Professional Documents
Culture Documents
Part 2
Introduction to the Rheology of
Complex Fluids
Rheometry
Viscometer vs Rheometer
Viscometer measures viscosity
Rheometer measures rheological properties
A rheometer is a viscometer, but a viscometer is not a
rheometer.
Capillary viscometers
Rotational rheometers
Cup
Glass
Extrusion rheometers
Parallel plates (disks)
Cone-and-plate
Couette
Brookfield viscometers
Rotational Rheometry
Rotational instruments makes it possible:
1.
2.
2.
Rotational Rheometry
Advantages:
1.
2.
3.
4.
5.
Disadvantages:
1.
2.
3.
4.
1.
2.
3.
4.
Low speed monotonic dependence of T(t) until steady state flow is reached
Increasing speed, during the transient stage, the shear stress maximum
(stress overshoot) appears.
The stress overshoot becomes more pronounced, and although the steady
flwo is observed it is followed by a drop in torque (approach to unstable
regime of deformation)
High speeds, steady flow is generally impossible.
A drop in torque is an indication of rupture in the sample or its detachment from the solid
rotating or stationary surface.
Dr. Aldo Acevedo - ERC SOPS
7
Constant torque
Typical experimental results:
1.
2.
3.
0
v v
0
rz
With this velocity field, and assuming incompressible flow, the continuity
equation gives:
1 (rvr ) 1 v vz
0
r r
r z
v
0
v A(r ) z B (r )
The boundary conditions:
v 0 @ z 0
v r @ z H
Solving:
rz
v
H
The rate-of-deformation tensor is then:
v (v)T
Dr. Aldo Acevedo - ERC SOPS
10
v (v)T
v v
r
r
v v
r
r
0
v
z
0
v
0
0
0
rz
0
0
v
z
0
v
z
0
rz
r
H
r
R
R
R
R
H
11
r
rt
(0, t ) (t )dt dt
H
H
0
0
t
21 z
r R
R
0
R
H
21 21 r R
0
R
12
rr 0
0
0
z
z
zz rz
z (r , z )
0
z
z C (r )
Unknown function
13
T (stress)(lever_arm)dA
A
R
T ( z
0
zH
)(r )(2rdr )
21 z (r )
(r )
0
(r )
Rewritting in terms of viscosity, then:
R
T 2 r 2 dr
Dr. Aldo Acevedo - ERC SOPS
14
2R 3 R 3
T
d
R 0
Now to eliminate the integral, we differentiate both sides by the shear
rate at the rim and using Leibnitz rule:
d
dR
3
3
2R 3 R ( )d (R )R
0 R
15
(R )
2R 3 d ln(T / 2R )
R
d ln R
Warning Since the strain varies with radius, not all material elements
experience the same strain. The torque however, is a quantity measured from
contributions at all r. For materials that are strain sensitive this gives results
that represent a blurring of the material properties exhibited at each radius.
16
17
2 HT0 sin
( )
R 4 0
2 HT0 cos
( )
R 4 0
18
0
v 0
v
r
Assuming that single shearflow takes place in the
-direction with gradient in the (-r)-direction):
Thus,
Dr. Aldo Acevedo - ERC SOPS
v C1 (r ) C2
19
/2
v r / 2 0
v 0
Applying BCs:
v
0 2
v
r
r r
0
0
sin v
sin
v
r r
0 0
sin v
0 0
r sin
0
0
r
r
0 rz
20
Thus,
sin v
r sin
1 v
r
0
0
The strain is then:
t
dt
0
0
0
(0, t ) (t )dt
0
21
1 v
r ( ) 0
21
21
T (stress)(lever_arm)dA
A
2 R
(
0 0
)(r )(rdd r )
2 3
T R
3
3T0
21
0
2R 3
In the limit of small angle, the cone-and-plate geometry produces
constant shear rate, constant shear stress and homogeneous strain
throughout the sample.
The uniformity of the flow is also an advantage with structure forming
materials, such as liquid crystals, incompatible blends, and suspensions
that are strain or rate sensitive.
Also, the first normal stress difference can be calculated from
measurement of the axial thrust on the cone.
23
Dr. Aldo Acevedo - ERC SOPS
2
F 2
0
First Normal-stress
coefficient in cone-and-plate
2
rdr R Patm
2 F 0
1 2 2
R
2
0Re it
SAOS for cone-and-plate
3 0T0 sin
2R 3 0
3 0T0 cos
2R 3 0
24
Couette (Cup-and-Bob)
The velocity field is:
0
v v
0
rz
The velocity:
k(r R)
v
k 1
Shear rate:
k
k 1
21 r
v
k
r
k 1
21 r
0
25
Couette (Cup-and-Bob)
Torque:
T (stress)(lever_arm)(area)
T ( r
r kR
)(kR)(2kRL)
T (k 1)
2R 2 Lk 3
Advantages:
Large contact area boosts the torque signal.
Disadvantages:
Limited to modest rotational speeds due to instabilities due to inertia or
elasticity.
Dr. Aldo Acevedo - ERC SOPS
26
27
The toppings
Magnetorheological cells
Electrorheological cells
Optical Attachments
UV- and Photo- Curing accessories
Dielectric Analysis
28
Capillary Flow
The flow is unidirectional in which cylindrical surfaces slide past each other.
Near the walls, except in the -direction, this flow is simple shear flow.
