1.

Introduction
4C-computer, communication,
consumer electronics, car electronics
and 3C
Application and development
2. Knowledge for OLED
Development of organic material
in OLED
particular characteristics of
organic material
Energy level
Mechanism
3. Charge Injection and
transmission material
a. Cathode material ( lower schottky barrier)
b. Anode material ( improve work function)
c. HIM (hole injection material)
d. HTM (hole transporting material, high Tg)
e. EIM (electron injection material, for
electronegativity)
f. ETM/HBM (electron transporting material
and hole block material, high Tg)
Cathode material ( lower schottky barrier)
For LUMO, use Alq3 layer to be Cathode material and Mg
(table 3-1)
compound metal: Ca, K, Li, high chemical active(Mg:Ag and Li:Al)
Anode material: ( improve work function)
transparent conducting oxide, TCO and metals , such as
ITO, ZnO, AZO (Al:ZnO) and Ni, Au, Pt, the substrate
must less than 15nm
HIM (hole injection material)
For LG
Theory of P type dopant

P type layer and energy-transfer

EIM
(electron injection material)
1. alkaline metal compounds
2. Al and Ag Li2O, LiBO2, K2SiO3,
CsCO3 and CH3COOM: M=Li,
Na,
K, Rb or Cs
3. N type dopant (lower schottky
barrie)
ETM/HBM (electron transporting material
and hole blocking material, high Tg)
1. ETM- oxadiazole derivatives and dendrimers
2-(4-biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole(PBD)
2,5-bis(4-naphthyl)-1,3,5-oxadiazole(BND) table 3-12
2. Metal chelates
3. Azole-based materials- triazole, triazine, imidazole, thiazole,
thiadiazole derivatives
4. quinoline derivatives
5. quinoxaline derivatives
( bis (phenylquinoxaline) BPQ and tris (phenylquinoxaline) TPQ)
6. anthrazoline derivatives
(diphenyl anthrazoline)
7. phenanthrolines derivatives
( bathophenanthroline BPen and 2,9-dimethyl-4,7-diphenyl-1,10-
phenanthroline BCP)
8. siloles compounds
9. perfluoro p-(phenylene)s oligomer(high Tm)
10. others
1. ETM-
oxadiazole derivatives and
dendrimers

PBD
2-(4-biphenyl)-5-
(4-tert-butylphenyl)-1,3,4-
oxadiazole(PBD)

BND
2,5-bis(4-naphthyl)-1,3,5-
oxadiazole
2. Metal chelates
3. Azole-based materials- triazole, triazine, imidazole,
thiazole, thiadiazole derivatives
4. quinoline derivatives
5. quinoxaline derivatives
( bis (phenylquinoxaline) BPQ
and tris (phenylquinoxaline) TPQ)
6. anthrazoline derivatives
(diphenyl anthrazoline)
7. phenanthrolines derivatives
( bathophenanthroline BPen and
2,9-dimethyl-4,7-diphenyl-1,10
-phenanthroline BCP)
8. siloles compounds
9. perfluoro p-(phenylene)s oligomer (high Tm)
10. others
4. phosphor luminescence
material
• a. red light material
• b. green light material
• c. blue light material
• d. sky blue
• e. yellow light
• f. white light
a. red light material
red dopant-DCM and DCJ
Non-dopant material (red light)
b. green light material

1. coumarins
The best one is C-545T
10-(2-benzothiazolyl)1,1,7,7-
tetramethyl-2,3,6,7-tetrahydro
-1H,5H,11H-[l]-benzopyrano-[6,7,8-ij]
quinolizin-1-one
2. quinacridone derivatives
Quinacridone(QA)-Pioneer
3. polycyclic aromatic hydrocarbon, PAH from Mitsubishi chemical
4. 1H-pyrazole[3,4-b]quinoxaline
PAQ-Net2 and PQ2

5. others
Bioluminescence GPF and

GPF3
c. blue light material
AND, Diarylanthracene, di(styryl)arylene (DSA), fluorrene, pyrene
D. Sky Blue

• Tetra(t-butyl)perylene(TBP)
• Diphenylamino-di(styryl)arylene
• Pyrene
• Fluorene
• Spirobifluorene
Tetra(t-butyl)perylene(TBP)