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Characteristics of arsenic
Arsenic is a chemical element of group 15 in the periodic table It is a metalloid, which in its elemental form appears either as a
nature
Arsenic is present in a number of different forms and oxidation
Sources of arsenic
Arsenic is the natural constitute of earth crust
It is the 20th most abundant element of earth crust The average concentration As in continental crust is 1-10 mg/kg It released into environment by the process weathering and
volcanic eruption it may be transported over a long distance as suspended particulate and aerosol by water and air human activities such as the combustion of fossil fuel, chemical manufacturing industries, the use of fertilizers and wood preservatives as well as from mine waste also release AS in Environment .
Arsenic release according to hydroxide reduction hypothesis The reductive dissolution is driven by the microbial metabolism of sedimentary organic matters in anaerobic environment. The extent of arsenic release depends on the amounts of arsenicbearing ferric oxy-hydroxide and organic matter present in sediments.
phosphate fertilizer over the past few years But there is no causal link between arsenic and the application of fertilizer. Among other reasons experiments showed that only 2 g/L of arsenic would be desorbed by 5 g/L phosphorus concentration in groundwater.
included arsenic in the category of toxic substances and established 200 ppb as the allowable concentration in drinking water (WHO, 1958) In updated standards of 1963, WHO lowered the allowable concentration to 50 ppb (WHO, 1963) The WHO continued its review work to lower the guideline value for arsenic in drinking water by establishing a guideline value (provisional) of 10 ppb in 1993 (WHO 1993).
Mode
Recent Instant
Chronic
10 year old children are developing the arsenicosis Cancers appear after 20 years Huge epidemic expected in the near future
Social Problems
is the application of field kits All field kits are based on the mercuric bromide stain method AAS (Atomic-Absorption Spectroscopy)
Ion exchange processes, specifically anion exchange Membrane processes, including nano-filtration, reverse osmosis and
electrodialysis.
Emerging methods
Fe-Mn-Oxidation
Green sand filtration Coagulation assisted Microfiltration
Conclusion
No doubt , International and national research groups are working on the investigation of the origin of the arsenic and methods for arsenic removal . But there is a need of the further development of simple and low cost determination methods as well as sustainable technology for arsenic treatment of groundwater and improved medical treatment for those suffering from chronic arsenic toxicity.
References
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Nickson, R.; McArthur, J.; Burgess, W.; Ahmed, K.M.; Ravenscorft, P.; Rahman, M. Arsenic poisoning of Bangladesh groundwater. Nature 1998, 395, 338 Singh A.K., 2004, Arsenic Contamination in Groundwater of North Eastern India, Eastern Regional Institute of Water and Land Management Neriwalm.
Islam, F.S.; Gault, A.G.; Boothman, C.; Polya, D.A.; Charnock, J.M.; Chatterjee, D.; Lloyd, J.R. Role of metal-reducing bacteria in arsenic release from Bengal delta sediments. Nature 2004, 430, 68-71.
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