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pH1 = 2 ,9

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pKA2(C6H5COOH/C6H5COO-) = 4,2

pH2 =3 ,1

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[HCOOH (aq)] = c ; [C6H5COO – (aq)] = c ; [C6H5COOH (aq)] = c' ; [HCOO – (aq) ] = c'.
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HCOOH(aq) + H2O(l)
HCOO–(aq) + H3O+
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xéq = 1,3×10–5 mol
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HCOOH (aq) + C6H5COO – (aq)
HCOO –(aq) + C6H5COOH(aq)


























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 C6 H 5COOH (aq)  éq .[ HCOO − (aq) ]éq
K =

C6 H 5COO − (aq)  éq .[ HCOOH (aq) ]éq

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HCOO (aq) + H3O KA 1 =
[ HCOOH (aq)]éq
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C6H5COOH(aq) + H2O(l)
C6H5COO (aq) + H3O KA2 =
C6 H 5COOH (aq)  éq

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[C H COOH ] 6 [HCOO ]. [H O ]
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K = [C H COO ]. [H O ] [HCOOH ]− +
6 5 ( aq ) eq 3 eq ( aq ) eq

K A1 10 − pK A1
K= = − pK A 2 = 10 pK A 2 − pK A1
K A 2 10
K = 104,2–3,8 = 100,4 = 2,5

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C6 H 5COOH (aq )  i .[ HCOO − (aq ) ]i
Qr,i =
C6 H 5COO − (aq )  i .[ HCOOH (aq ) ]i
c'.V c'.V
. c '²
Qr,i = 4V 4V =
c.V c.V c²
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4V 4V
(5, 0 × 10−3 )²
Qr,i = = 0,25
(1, 0 × 10−2 )²

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(2.2.2Qr,i = K ‫و‬ =K
c²
c'² = K.c²
c' = K.c² = c. K
c' = 1,0×10–2 × 2,5
c' = 1,6×10–2 mol.L–1


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