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Objective of Research
Research Methodology Material Description and Technique used Course Work Details
Work of Adhesion
Definition: The work of adhesion is the separation to create two new surfaces from one interface or The free energy change, or reversible work done, to separate unit areas of two media 1 and 2 from contact to infinite in vacuum. Jacob.N. Israelachvili
1
1
1
= 11 2
1 2
12
1 2
12 = 1 + 2 12
121
1
= 212 2
3
1
132
132 = 12 + 33 13 23 Where 1 , 2 Surface energy per unit area of surface 1 and 2 Date: 15/02/2013 1/3
Mallikarjunachari.G
Adsorption Effect
12 = 1 + 2 12 12 = 1v + 2v 12
1 differs from 1v by the spreading pressure which represents the lowering of the surface energy of material in vacuum by adsorption of the vapour 1= 1 - 1v
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OWRK
(mJ/m2) Diiodomethane Ethylene Glycol Formamide Water 50.8 48.0 58.0 72.8 50.8 29.0 39.0 21.8 0.0 1.9 2.3 25.5 0.0 47.0 39.6 25.5 50.8 29.0 39.0 21.8 0.0 19.0 19.0 51.0
Ref: Thesis
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Fowkes Theory:
Assumptions: Additivity
= + + + + +. . . d = dispersion force p = polar force h = hydrogen bonding force i = induction force(Debye) ab= acid/base force
Geometric Mean
12 = 2 1 2 12 = 2 1 2 1 2
Dispersion
Polar
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Method of OW (Owens-Wendt)
2
Dispersion (London dispersion Van der Waals)
0.5
3
Van der Waals
Dipole dipole, dipole induced dipole and London
Acid Base
+ +
0.5 0.5
+ + + + + +
0.5 0.5
+ + + + + +
0.5
0.5
0.5
0.5
=
Where = surface free energy of solid = Dispersion component = Polar component Mallikarjunachari.G
+ = 2
0.5
= +
+ , =Acid , Base interactions
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2. Material Transitions Eg: glass and crystalline transitions, contaminants and adsorbed materials polar and apolar interactions, drop dimension, surface crystallinity, molecular weight and conformation of chains.
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Contact Angle Measurements (degrees) Substrate Glass Diiodomethane 34.7(2.2) Distilled Water 49.5(3.1) Glycerol 48.5(3.5)
Epoxy
26.6(1.8)
70.6(3.9)
62.5(2.6)
Glass
Epoxy Silica Epoxy
42.2
45.6 78.0 41.2
0.43
0.02 -
27.4
10.39 -
6.9
0.9 209.0 5.0
49.1
46.5 287.0 46.2
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Specific Assumption
Surface must be smooth at the 0.1 to 0.5 m level Surface must be homogeneous at the 0.1 m level and above
Effect on Hysteresis
increase with increasing roughness (adv. increases and rec decreases with increasing roughness) adv. dependent on low energy phase: rec dependent on high energy phase
Time Dependent
No
Surface is homogeneous
No
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Specific Assumption
Modulus of elasticity in surface > 3x105 dyne/cm Liquid molecular volume > 60-70 ccmole Reorientation time at time of measurement Configurational entropy independent of local environment
Effect on Hysteresis
Not known
Time Dependent
Yes due to surface deformation/relaxation effects Yes due manly to diffusion
Increased tendency to orient lends to increased hysteresis Unknown but probably increase in hysteresis as surface mobility increases
Yes
Yes
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