction is a positive value. C. Reactants have the same energy content as the products. D. A maximum temperature of reaction mixture will be obtained. 7. Which of the following is an endothermic reaction? A. Reaction between acid and alkali. B. Potassium nitrate dissolves in water. C. Reaction between acid with a metal carbonate. D. The displacement of a metal from its salt solution. 8. A. B. C. The heat of precipitation of a substance is the heat change when 1 mole of the substance is formed. the heat change when 1 mole of the substance is consumed. the heat change for 1 oC increase in temperature.

D. the heat change when 1 mole of water is formed. 9. When 50 cm 3 of 1.0 mol dm 3 lead(II) nitrate solution is added to 50 cm 3 of 1.0 mol dm 3 sodium chloride solution, a white precipitate is formed. The temperature of the mixture increased by 8.5 o C. What is the heat energy released in this reaction? [Specific heat capacity of water = 4.2 J g 1 oC 1 ;desnity of solution = 1 g cm 3] A. 1785 J B. 3570 J C. 1785 kJ D. 3570 kJ 10. Which of the following statements is correct? A. A reducing agent is a substance that receives electrons. B. Chlorine is a strong reducing agent. C. Reduction occurs at the cathode of an electrolytic cell. D. An oxidizing agent is a substance that releases electrons. 11. When potassium bromide solution is added to aqueous chlorine, A. the solution changes from yellow to purple. B. bromine is displaced by chloride ions. C. bromide ion is oxidized to bromine by chlorine. D. electrons are transferred from chlorine to bromide ions. 12.. In which compound(s) would you find iron occurring with an oxidation number of +3? I K3Fe(CN)6 II K2Fe(CN)6 III Fe2(SO4)3 IV Fe(NO3)2 A. III only B. I and III only C. II and IV only D. I, II, and III only 13. The above experiment is carried out to study the transfer of electrons at a distance. Which of the following statements is not true? A. The oxidation number of bromine decreases from -1 to 0. B. The oxidation number of manganese decreases from +5 to +2. C. Electrons are transferred from KBr solution to KMnO4 solution. D. Bromide ions acts as a reducing agent. 14. In a redox cell, a salt bridge between the two reagents serves to I separate the oxidizing agent from the reducing agent II allow electrons to flow from the negative terminal III cause a deflection in the galnometer IV allow ions to flow between the two solutions in the U-tube A. I and III only B. II and IV only C. I, II and III only D. I, II, and IV only 15. The body of an aeroplane is made of duralumin. What is the main metal in duralumin? A. Iron B. copper C. aluminium D. magnesium 16. Why is ceramic used form the wall of a nuclear reactor? A. Ceramic is very hard /seramik sangat keras B. ceramic is malleable/seramik mudah dibentuk C. ceramic is inert towards chemicals/seramik lengai terhadap bahan kimia D. ceramic can withstand high temperature/seramik tahan suhu tinggi 17. The diagram shows the stages in the production of sulphuric acid usng the contact process.

Sulphur Sulfur

sulphur dioxide sulfur

O2

O2 sulphur concentrated sulphuric acid trioxide sulfur asid sulfuric pekat

dioksida

trioksida sulphuric acid asid sulfurik substance X oleum bahan X

What is substance X? /apakah bahan X? A water / air B. sulphur / sulfur C. oxygen /oksigen D. sulphur dioxide/sulfur dioksida 18.The diagram shows polymerization process. /gambarajah menunjukkan suatu proses pempolimeran.

Substance R substance S Bahan R bahan S Which of the following properties is identical for substances R and S? Antara sifat berikut yang manakah sama bagi bahan R dan bahan S? A. Melting point/takat lebur B. density/ketumpatan C. relative molecular mass/jisim molekul relative D. percentage composition/peratusan komposisi 19. The diagram shows the energy profile of a reaction. Ea is the activation for this reaction. Gambarajah di bawah menunjukkan profil tenaga bagi suatu tindak balas. Ea ialah tenaga pengaktifan bag tindak balas itu. What will change the activation energy from Ea to Ea1 ? /apakah yang akan mengubah tenaga pengaktifan daripada Ea to Ea1 ? A. Temperature /suhu B. catalyst/mangkin C. concentration/kepekatan D. total surface area /jumlah luas permukaan 20. Which of the following explains the meaning of effective collision?/yang manakah antara berikut menjelaskan perlanggaran berkesan? A. The collision where its energy is less than the activation energy Perlanggaran yang tenaganya kurang daripada tenaga pengaktifan. B. The collision that has a low energy /perlanggaran yang mempunyai tenaga yang rendah C. The collision which takes place before a reaction /perlanggaran yang berlaku sebelum suatu tindak balas D. The collision that causes a reaction ./perlanggaran yang menghasilkan tindak balas Structured questions 1. Soap is manufactured by mixing fatty acids with an alkaline solution. (a) Name the process of manufacturing soap. [1 mark] (b) The process stated in (a) is a combination of two processes. Name the two processes. [2 marks] (c) One type of fatty acid that can be used to produce soap is palmitic acid. Where can it be obtained from? [1 mark] (d) One of the by products of manufacturing soap is an alcohol. Name that alcohol. [1 mark]

