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CHEMISTRY
(Gravimetry)
Dr.S.SURESH
Assistant Professor
Email:avitsureshindia@gm
ail.com
Gravimetric Analysis
Gravimetric analysis is the quantitative
determination of analyte concentration through a
process of precipitation of the analyte, isolation of
the precipitate, and weighing the isolated product.
Gravimetric Analysis
1. A weighed sample is dissolved
2. An excess of a precipitating agent is
added to this solution
3. The resulting precipitate is filtered,
dried (or ignited) and weighed
4. From
the
mass
and
known
composition of the precipitate, the
amount of the original ion can be
determined
Types of Crucibles
Different types of crucibles are used for
drying and weighing the precipitates.
They are mainly of two types.
Crucibles made of porcelain or silica are
used when the precipitates are dried in
an oven or muffle furnace.
Sintered
crucibles
are
used
for
precipitates which are weighed after
drying in air-oven.
Silica Crucible
Porcelain Crucible
Sintered Crucible
Co-precipitation and
Post-precipitation
Co-precipitation : Soluble impurities
which are getting precipitated along
with the formation of the precipitate.
Post-precipitation: After the formation
of the precipitate, the impurities will
get soluble.
Postprecipitation
Ca2+
(NH4)2C2O4
CaC2O4
BaSO4
BaCrO4
Gravimetric factor
A gravimetric factor converts grams of a
compound into grams of a single element.
Example: To find the gravimetric factor of Cl in
AgCl
AgCl
Ag
+ Cl
mass of Cl
Gravimetric factor Molecular
=
Mass of AgCl
35.5
143.3=
= 0.24
Gravimetric factor
Determine gravimetric factor of calcium in
water, if you precipitate calcium as CaCO 3.
Gravimetric factor =
Mass of Ca
Molecular Mass of CaCO3
= 40
100
= 0.4