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4541/2 Chemistry Paper 1 Paper 2

May 2009 Marking Scheme

JABATAN PELAJARAN MELAKA

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UJIAN PENGESANAN PERTENGAHAN TAHUN SIJIL PELAJARAN MALAYSIA 2009

MARKING SCHEME CHEMISTRY Paper 1 and Paper 2

Kertas soalan ini mengandungi 10 halaman bercetak 4541/2 [Lihat sebelah

SKEMA PERMARKAHAN CHEMISTRY 1 4541/1

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1 2 3 4 5 6 7 8 9 10

D C A D C D A B B B

11 12 13 14 15 16 17 18 19 20

D A B C B D C D D B

21 22 23 24 25 26 27 28 29 30

D C A C B A A C B C

31 32 33 34 35 36 37 38 39 40

B B C C B D A A C C

41 42 43 44 45 46 47 48 49 50

B A A B D A A D D A

3 PAPER 2 SECTION A

No 1(a) (i) (ii) (iii)

Marking Scheme 14 B Correct number of shells Correct number of electrons at each shells Correct number of proton in nucleus Correct number of neutron in nucleus Examples:

Mark 1 1 1 1 1 1 1 1 4

(b)

(i) (ii)

P: liquid S: solid Has weak force of attraction between molecules Need low energy to overcome the force of attraction

1 1 1 1

2 2 10 1 1 1 1 1 1 1 1 1 2

(a) 1. Formula that shows the simplest ratio

2. the number of atoms for each element in the compound.

(b) Anhydrous calcium chloride//concentrated sulphuric acid (c) To remove all the air in the tube (d) 1. Repeat the process of heating, cooling and weighing
2. until a constant mass is obtained

(e) 1. 2. 3. 4.

[Determine the mass of Pb and O correctly] [Calculate the no. of mole of Pb and O correctly] [Determine the simplest ratio of mole of Pb and O correctly] [State the empirical formula correctly] Pb 4.14 g 4.14/207 // 0.02 0.02/0.02 = 1 PbO2 O 4.78 4.14 // 0.64 g 0.64/16 // 0.04 0.04/0.02 = 2

Examples: Mass/g No.of mole Simplest ratio Empirical formula (f)

Magnesium is more reactive than hydrogen // Hydrogen is less reactive than magnesium // Hydrogen cannot reduce the magnesium oxide // Hydrogen is below magnesiumin reactivity series.

10 3(a) 1. Correct formula of reactant 2. Correct formula of product 3. Balance of equation Examples: 4Na + O2 2 Na2O Colourless turn to pink Burn very rapidly//White fume are produced//produced white solid when cooled. (i) (ii) (iii) Have 3 shells occupied/fill with electrons Decrease Number of shell filled with electron still same/three Number of proton and electron increase The nucleus attraction will increase // nuclei attraction on the valence electron increases 1 1 1

(b) (c)

1 1 1 1 1 1 1

1 1 1 1

(d)

3 10

(a) 1. Substances that conduct electricity 2. in molten state or aqueous solution 3. undergoes chemical changes

(b) Mark (+) at electrode P and (-) at electrode Q correctly (c) (i) (ii) (d) (i) (ii) Brown gas Bromine Na+ , Cl- , H+ , OHElectrode R Cl- , OH1 mark Electrode S Na+ , H+ 1 mark

1 1 1 1

1+1

2 1 1 1 10

(iii) Chloride (iv) Concentration of chloride ions is higher than hydroxide ions (v) 2Cl- Cl2 + 2e

5(a) (b) (i)

1. Functional apparatus and labeling of water 2. [Correct apparatus to collect gas] e.g measuring cylinder 1. Correct axis 2. Correct scale 3. Transferring of point and smooth curve 1. Able to draw the correct tangent at 40 s 2. Able to state the rate of reaction with correct unit Range : 0.85 k 0.88 1. [Able to draw the graf which steeper than the first graph and has the same maximum volume of gas collected] 2. Labelled the graph. Mass of zinc decrease.

1 1 1 1 1 1 1

3 2

(ii)

(c)

1 1 1

2 1 10

(d)

(a) (i) (ii)

Alcohol OH H H l l l H- C C C H l l l H H H

1 H H OH l l l or H C C C H l l l H H H 1 1 1

(b)

1. Correct formula of reactants and products 2. Balance the equation Example: C3H7OH + 9/2O2 3CO2 + 4H2O Propanoic acid Dehydration 1. [Functional diagram] 2. [Labeled Al2O3, glass wool + propan-1-ol and heat] 1. Hexene burns with more sooty flame 2. Percentage of carbon by mass in hexane is higher// [show calculation]

(c) (d) (i) (ii) (e)

1 1 1 1 1 1 2 2 10

PAPER 2 SECTION B 7 (a) (b)(i) Change of quantity of reactant/ product Time taken 1. 2. 3. Mg + Formula of reactants Formula of products Balance chemical equation 2HCI MgCI2 + H2 1 1 1 1 1 1 1 1 1 3 5 1

1mol Mg = 1 mol H2 0.2g X 24 = 0.2 dm3 24 (ii) 1. Both axes labeled with correct unit 2. [Experiment III is more steeper than Experiment II , Experiment I is the less steeper] 3. Same maximum volume of gas collected

(iii) Experiment I 0.2 / 0.004 50 (iv) II 0.2 / 0.010 20 III 0.2 / 0.013 15 1+1+1 3

1.Concentration of acid in experiment II is higher than experiment I. 2. Number of particles per unit volume is higher in Exp. II. 3. Collision between particles is higher in Exp. II. 4. Frequency of collision between particles is higher in Exp. II. 5. Frequency of effective collision also higher in Exp. II. 6. Experiment III using catalyst but not in Experiment II 7. Catalyst lower the activation energy. 8. Frequency of effective collision in Exp. III is higher than in Exp. II.