(e)

H H H H H H H H H H H O || HCCCCCCCCCCCCOSO Na +

 || H H H H H H H H H H H H

Circle the hydrophobic part of the detergent molecule above. [1 mark] (f) Sodium carboxymethyl cellulose is added into detergents as an additive. What is its function? [2 marks] (g) State two disadvantages of using detergents. [2 marks] 2. (a) Turmeric powder is commonly used in cooking as a traditional food additive. Name two uses of turmeric. [2 marks] (b) What is tartrazine used for? [1 mark] (c) State the method that can be used to separate tartrazine from food? [1 mark] (d) State two uses of aspirin. [2 marks] (e) Barbiturate is an antidepressant used as sleeping pills and to treat fits. State one of its disadvantages. [1 mark] (f) State three important ways of taking medication. [3 marks] 2. An experiment was carried out to determine the heat of precipitation of barium sulphate, BaSO 4. The initial temperature of 50 cm 3 of 1.0 mol dm 3 barium nitrate solution was recorded and the solution was added to 50 cm 3 of 1.0 mol dm 3 potassium sulphate solution. The highest temperature of the reaction mixture was recorded. The readings of the thermometer are shown in the figure below. The mixture was stirred and the highest temperature recorded. (a) Why is polystyrene cup used? [1 mark] (b) What is the colour of the precipitate formed? [1 mark] (c) What type of reaction is this in terms of heat change? [1 mark] (d) Calculate the change in temperature. [1 mark] (e) Construct the equation for this reaction. [1 mark] (f) Calculate the heat change for this reaction. [1 mark] (g) Calculate the heat change to form one mole of barium sulphate in this experiment. [1 mark] (h) Draw the energy level diagram for this reaction. [Density of solution = 1.0 g cm 3; Specific heat capacity of water = 4.2 J g 1 oC 1]

Essay Question
1. (a) Outline an experiment to prepare a sample of soap by using coconut oil in the laboratory. [8 marks] (b) Describe the cleansing action of soap on a piece of handkerchief stained with grease. [8 marks] (c) Give two examples of traditional medicines derived from plants and state their functions. [4 marks] 2. (a) Define exothermic and endothermic reactions. Give one example for each type of reaction. [4 marks] (b) Outline an experiment to determine the heat of precipitation of lead(II) chloride. Your answer should include workings of calculations, assumptions made, and energy level diagram for the reaction. [12 marks] (c) Give the advantages of using liquid hydrogen as fuel for rockets. [4 marks]

Set II

Multiple choice
1. Analgesic is A. a type of medicine which is used as an antidepressant B. used to retard growth of microorganisms D. a type of steroid used to cure arthritis rheumatoid 2. Caffeine, nicotine, and dextroamphetamine are types of A. antipsychotic drugs B. antidepresants C. steroids

C. used to relieve pain

D. stimulants

3. Which of the following is most commonly used in the treatment of rheumatoid arthritis? A. Panadol B. Prednisone C. Codeine D. Steptomycin 4. Which of the following is true about hormones? I Hormone carries the function of controlling metabolism, physiological and homeostatic activities in the body. II Endocrine glands release hormones directly into the blood stream III Excessive use of hormones may cause side effects such as insulin shock and liver disorders. IV Females will have the characteristics of a male when testosterone is taken e\ A. I, II, and IV only B. I, III, and IV only C. II, III, and IV only D. I, II, III, and IV 5. Vineger, lime, onions, salt and cinnamon are all used as A. natural flavouring B. natural stabilisers C. natural preservatives D. natural antioxidants 6. Which of the following data are required to determine the heat of reaction between excess zinc powder and copper(II) nitrate solution? I Relative atomic mass of zinc II Volume of copper(II) nitrate solution III Concentration of copper(II) nitrate solution IV The increase in temperature of the mixture. A. I and III only B. II and IV only C. II, III, and IV only D. I, II, III, and IV. 7. The figure below shows the energy level diagram for the reaction between zinc and copper(II) nitrate solution.
Cu 2+ (aq) + Zn(s)

excessively.

Energy

H = - 190 kJ mol 1 Cu(s) + Zn 2+(aq)

What is the energy released if 2 g of copper is formed? A. 95 J B. 380 J C. 5937.5 J

[Relative atomic mass: Cu = 64] D. 6080 J

8. A mixture of 50 cm 3 of 1.0 mol dm 3 sodium hydroxide solution and 50 cm 3 of 1.0 mol dm 3 hydrochloric acid

releases 2850 J of energy. Which of the following mixtures will produce the same amount of energy? I 50 cm 3 of 1.0 KOH and 50 cm 3 of 1.0 mol dm 3 HCl II 50 cm 3 of 1.0 mol dm 3 NaOH and 1 dm 3 of 0.025 mol dm 3 H2SO4 III 50 cm 3 of 0.5 mol dm 3 NaOH and 1 dm 3 of 1.0 mol dm 3 HNO3 IV 50 cm 3 of 1.0 mol dm 3 KOH and 50 cm 3 of 1.0 mol dm 3 HNO3 A. I and II only B. I and IV only C. I, II, and IV only D. I, II, III, and IV

