PROPILENO

ROBLES LUNA JOEL

ARBOL PETROQUIMICO II

ESQUEMA DEL CRACKER

TERMICO

ANALISIS DE LA DEMANDA

Global Propylene Capacity Additions

2008 - 2010
PG/CG Propylene Capacity: -000- Metric Tons
Total
2008 2009 2010
2008 - 2010
Region
Northeast Asia

1,410

1,116

3,775

6,301

Middle East/Africa

1,208

2,077

1,121

4,405

Southeast Asia

295

447

1,220

1,962

Indian Subcontinent

----

675

525

1,200

Europe

664

(146)

72

589

Americas

852

(627)

205

430
14,887

PRODUCCION

PRODUCCION

DEDHIDROGENACION DEL PROPANO

EFECTO DE LA TEMPERATURA EN LA
DESHIDROGENACION

PROCESO DE PRODUCCION DEL

PROPILENO

CO-PRODUCCION DE
PROPILENO

CRAQUEO CON VAPOR

Etapas del proceso:

SEPARACION DE LOS GASES DE

REFINERIA

SEPARACION DE LOS GASES DE

REFINERIA

OTROS PROCESOS

ALGUNOS PROCESOS COMO

EJEMPLO

EJEMPLOS

PARAMAX

Aromatic Complex Blocks Functions

ParamaX Suite

ing:
m
r
efo
A9+
R
/
X
R
/
CC
B/T
o
t
a
hth
p
a
N

HN
BT

A9+
A8

T&
d
H
N
ion
t
a
n
tio
Frac

tion
a
l
y
k
s al
/C8A
Z
B
Tran
+ to
9
A
Tol+
A8

FRN

ion
t
c
a
xtr
BT E tionation
ac
& Fr

BZ

BZ

BZ

PX

Loop
s
e
n
Xyle o PX/BZ
t
C8A

Refining & Petrochemical Flow

Exchanges
Petrochemical
Petrochemical

Refining

Unsaturated ROG
FCC C3 cut
FCC C4-C5 cuts

Technology

Final
Products

ss

PRU
Conversion to C3=

(C3=) PP

Coker C3-C4 cuts

Saturated ROG
Excess of C3, C4

Purification
Dehydrogenation
H2, C4, Pygas

SR Naphtha
Cracked Naphtha
CCR Reformate
Gas Oil
HC bleed
VGO
AR/VR

Steam
Steam
Cracker
Cracker

HDT & Splitter

to Aromatics
to SC
to SC or PetChem FCC
PetChem RFCC
Gasoline Pool Bases

Raffin.

(C2=) PE,
PVC
(C3=) PP

Pygas

Aromatics
Aromatics
Complex
Complex
ParamaX
ParamaX

(Styrene) PS
Polyethylene
terephthalat
e PET

HP FCC Technology
Riser separator RS
Stripper / Packing
Regenerator
Bathtub catalyst
distributor

540-560C
C/O = 10
ZSM-5 content
)crystal 40% (10-20%

Feed
LCN recycle

Resid to Propylene
Fuel Gas
Process Scheme
& Technology
Fractionator
Fractionator &&
Gas
Gas Recovery
Recovery

C3
C3 C4
C4 LPG
LPG
Treatment
Treatment
&& Separation
Separation

C3
C3
Splitter
Splitter

Propylene PG

Propane
Naphtha
Naphtha
Splitter
Splitter

Raw C4

720-740C

550C
C/O 8

HCN
LCO

590C
C/O 12

Slurry/CLO
FEED

660C

R2R
R2R
R2R
R2R
Risers
Risers
Risers &&&
Risers
Regenerators
Regenerators
Regenerators
Regenerators
LCN
Recycle

R2R Unit

Main Riser
Resid

PetroRiser
LCN

FlexEneTM - Flow Scheme

Polymer Grade
Sweetening
Sweetening
TM
Sulfrex
SulfrexTM

Propylene
Propane

Gas
Gas Recovery
Recovery
Raffinate
C4-C5 cut
Gasoline

Gasoline
Recycle

FCC
Feed

Distillate

TM
PolynaphthaTM

Recycle Oligomers from

Polynaphtha to FCC riser Or
to maximize C3=

MF
Pool

Distillate

Valorize Polynaphtha
Gasoline or Distillate
to Motor Fuel to adjust
Gasoline/Diesel ratio

Operability
Continuous Catalyst
Regeneration
is based on
Axens CCR experience
> 100 Octanizing &
Aromizing references
Iso-5 Process
Flexible and easy to
operate regenerator

