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Merve Ayvaz
Boazii University
9%
Particle size:11-16 nm
Crystallite Size
Co3O4 and CoO phases contain significant
d(Cocpp)=
0.80d(Co3O4
)
CoO in the metallic cobalt particles may reduce the
9.35
o
Conclusion
A 20%Co-1%Re/g-Al2O3 catalyst characterised
39.50
d=2.2
8
500
d=1.8
2
590
d=1.5
6
character of MoS3.
Rapid increase of temperature during reduction, increase
the surface area and presence of amorphous particles.
32.70 36.50
55.50
600
d=2.74d=2.46
0d=1.65
45.5
d=1.54
d=1.95
Conclusion
Co-MoS2 is the primary phase in K2CO3/Co-MoS2 .
Co9S8 phase is not present at Co/Mo mole ratio of
0.5.
XPS binding energy difference of molybdenum
dependant.
Literature
1V/Zr
K-3V/Zr
consist of 2 phases:
metastable tetragonal
and monoclinic.
K-3V/Zr calcined at 853
K. But the ratio of the
peak intensities
Upon
increasing the
(111)M/(111)temperature
T are
calcination
different
to
1253 K.
So
the phasephase
Tetragonal
composition
disapperingdepend
on
both temperature
Crystallite
size increases
and chemical
97
5
K
10
25
K
Strong interactions
between vanadia and
the supported
material stabilize
tetragonal zincoria in
the absence of alkali
additives up to 1025K
Beginnin
g of
phase
transitio
n
ESR-Zirconia supported
V2O5 catalyst with various
vanadia loadings
temperatures.
More information on the nature of V4+ species
responsible for the complex structure of the spectra.
1V/Z
3V/Z
r Stepwise calcinations.
r
At temperatures above 1053 K, similar sequences of spectra
was recorded.
It indicates that in both cases V4+ ions occupy the same
Conclusion
Phase transitions are observed.
Metastable tetragonal
monoclinic
Phase transitions are influenced by additives.
(vanadium and potassium).
Vanadium stabilizes the metastable tetragonal
phase of zirconia.
Diffusion of the surface V4+ into ZrO2 matrix is
strongly accelerated by phase transition.
Thank you