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SULIT 4541/3 Chemistry Paper 3 May 1 1/2 hours JABATAN PELAJARAN MELAKA ____________________________________________________________ UJIAN PENGESANAN PERTENGAHAN TAHUN

SIJIL PELAJARAN MALAYSIA 2009

CHEMISTRY Paper 3 One hour and thirthy minutes

MARKING SCHEME

Question 1 (a) (i)

Rubric Able to record all readings accurately to one decimal point with unit Sample answer: Set I: 55.0s Set II: 48.0s Set IV: 37.0s Set V: 33.0s Set III: 42.0s

Score 3

Able to record all readings correctly without unit / without decimal point Sample answer: Set I: 55.0 / 55s Set IV: 37.0 / 37s 2 Set II: 48.0 / 48s Set V: 33.0 / 33s Set III: 42.0 / 42s

Able to record three readings correctly Sample answer: Set I: 55 Set II: 45.6 Set IV: 37 Set V: 30.6 1 Set III: 42

No response or wrong response 1 (a) (ii) Able to construct a table that contain: 1 Correct titles 2 Readings and units Sample answer Set I II III IV V Temperature / 0C 30.0 35.0 40.0 45.0 50.0 Time taken / s 55.0 48.0 42.0 37.0 33.0

Note : ecf for the time taken for Set I to Set V Able to construct a less accurate table that contain: 1 Titles 2 Readings without unit

3 Question Sample answer Set I Set II Set III Set IV Set V Temperature 30.0 35.0 40.0 45.0 50.0 Time taken 55.0 48.0 42.0 37.0 33.0 Rubric Score

Able to construct a table with at least two title Sample answer Temperature 30 35 40 45 50 Time taken 55 48 42 37 33

No response or wrong response 1 (b) Able to give the relationship accurately and state the direction.

3 Sample answer: The higher the temperature, the shorter the time taken for magnesium ribbon to completely dissolved. Able to give the relationship correctly without state the direction 2 Sample answer: Temperature affects time taken for magnesium ribbon to completely dissolve. Able to give an idea of the relationship Sample answer: Time for magnesium ribbon to dissolve become shorter 1

4 Question 1 (c) Rubric No response or wrong response Able to state all three variables correctly Manipulated variable: Responding variable: Constant variable: Sample answer: Temperature Time taken Concentration & volume of hydrochloric acid // length of magnesium ribbon Score 0

Able to state any two variables correctly Able to state any one variables correctly No response or wrong response 1 (d) Able to give accurate reading ( 37.0s < X < 42.0s) to one decimal point with unit

2 1 0

3 Sample answer: 38.0s // 39.0s // 40.0s // 41.0s Able to give correct reading without decimal point / unit Sample answer: 38s // 39.0 // 40s // 41.0 Able to give range of reading without decimal point / unit Sample answer: (37.0 < X < 42.0) No response or wrong response 2 (a) Able to draw a graph of the height of precipitate against volume of potassium chromate(VI) by showing the following information 3 i. ii. The axes are labeled correctly with unit Uniform scale & size of the graph at least 50% of the 1 2

5 Question Rubric graph paper iii. All points are transferred correctly Able to draw a graph of the height of precipitate against volume of potassium chromate(VI) by showing the following information 2 i. ii. The axes are labeled correctly without unit All points are transferred correctly Score

Able to draw a graph of the height of precipitate against volume of potassium chromate(VI) by showing the following information 1 i. The axes are labeled correctly without unit ii. Curve / straight line on the graph No response or wrong response 2 (b) Able to state the observation correctly Sample answer: The height of the precipitate increases from test tube 1 to test tube 4 and become constant from test tube 5 to test tube 7. Able to state the observation incompletely. Sample answer: The height of the precipitate increases and then become constant Able to state an idea of the observation Sample answer: The height of the precipitate increases. No response or wrong response 2 (c) Able to state the inference correctly Sample answer: The reaction has been completed at test tube 5 because the height of precipitate becomes constant from test tube 5 to test tube 7. Able to state the inference incompletely. Sample answer: The reaction has been completed when the height of precipitate becomes constant. 2 3 1 2 3 0