9. The figure below shows the energy level diagram for the combustion of ethanol in excess oxygen.
CH3CH2OH + 3O2

Energy

H = - 1366 kJ mol 1 2CO2 + 3 H 2O

What is the mass of ethanol required to release 273.2 kJ of energy? [Relative atomic mass: H=1 ; C=12; O=16] A. 4.6 g B. 9.2 g C. 13.1 g D. 46 g 10. The table below shows the heat of combustion of three alcohols. Alcohol Heat of combustion/ kJ mol 1 Methanol -725 Ethanol -1376 Propanol -2015 Which of the following statements is not true? A. Propanol is more flammable than methanol B. The heat of combustion increases from methanol to propanol C. Propanol releases the highest energy when it is burnt because it has the largest molecule D. Molecule with higher percentage of carbon releases higher amount of energy when it is burnt. 11. Which of the following conversions would involve a gain in electrons? I Hydrogen atoms are converted into hydrogen ions. II Iodine atoms are converted into iodide ions. III Manganate(VII) ions are converted into manganese(II) ions IV Iron(III) ions are converted into iron(II) ions. A. I and IV only B. II and III only C. I, II, and III only D. II, III, and IV only.

12.Aluminium can reduce the oxide of metal X but cannot reduce the oxides of metal Y and metal Z. Metal Z cannot reduce the oxide of metal Y. Of the following, which one represents the arrangement of the four metals in descending order of their reactivity? A. Y, Al, X, Z B. Y, Z, Al, X C. X, Al, Z, Y D. Al, X, Z, Y 13. A mixture of aluminium oxide, copper(II) oxide and excess zinc is heated strongly until there is no further change. Which of the following substances would be present in the final mixture? I Aluminium

II zinc oxide III Zinc IV Copper A. I and IV only B. II and IV only

C. I, II, and IV only

D. I, II, III, and IV

14. Aluminium cannot be extracted from bauxite by heating it with coke because A. Aluminium is more reactive than oxygen B. the reaction between bauxite and coke is too vigorous C. aluminium is more reactive than carbon D. aluminium is less reactive than carbon 15.

Structured questions 1. An experiment was carried out by a student to determine the heat of displacement of iron from its salt solution by
magnesium. About 4 g of magnesium powder was added into a plastic cup containing 50 cm 3 of 1.0 mol dm 3 iron(II) sulphate solution. The mixture was stirred by using a thermometer until the highest temperature was obtained. The table below shows the data of the experiment. Initial temperature of iron(II) sulphate 28.6 oC Highest temperature of the mixture 49.6 oC [Relative atomic mass: Mg , 24; density of solution, g cm 3 , Specific heat capacity of water = 4.2 J g 1 oC 1 ] (a) Besides the change in temperature, state one other observation in this experiment. [1 mark] (b) What are the data requried in calculating the heat of displacement of iron. [2 marks] (c) Construct an overall ionic equation for this reaction. [1 mark] (d) Calculate the heat change for this reaction. [1 mark] (e) Calculate the heat of displacement of iron from iron(II) sulphate by magnesium. [2 marks] (f) Draw an energy level diagram for this reaction. [2 marks] 2. The figure below shows an experiment carried out to determine the position of hydrogen in the reactivity series using two metallic oxides.

fugure 1

pg 323

The oxide of P is heated strongly. Then the experiment is repeated by using the oxide of Q. The following results were obtained. Substance Observation Oxide of P Glows in red Changes colour from reddish-brown to grey Grey product is attracted by a magnet Oxide of Q White solid does not glow Turns yellow when hot; changes back to white when cold (a) State two safety measures which you would take while doing the experiment. (b) How would you prepare dry hydrogen in the laboratory? Draw a diagram to show it. [2 marks] [2 marks]

(c) From the results given in the above table, arrange hydrogen and metals P and Q in descending order of their reactivity. [1 mark] (d) Identify the metals P and Q based on the results in the above table. Explain your answer. [2 marks] (e) Write the chemical equation for the reaction between the oxide of P and hydrogen. [1 mark] (f) Name the liquid R that is formed as shown in the above figure. State a confirmatory test [2 marks] (g) Predict what would happen if copper(II) oxide is heated in the presence of hydrogen. Explain your answer. [2 marks]

Essay questions
1. (a) A reduction is always accompanied by an oxidation reaction.

Explain the statement above in the following reactions. Write balanced equations for reactions. (i) The reaction between iron(II) chloride and chlorine. Explain in terms of change in oxidation number. (ii) The reaction between magnesium and copper(II) oxide. Explain in terms of electron transfer. (iii) The reaction between hydrogen sulphide and chlorine. Explain in terms of addition and loss of hydrogen. [12 marks] (b) Explain the rusting of iron in terms of redox reactions. [8 marks]