Professional Documents
Culture Documents
AB2
AB2
AB3
AB4
109. 5
107
104 .5
Methane (CH4)
Ammonia (NH3)
Water (H2O)
Formaldehyde (H2CO)
10
11
Note: because nonbonding electron pairs exert larger repulsion than bond pairs, 12 they always occupy the equatorial positions in AB5 molecules
Note: the placement of a single nonbonding electron pair in an AB6 molecule is arbitrary. The placement of two nonbonding pairs must be on opposite sides of 13 the octahedron.
Tetrahedral
H H C H
H C
.. O ..
H
14
Given that the dipole moment for HCl ( ) = 1.03 D how much separation of charge exists between the H and Cl atoms. = Qr 1.03D ( 3.33 x 10-30 C-m/D) = Q (1.36 A) (1x 10-10m/A)
Q = 2.52 x 1020C
%Q = (2.52 x 1020C/1.6 x 10-19C)x 100 = 15.8
15
The polarity of a molecule is dependent upon both the polarities of the bonds and the geometry of the molecule
16
17
18
-bonds
-bonds
Formaldehyde (H2CO)
-bonds: result from the overlapping of two p-orbitals, one from each atom. These covalent bonds are constructed from overlapped regions above and below the internuclear axis
19
Covalent Bonding and Orbital Overlap: Hybrid Orbitals :F : Be F : : 1s2 2s2 2p5
1s2 2s2
2p5
In order for an overlap to occur Beryllium must provide unpaired electrons. This is accomplished by promoting one of the 2S electrons
1s2 2s1
1s2 2s2
In order for each of the bonds to be identical, the 2s1 and 2p1 orbitals become hybridized
1s2
2sp
: 2p1 2p
20
Be
Fluorine 2p orbitals
21
1s2
2s 2
2p1
22
1s2 2s1
2p1
In order for each of the bonds to be identical, the 2s1 and 2p1 orbitals become hybridized
1s2
2sp2
2p
23
24
1s2 2s2
109. 5
2p1
promote
1s2
sp3
25
26
3s2
Phosphorous Pentafluoride (PF4)
3p3
promote
3d
3s2
3p3
3d
hybridize
Atoms in the third period and beyond can use their d orbitals
3sp3d
3d
27
28
29
1s2 2s2
2p2
promote
1s2 2s1
2p3
hybridize
1s2
sp2
2p
30
Note that the bond angles are probably trigonal planar. This suggests an sp2 configuration with one electron remaining in an unhybridized 2p orbital
31
1s2 2s2
2p2
promote
1s2 2s1
2p3
hybridize
1s2
sp
2p2
Note that the bond angles are probably linear. This suggests an sp configuration 32 with each of the two remaining electrons located in unhybridized 2p orbital
33
34
antibonding orbitals
bonding orbitals
Contour Representations
36
37
38
39
40
2p 2p
41
42
43