6 Question Rubric Able to state an idea of inference. Sample answer: The reaction has been completed at test tube 5 No response or wrong response 2 (d) Able to state the relationship correctly between the manipulated variable and the responding variable with direction. 3 Sample answer: As the volume of potassium chromate(VI) increased, the height of the precipitate increase until it achieves a maximum height. Able to state the relationship between the manipulated variable and the responding variable with direction. 2 Sample answer: When the volume of potassium chromate(VI) increased, the height of the precipitate also increase. Able to state the idea of hypothesis. Sample answer: The height of the precipitate increase. No response or wrong response 2 (e) Able to state the correct operational definition for continuous variation method correctly. 3 Sample answer: The height of precipitate formed will increased and remain constant when a fix volume of lead(II) nitrate solution is added with potassium chromate(VI) solution. Able to state the meaning of continuous variation method incompletely. Sample answer: The height of precipitate formed will increased and remain constant when lead(II) nitrate solution is added with potassium chromate(VI) solution. 2 1 1 0 Score

7 Question Rubric Able to state an idea of continuous variation method. Sample answer: Precipitate will formed when lead(II) nitrate solution is added with potassium chromate(VI) solution. No response or wrong response 2 (f) Able to classify all the six ions correctly. Sample answer: Positive ion / Cation Pb2+ K+ H+ 3 Negative ion / Anion NO3IOH1 Score

Able to classify any four ions correctly. Sample answer: Positive ion / Cation Pb2+ K+ 2 Negative ion / Anion NO3I-

Able to classify any two ions correctly. Sample answer: Positive ion / Cation Pb2+ NO3+ No response or wrong response 3 (i) Able to give the statement of the problem accurately by relating the following four information: i. Position / distance ii. Pair of metals // two metals iii. Electrochemical series (ECS) iv. Voltage Sample answer: How does position between two metals in the Electrochemical 1 Negative ion / Anion IK0

8 Question Series affect the voltage? Able to give the statement of the problem correctly by mention i. position / distance // pair of metal ii. ECS / Reactivity Series iii. Voltage Sample answer: Does the position of metals in ECS affect the voltage? // Does the position of electrode in Reactivity Series affect the voltage? // Does the distance of metals in ECS affect the voltage Able to give an idea of statement of the problem correctly Sample answer: Metals/electrode produces voltage. No response or wrong response 3 (ii) Able to state all three variables correctly Manipulated variable: Responding variable: Constant variable: Sample answer: pairs of metals // two electrodes Voltage // voltmeter reading // potential difference Electrolyte // volume & concentration of electrolyte // metal as the positive / negative terminal 3 1 2 Rubric Score

Able to state any two variables correctly Able to state any one variables correctly No response or wrong response

2 1 0

9 Question Rubric Able to state the relationship between the manipulated variable and the responding variable and state the direction 3 (iii) Sample answer: The further / nearer the distance of the two metals in Electrochemical Series, the bigger / smaller the voltage. Able to state the relationship between the manipulated variable and the responding variable without stating the direction 2 Sample answer: The distance between metals in ECS affect the voltmeter reading Able to state the idea of hypothesis correctly 1 Sample answer: Different metal produces different voltage No response or wrong response 3 (iv) Able to give complete list of substances and apparatus i. At least three metal below Ca in ECS ii. Voltmeter iii. Electrolyte, beaker, wire, sand paper Sample answer: Aluminium, zinc, copper, voltmeter, copper(II) sulphate solution, beaker, connecting wires, sand paper Able to state the following things i. At least two metal below Ca in ECS ii. Voltmeter iii. Electrolyte, container Sample answer: Zinc, copper, voltmeter, copper(II) sulphate solution, beaker, Able to state the following things i. two metals ii. electrolyte Sample answer: 0 3 Score

10 Question Rubric Aluminium, zinc, sodium hydroxide solution No response or wrong response 3 (v) Able to state the following six steps 1. 2. 3. 4. 5. 6. Add/pour the electrolyte into a container Clean the metal strip with sandpaper Dip both metals into the electrolyte Connect the metals to the voltmeter// complete the circuit Record the voltmeter reading Repeat step 1-5 by substituting one metal for another 3 Score 0

Step 1 or 3, 4, 5, 6 Step 1 or 3 No response or wrong response 3 (vi) Able to exhibit the tabulation of data that includes the following information: 1. Heading for manipulated variable 2. Heading for the responding variable with unit 3. Examples of two pairs of metals Sample answer: Pair of metals Zinc and copper Iron and copper

2 1 0

Voltage / V

Able to exhibit the tabulation of data that includes the following information: 1. Heading for manipulated variable 2. Heading for the responding variable without unit 3. Examples of one pairs of metals

11 Question Sample answer: Pair of metals Zinc and copper Rubric Voltage Score

Able to exhibit the tabulation of data that includes the following information: Heading for the (manipulated variable) / (responding variable without unit) Sample answer: Pair of metals

No response or wrong response END OF MARK SCHEME

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