Set V Section A

1. Which of the following statements is true of the chemical properties of halogens? A. They are reducing agents B. They form acidic oxides C. They have similar physical and chemical properties D. They oxidise iodide to iodine 2. Which of the following statements is true of oxides of elements across Period 3? A. The acidic property of the oxides decreases across the period B. Each of the oxides are soluble in water C. The melting point of the oxides decreases across the period D. The basic property of the oxides increases across the period 3 Lithium, sodium, and potassium have only electron in the outermost shell. Hence they show A. similar reactivity in their reactions with water B. similar chemical properties C. similar physical properties D. similar relative atomic mass 4. Which of the following statements is true about elements when moving down Group 17? A. The colour of the elements becomes darker B. The density decreases C. The electrical conductivity increases D. Reactivity increases 5. Magnesium nitrate decomposes when heated as shown in the following equation. 2MgO + 4NO2 + O2 2Mg(NO 3)2 Calculate the mass of magnesium oxide produced when 14.8 g of magnesium nitrate is completely decomposed by heating? [relative atomic mass: Mg = 24; N = 14; O = 16] A. 2 g B. 4g C. 6 g D. 8 g 6. The formula of ammonium phosphate is (NH 4)3PO4 and the formula of M oxide is M2O. Which of the following represents the formula of M phosphate? A. M(PO4)3 B. M2 (PO4)3 C. MPO4 D. M3PO4

7. The relative isotopic mass of an isotope

A

X
Z

is

Mass of one isotope A. -----------------------------------------------(1/16) x mass of an atom of oxygen-16 Mass of one isotope B. ---------------------------------------------------(1/12) x mass of an atom of carbon-12

Mass of one isotope

C.

---------------------------------------------------12 x mass of an atom of carbon-12

Mass of one isotope D. -----------------------------------Mass of an atom of hydrogen 8. 2SO2 + O2 == 2 SO 3 The above equation represents the reaction which occurs in the Contact process. Which of the following reactions are correct? I The pressure is 250 atmosphere II The temperature is 450 oC III The catalysed used is iron powder IV The reaction is exothermic A. I and III only B. II and IV only C. I, II, and IV only D. I, II, III, and IV

9. An aqueous solution of sodium chloride is electrolysed using carbon as electrodes. Which of the following occurs during the electrolysis? A. Chlorine gas is formed at the anode. B. Sodium metal is formed at the cathode C. Oxygen gas is formed at the cathode D. Hydroxide ions accepts electron at the anode. 10. Which of the following represents a redox reaction? A. KCl + AgNO3 AgCl + KNO3 B. Cl2 + 2FeCl2 2FeCl3 C. 2KHCO3 K2CO3 + CO2 + H 2O CH3COOK + H 2O D. CH3COOH + KOH 11.

X electrode

copper electrode

Electrolyte

A simple cell which consists of an copper electrode and electrode X is shown in the above. The galvanometer registers a reading when the circuit is completed. Which of the following metals, when used as X electrode, would the highest reading? A. Silver B. Zinc C. Tin D. Lead 12. 2CO(s) + O2(g) CO2(g) ; H = - 110 kJ mol 1

By referring to the above equation, how many moles of carbon monoxide would react with excess oxygen in order to produce 330 kJ of heat? A. 4.5 B. 5.0 C. 6.0 D. 8.0

13. Compound J is formed when ethanol is heated with ethanoic acid in the presence of a small amount of concentrated s I Insoluble in water II Fruity smell III Has a structural formula of CH3COOC2H5 IV Has ionic bonds A. I and III only B. II and IV only C. I, II, and III only D. I, III, and IV only

14. In a reaction between calcium carbonate and dilute hydrochloric acid, the rate at which carbon dioxide evolved increases when the acid is heated. Which of the following statements is true of the above experiment? I Activation energy of reaction is lowered II Average kinetic energy of particles increases III Frequency of collision between acid particles and calcium carbonate increases IV Heat of reaction increases A. I and IV only B. II and III only C. I, II, and III only D. II, III, and IV only 15. Which of the following equations can be used to prepare an insoluble salt? A. 2KOH + H 2 SO 4 2 H 2O + K 2 SO 4 B. Zn + 2HNO 3 H 2 + Zn(NO 3) 2 C. ZnCO3 + 2HCl ZnCl2 + CO 2 + H 2O D. Pb(NO 3)2 + 2KCl PbCl2 + 2KNO 3

Section B
1.
delivery tube

boiling tube

lead carbonate powder

lime water Heat

The figure above shows the set-up of an experiment to investigate the effect of heat on lead(II) carbonate powder. A colourless gas is evolved in the reaction. (a) (i) Name the gas evolved. [1] (ii) What is the function of using lime water? [1] (b) State two observations in the above experiment. [2] (c) (i) Write an equation for the decomposition of lead(II) carbonate. [1] (ii) Name the residue formed. [1] (iii) Calculate the maximum mass of the product formed when 2.67 g of lead(II) carbonate is completely decomposed. [relative atomic mass: Pb = 207; C = 12; O=16] [2]

(iv) Calculate the number of molecules of the gas formed above. [Avogadro number = 6 x 10 23 per mol] [1] 2+ (d) Describe what happens when sodium hydroxide solution is added to a solution which contains Pb ions. [1] 2. The flow chart below shows the conversion of ethene into some other compounds.
Step I P Bromine in tetrachloromethane Step II in air Complete combustion Ethene + water Q

Ethanol

Step III

esterification

CH3COOCH2CH3

(a) Ethene is an unsaturated hydrocarbon. (i) Explain what is meant by hydrocarbon? (ii) What do you understand by `unsaturated`? (b) Draw the full structural formula of ethene. (c) (i) Write the full structural formula of compound P. (ii) State the observation in step I. (d) (i) What is meant by `esterification`? (ii) Name the reagents and condition in Step III. (iii) Write an equation for the reaction in Step III. (e) Name compound Q. Section C 1. (a) The heat of combustion of four types of alcohol is shown below Alcohol Formula of alcohol Heat of combustion / kJ mol 1 Methanol CH 3OH - 500 Ethanol CH 3 CH 2OH - 1050 Propanol CH 3 CH 2 CH 2OH - 1600 Butanol CH 3 CH 2 CH 2 CH 2OH - 2100

[1] [1] [1] [1] [1] [1] [2] [1] [1]

(i) Plot a graph of heat of combustion against number of carbon atoms.(You may ignore the negative sign of the heat of combustion]. [3] (ii) Based on your graph, predict the heat of combustion of pentanol, C5H11OH. [2] (iii) With reference to methanol, define heat of combustion. [2] 3 (iv) In an experiment, 0.46 g of ethanol was completely burnt to heat up 500 cm of water. Calculate the temperature of the water. [relative atomic mass: C=12; H=1; O=16; Specific heat capacity of water = 4.2 J g 1 oC 1]

[4] (v) Explain why the heat of combustion of alcohol increases down the homologous series. [3] (b) (i) A very important step in the Contact process for the manufacture of sulphuric acid involves the conversion of sulphur dioxide to sulphur trioxide. Describe the industrial reaction conditions used in order to maximise the production of sulphur trioxide. [4] (ii) Calculate the percentage of nitrogen in ammonium phosphate, (NH4)3 PO 4 , and urea, CO(NH2)2. [relative atomic mass: C=12; N=14; P=31; O=16; H=1] [2]