1 1 1 1 1 1 1 1 8 20

(a) (i)

1. [Example of strong acid] H2SO4 // Sulphuric acid // HCl // Hydrochloric acid // HNO3 // Nitric acid 2. Strong acid ionised completely in water 3. formed H+ with higher concentration 4. [Example of weak acid acid] CH3COOH // ethanoic acid 5. Weak acid ionised partially in water 6. formed H+ with lower concentration

1 1 1 1 1 1 1 Max 4

(b) (i)

1. Correct formula of reactants 2. Correct formula of products 3. Balance H2SO4 + 2 KOH K2SO4 + 2 H2O

1 1 1

4. The no. of mol of H2SO4 = 22 x 0.1/1000 // 0.0022 5. Mol of KOH = 2 x 0.0022 // 0.0044 6. Molarity of KOH = 0.0044x 1000 /25 // = 0.176 mol dm -3 OR 0.1 x 22 4. Mb x 25 = 2 1

1 1 1 6

5. Mb = 2 x 0.1 x 22 25 6. 0.176 mol dm-3

(c)

[chemical substances [ apparatus [procedure [chemical equation

- 1 mark] - 1 mark] - 7 marks] - 1 mark] 1

Sample answer : 1. [chemical substances] magnesium powder /magnesium oxide(Hydroxide, carbonate) and sulphuric acid 2. [ apparatus] Beaker, filter funnel, filter paper, glass rod [procedure] 3. [20 100] cm3 sulphuric acid [0.5 2.0 ] mol dm-3 is poured into a beaker 4. magnesium powder is added to sulphuric acid until undissolved /excess / no more effervescence 5. Stir 6. the mixture is filtered 7. the filtrate is evaporated until saturate (one-third of it original volume) 8. the saturated solution is then allowed to cool to room temperature. 9. crystals is dried between filter paper 10. [chemical equation] Mg + H2SO4 MgSO4 + H2 // MgO + H2SO4 MgSO4 + H2O// MgCO3 + H2SO4 MgSO4 + CO2 + H2O

1 1 1 1 1 1 1 1 10

20

(a) (b)

Substance/compound that contains carbon and hydrogen only 1. n(CH2) = 56 12n + 2n = 56 2. n = 4 3. Molecular formula C4H8 1 1 1

3 6

(c)

1. [Correct structural formula] 2. [ Correct name] Examples:

1+1+1 1+1+1

But-1-ene

But-2-ene

2-Methylpropene

(d)

[chemical substances and quantity - 1 mark] [ apparatus - 1 mark] [procedure - 5 marks] [Observation 1 mark] [chemical equation - 2 mark]
1. [2-5] cm3 ethanol and [2-5] cm3 butanoic acid 2. boiling tube 3. Add ethanol to butanoic acid 4. Shake the mixture 5. Add a little drop of concentrated sulphuric acid 6. Heat it 7. Poured into a beaker of water 8. The product form has a fruity smell 9. Correct formula of reactants 10. Correct formula of products

1 1 1 1 1 1 1 1 1+1

10

C3H7COOH + C2H5OH C3H7COOC2H5 + H2O

10

10

(a) (b)

Haber process i) Formula of reactant ii) Formula of product iii) Balance of equation 1. N2 + 3H2 2. 3. 4. 5. 2 NH3

1 1 1 1

1 volume of nitrogen gas to 3 volume of hydrogen gas Pressure at 200 atm. Temperature at 4500 C Catalyst : Iron

1 1 1 1

(c)

Apparatus : Retort stand with clamp, [1 kg] weight, steel ball bearing metre rule. Material : Copper block, bronze block, cellophane tape, thread. 1. Stick a stell ball bearing onto the copper block using cellophane tape. 2. Hang 1 kg weight at a height of 50 cm above the ball bearing. 3. Drop the weight so that it hits the ball bearing. 4. Measure the diameter of the dent made on the copper block. 5. Repeat step1 to 4 twice on the other parts of the copper block. 6. Repeat step 1 to 5 using the bronze block to replace the copper block. 7. [Diagram ] - Functional diagram 8. [Diagram ] labelling of copper/bronze block, steel Ball bearing, metre rule, weight 1. Fibre glass 2. High tensile strength // low density// easily moulded

1 1 1 1 1 1 1 1 1 1 1 1 10 2 20

(d)

END OF MARKING SCHEME