Set II

Multiplechoice
1. Analgesic is A. a type of medicine which is used as an antidepressant B. used to retard growth of microorganisms relieve pain D. a type of steroid used to cure arthritis rheumatoid 2. Caffeine, nicotine, and dextroamphetamine are types of A. antipsychotic drugs B. antidepresants C. steroids C. used to

D. stimulants

3. Which of the following is most commonly used in the treatment of rheumatoid arthritis? A. Panadol B. Prednisone C.Codeine D.Steptomycin 4. Which of the following is true about hormones? I Hormone carries the function of controlling metabolism, physiological and homeostatic activities in the body. II Endocrine glands release hormones directly into the blood stream III Excessive use of hormones may cause side effects such as insulin shock and liver disorders. IV Females will have the characteristics of a male when testosterone is taken e\ excessively. A. I, II, and IV only B. I, III, and IV only C. II, III, and IV only D. I, II, III, and IV 5. Vineger, lime, onions, salt and cinnamon are all used as A. naturalflavouring B. naturalstabilisers C. natural preservatives D. natural antioxidants 6. Which of the following data are required to determine the heat of reaction between excess zinc powder and copper(II) nitrate solution? I Relative atomic mass of zinc II Volume of copper(II) nitrate solution III Concentration of copper(II) nitrate solution IV The increase in temperature of the mixture. A. I and III only B. II and IV only C.II, III, and IV onlyD.I, II, III, and IV. 7. The figure below shows the energy level diagram for the reaction between zinc and copper(II) nitrate solution.
Cu 2+(aq) + Zn(s)

EnergyH = - 190 kJ mol1 Cu(s) + Zn 2+(aq)

What is the energy released if 2 g of copper is formed?[Relative atomic mass: Cu = 64]

A. 95 J D. 6080 J

B. 380 J

C. 5937.5 J

8. A mixture of 50 cm 3 of 1.0 moldm3 sodium hydroxide solution and 50 cm 3 of 1.0 moldm3 hydrochloric acid releases 2850 J of energy. Which of the following mixtures will produce the same amount of energy? I 50 cm 3 of 1.0 KOH and 50 cm 3 of 1.0 moldm3 HCl II 50 cm 3 of 1.0 moldm3 NaOH and 1 dm3 of 0.025 moldm3 H2SO4 III 50 cm 3 of 0.5 moldm3 NaOH and 1 dm3 of 1.0 moldm3 HNO3 IV 50 cm 3 of 1.0 moldm3 KOH and 50 cm 3 of 1.0 moldm3 HNO3 A. I and II only B. I and IV only C.I, II, and IV only D. I, II, III, and IV

9. The figure below shows the energy level diagram for the combustion of ethanol in excess oxygen.
CH3CH2OH + 3O2

Energy

H = - 1366 kJ mol1 2CO2 + 3 H 2O

What is the mass of ethanol required to release 273.2 kJ of energy? [Relative atomic mass: H=1 ; C=12; O=16] A. 4.6 g B. 9.2 g C.13.1 g D. 46 g 10. The table below shows the heat of combustion of three alcohols. Alcohol Heat of combustion/ kJ mol1 Methanol -725 Ethanol -1376 Propanol -2015 Which of the following statements is not true? A. Propanol is more flammable than methanol B. The heat of combustion increases from methanol to propanol C. Propanol releases the highest energy when it is burnt because it has the largest molecule D. Molecule with higher percentage of carbon releases higher amount of energy when it is burnt. 11. Which of the following conversions would involve a gain in electrons? I Hydrogen atoms are converted into hydrogen ions. II Iodine atoms are converted into iodide ions. III Manganate(VII) ions are converted into manganese(II) ions IV Iron(III) ions are converted into iron(II) ions. A. I and IV only B. II and III only C.I, II, and III only III, and IV only.

D. II,

12.Aluminium can reduce the oxide of metal X but cannot reduce the oxides of metal Y and metal Z. Metal Z cannot reduce the oxide of metal Y. Of the following, which one represents the arrangement of the four metals in descending order of their reactivity?

A. Y, Al, X, Z

B. Y, Z, Al, X

C. X, Al, Z, Y

D. Al, X, Z, Y

13. A mixture of aluminium oxide, copper(II) oxide and excess zinc is heated strongly until there is no further change. Which of the following substances would be present in the final mixture? I Aluminium II zinc oxide III Zinc IV Copper A. I and IV only B. II and IV only C.I, II, and IV only D. I, II, III, and IV 14. Aluminium cannot be extracted from bauxite by heating it with coke because A. Aluminium is more reactive than oxygen B. the reaction between bauxite and coke is too vigorous C. aluminium is more reactive than carbonD. aluminium is less reactive than carbon 15.

Structured questions 1.An experiment was carried out by a student to determine the heat of displacement of iron from
its salt solution by magnesium. About 4 g of magnesium powder was added into a plastic cup containing 50 cm 3 of 1.0 moldm3 iron(II) sulphate solution. The mixture was stirred by using a thermometer until the highest temperature was obtained. The table below shows the data of the experiment. Initial temperature of iron(II) sulphate 28.6 oC Highest temperature of the mixture 49.6 oC [Relative atomic mass: Mg , 24; density of solution, g cm 3 , Specific heat capacity of water = 4.2 J g 1oC1 ] (a) Besides the change in temperature, state one other observation in this experiment. [1 mark] (b) What are the data requried in calculating the heat of displacement of iron. [2 marks] (c) Construct an overall ionic equation for this reaction. [1 mark] (d) Calculate the heat change for this reaction. [1 mark] (e) Calculate the heat of displacement of iron from iron(II) sulphate by magnesium. [2 marks] (f) Draw an energy level diagram for this reaction. [2 marks] 2. The figure below shows an experiment carried out to determine the position of hydrogen in the reactivity series using two metallic oxides. fugure 1 pg 323

The oxide of P is heated strongly. Then the experiment is repeated by using the oxide of Q. The following results were obtained. Substance Observation Oxide of P Glows in red Changes colour from reddish-brown to grey Grey product is attracted by a magnet Oxide of Q White solid does not glow Turns yellow when hot; changes back to white when cold (a) State two safety measures which you would take while doing the experiment. [2 marks] (b) How would you prepare dry hydrogen in the laboratory? Draw a diagram to show it. [2 marks] (c) From the results given in the above table, arrange hydrogen and metals P and Q in descending order of their reactivity. [1 mark] (d) Identify the metals P and Q based on the results in the above table. Explain your answer. [2 marks] (e) Write the chemical equation for the reaction between the oxide of P and hydrogen. [1 mark] (f) Name the liquid R that is formed as shown in the above figure. State a confirmatory test [2 marks] (g) Predict what would happen if copper(II) oxide is heated in the presence of hydrogen. Explain your answer. [2 marks]

Essay questions
1. (a) A reduction is always accompanied by an oxidation reaction. Explain the statement above in the following reactions. Write balanced equations for reactions. (i) The reaction between iron(II) chloride and chlorine. Explain in terms of change in oxidation number. (ii) The reaction between magnesium and copper(II) oxide. Explain in terms of electron transfer. (iii) The reaction between hydrogen sulphide and chlorine. Explain in terms of addition and loss of hydrogen. [12 marks] (b) Explain the rusting of iron in terms of redox reactions. [8 marks]