The velocity is:
0 x2
v 0
0
123
Assuming cylindrical coordinates:
21 rz
r R
v z
v z
0
r
r
Dr. Aldo Acevedo - ERC SOPS
29
Capillary Flow
The rate-of-deformation tensor is then:
v (v)T
0
v z
r
0
0
0
v z
r
0
0
rz
vz
r
Thus,
vz r r R
( R )
Dr. Aldo Acevedo - ERC SOPS
v z
r
R
rR
30
Capillary Flow
The viscosity for capillary flow is then:
rz r R
rz r R
21
v
0
R
z
r r R
Now expressions for both the shear rate and stress in terms of
experimental variables must be obtained.
vz
v
0
z
31
Capillary Flow
The equations of motion:
0 P -
P P gz
Assumption:
stresses and pressure are independent of -direction
the flow field does not vary with z (fully developed flow)
capillary is long, such that end effects are diminished
stress tensor is symmetric
Thus, the -component of the equation of motion gives:
1 2
r r 0
2
r r
32
C1
2
r
Using the mathematical boundary condition that the stress is finite at the
center (r=0). Thus, it equals zero.
The z-component:
P (r , z ) 1
r rz (r )
z
r r
The r-component:
P 1
(r rr )
r r r
r
Dr. Aldo Acevedo - ERC SOPS
33
P rr rr
r
r
r
r
P N 2 N 2
r
r
r
r
Thus, the condition that both must be zero should be met easily by most
materials.
P
0
r
34
P ( z ) 1
r rz (r )
z
r r
P0 PL r C1
rz
L 2 r
Solving:
r
P0 PL
rz
r R
R
2L
Dr. Aldo Acevedo - ERC SOPS
35
2Q
r
vz (r ) 2 1
R R
dvz 4Q r
3
dr R R
4Q
R 3
R
21 R
0
R
( P0 PL ) R R 3
2L
4Q
4Q
1 ( P0 PL ) R
a
3
R
2L
1
a R
Q 2 v z (r )rdr
0
Integrating by parts:
R
Q r 2 dr
0
r
rz R
R
Dr. Aldo Acevedo - ERC SOPS
3 R
R
2
Q 3 rz d rz
R 0
37
4Q
4 R
2
a
rz
rz d rz
3
3
R
R 0
Differentiate with respect to tR and apply Leibnitz rule
R
a R 3 4 ( rz ) rz 2 d rz
0
R
d
3
(a R ) 4
( rz ) rz 2 d rz 4 ( R ) R 2
d R
R
0
Rearranging:
1
d ln a
( R ) R a 3
d ln R
4
Dr. Aldo Acevedo - ERC SOPS
Weissenberg-Rabinowitsch correction
38
4 R
(R )
a
d ln a
3
d ln R
39
Capillary Flow
Advantages:
1.
Simple experimentally and equipment set-up
2.
Inexpensive
3.
Higher shear rates
Disadvantages:
1.
May need multiple corrections:
End effects
Wall slip
Temperature
2.
No good temperature control
40
41
42
Extensional Rheometers
43
44
45
Instrument Design
46
Operating Space
Operating Space
The operation space accessible for a given fluid may be constrained by
instabilities associated with gravitational sagging, capillarity or elasticity.
The instabilities can arise from either the interfacial tension of the fluid or
the intrinsic elasticity of the fluid column.
48
Flow
49
Flow
50
f (t )
zz Patm
A(t )
where, f(t) is the magnitude of the tensile force
A(t) is the changing cross-sectional area
f (t )
zz rr zz rr
A(t )
Dr. Aldo Acevedo - ERC SOPS
51
A(t ) A0 e
0t
f e 0t
A00
52
l (t ) D0
l0
D(t )
p (t )
53
L ln(l / l0 )
D 2 ln( Dmid / D0 )
Dr. Aldo
Acevedo
ERC SOPS
Anna,
etal
An- interlaboratory
comparison of measurements from filament-stretching
rheometers using common test fluids, Journal of Rheology 45(1) 83-114 (2001)
54
55
Elongational Viscosity
The unsteady extensional viscosity is obtained from:
(0 )
( 33 11 ) ( zz rr )
0
0
Where the strain rate is obtained by fitting to the raw diameter data.
The Trouton ratio (or dimensionless extensional viscosity) is:
(0 )
Tr
0
56
Elongational Viscosity
Representative result
57
58
Filament Evolution
The general evolution in the experiment typically exhibit three characteristic
regimes:
A. Filament elongation
the radius decreases exponentially
At short times (early strains) there is a solvent-dominated peak
in the force followed by a steady decline due to the exponential
decrease in the cross-sectional area.
Intermediate times (or strains) the force begins to increase
again owing to the strain hardening in the tensile stress. Since
the area decreases, an increase in the force indicates that the
stress is increasing faster that the exponential of the strain.
At very large strains, a second maximm in the force may be
observved after th eextensional stresses saturate and the
extensional viscosity of the fluid recahes steady-state.
59
Filament Evolution
The general evolution in the experiment typically exhibit three characteristic
regimes:
B. Stress relaxation
The radius remains almost constant.
This region is typically short, lasting only one or two fluid
relaxation times.
As elastic stresses decay, pressure and gravity stresses
dominate and filament breakup ensues
C. Filament break-up
The force decays and the radius decreases in similar manner
60
Haake CaBER I
Uses a high precision laser micrometer to accurately track the filament
diameter as it thins. Aside from its resolution (around 10m) the
micrometer is also immune to large ambient light fluctuations and can
resolve small filaments easily (a different issue from the resolution).
The plate motion is controlled by a linear drive motor. The fastest stretch
time is of the order of 20 ms (depending on stretch distance) and the
motor has a positional resolution of 20 m.
61
62
References
63