Professional Documents
Culture Documents
ECONOMICS OF CORROSION
In the United States alone, the cost of corrosion to the economy has been variously estimated at between 10 and 15 billion dollars annually. Worldwide, that figure balloons to over 45 billion dollars. Corrosion of metals in soils represents a substantial portion of that cost.
OUTLINE
Affected Facilities Factors Affecting Corrosion Soil Corrosivity Corrosion Mechanisms Corrosion Control Methods Sacrificial Anodes References Additional Questions
Affected Facilities
Buried Structures:
Underground Storage Tanks Transmission & Distribution Pipelines Foundations Cables
Corrosion Damage
Reduced Life of Structures
I-35 Bridge Collapse
Aeration
More Air = Less Corrosion Drier Environment Reduces Galvanic Action
Order of Increasing Corrosion: Gravels Coarse Sands Fine Sands
Water Retention
More Water = More Electrolyte = More Corrosion
Soil Resistivity
Resistivity vs Corrosivity
Soil Resistivity,(ohm-cm) Corrosivity 0 500 500 - 1000 1000 2000 2000 10,000 > 10,000 Very corrosive Corrosive Moderately corrosive Mildly corrosive Negligible corrosivity
Soil Acidity
Steels greater corrosion in acid soils -- passive in neutral/alkaline soils
Aluminum passive in neutral soils -- greater corrosion in strong acid or alkaline soils
Corrosion Mechanism
Galvanic Action is the primary corrosion mechanism in soils
Galvanic Corrosion
Dissimilar materials are in contact
Two different metals or alloys Same nominal alloy in different environments
Copper (V = -.2)
Zinc (V = -1.1)
Cathode
Ion Flow
Anode
CHEMICAL REACTION
Zn Cu + 2 eZn +2 + 2 eCu -2
SOIL
Stray-Current Corrosion
External Induced Electrical Current
Independent of environmental factors
Currents follow paths other than their intended circuits due to:
Poor electrical connections Poor insulation
Corrosion Control
Cathodic Protection Applied Current
Sacrificial Anodes
Cathode
Impressed Current Requires a power supply and buried anode Makes structure into the cathode of an electric circuit
AIR
Power Supply
GROUND
Structure (cathode)
Anode
SACRIFICIAL ANODE
SOIL
Structure (Steel)
Wire
Anode (Zn or Mg)*
Ion Flow
* Zn = Zinc; Mg = Magnesium
ANODE PLACEMENT
Remote Anodes 50-100 yards or more from structure. Uniform current flow. Close Anodes within a few yards. Higher current to localized region.
Modern Practice
Cathodic Protection used in conjunction with coatings on structures. Provides a reduction of power and equipment costs to 5/10% of cost of cathodic protection alone. Generally results in complete protection.
REFERENCES
1 Corrosion: Understanding the Basics; J.R. Davis, ed., ASM (2000) 2 Handbook of Corrosion Engineering; Pierre R. Roberge, McGraw-Hill (1999) 3 Practical Handbook of Corrosion Control in Soils; Sam Bradford, CASTI (2001)
QUESTIONS?
COMMENTS?
NEED MORE INFORMATION? Please email me at raymond@mignogna.org or visit www.mignogna.net