Axens Technologies for

Olefins Upgrading
Ethylene

C3=

MAPD
MAPD

Selective
Selective
Hydrogenation
Hydrogenation

Oligomerization
Oligomerization
AlphaSelect/
-Select/
-Hexol
AlphaHexol

Dimerization
Dimerization
AlphaButol
AlphaButol

Purification
Purification
Multibed
Multibed

Maximum Butadiene

C4 Acetylenes
Acetylenes
C4

C4

Selective
Selective
Hydrogenation
Hydrogenation

Maximum Butenes

Steam Cracker

Butadiene
Butadiene

Selective
Selective
Hydrogenation
Hydrogenation

Hydrogenation
Hydrogenation

IB= Purification
Purification
IB=

Skeletal
Skeletal

Isomerization
Isomerization

C5=

Iso-5
Iso-5

/C5
CC44/C
5

Etherification
CC55Etherification
Catacol
Catacol

Olefins
Olefins
Hydrogenation
Hydrogenation
C2

Dimerization
Dimerization
Dimersol
Dimersol-X

Hydration

Isopure
Isopure

Oligomerization
Oligomerization
Selectopol
Selectopol
Polynaphtha
Polynaphtha

Dehydro.

Olefins
Olefins

Hydrogenation
Hydrogenation

C6-C10

Pygas
Pygas

Selective
Selective
Pygas Hydrogenation
Hydrogenation

GHU1
GHU1

C6-C10

C6-C8

Pygas
Pygas

Hydrodesulfurization
Hydrodesulfurization

GHU2
GHU2

Removal of
Arsenic & Mercury
RAM II

C9-C10

n-Butane
MEK
Solvents
TAME, TAEE

APU
APU

C5

Octenes

MTBE, ETBE

Advanced
Advanced
Pygas
Pygas
Upgrading
Upgrading

LPG

C5-C10

2-Butenes

Hydrogenation Fractionation
Fractionation
Hydrogenation

Max B=2
B=2
Max

C4/C5

Propylene
Butadiene
Isobutane
Isobutylene

SuperSuper-

Max B=1
B=1
Max

Etherification
Etherification

Catacol
Catacol

Lin. - Olefins

1-Butene

Butadiene
Extraction
CC44

1-Hexene

Extraction
Extraction
Sulfolane
Sulfolane
Morphylane
Morphylane
Sulfur
Sulfur
Removal
Removal
OATS
OATS

Benzene
Toluene
C8 Aromatics
to Aro. Complex

To Motor
Gasoline Pool
Condensates

Refinery with HCK, HP FCC + ParamaX

SR Naphtha

CDU

Aromatic Complex
ParamaX

Naphtha Naphtha
H2

Benzene
Paraxylene

Gasoline
Toluene rich cut, A8+
A9+, raffinate, light naphtha Pool
Kero

HCK
VDU

Gasoline

Bleed

VGO

HP FCC
Delayed HCGO
Coker
Refinery production
400,000 bbl/d

Diesel

Propylene

LPG
Coke
Aromatics production
Paraxylene: 700 kt/y (2.5% of 2009 PX world production)
Benzene: 140 kt/y

Existing Refinery with Steam Cracker +

ParamaX
Heavy Naphtha

Aromatic Complex
ParamaX

Benzene
Paraxylene

Existing refinery

Gasoline

H2 export
Pygas

Kero
Diesel
Residue

Propylene

C2, LPG, raffinate

Light Naphtha

Existing Refinery production

400,000 bbl/d

SC

Ethylene

Aromatics production
Paraxylene: 1,400 kt/y (5% of 2009 PX world production)
Benzene: 650 kt/y

Propylene Production from Refinery

LPG

Steam Cracker
Complex
Naphtha
Resid

Coker

FCC

VGO High Propylene FCC

HS-FCC
Resid
Resid to Propylene

Alternative Fuel
units
Fischer-Tropsch

C4-C5 cut

>8 wt%
C2=
>30 wt%
C3=

Olicrack

On-purpose C3= unit

C4-C5 cut
C4-C5 cut

C3= / C2= ratio > 3 - 4

C4-C5
Olefins
Recovery

or

C3=

8 to 20 wt
%

C 3=
FlexEne

or

C4-C5 cut
Unique integration
With FCC for
flexibility

Gasoline
/Distillate

HUNGARY

BAHA BLANCA

CATALIZADORES

CATALIZADORES

TESIS DE SEPARACION

SEPARACION POR
MEMBRANAS

SEPARACION DE PROPANO Y
PROPILENO

PRODUCTOS DERIVADOS DEL

PROPILENO

MEXICO

PRODUCTOS DERIVADOS DEL

PROPILENO