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Wavelength
Relative sizes of
wavelengths
F
r
e
q
u
e
n
c
y
www.atmos.washington.edu/~hakim/301/handouts.html
http://www.astro.virginia.edu/class/oconnell/astr30/im/photoelectric-effect2.jpg
E=h
6.626 x 10-34 Js
What is a Joule?
A Joule is the derived unit of
energy in the SI system. It is
the energy exerted by a force
of one Newton acting to move
an object through a distance of
one meter.
James Prescott
Joule
kg m/s m = kgm /s
2
abyss.uoregon.edu/~js/images/wave_particle.gif
Spectroscopy
ctrum
e
p
S
n
o
si
is
m
-E
e
in
L
Bright
The Hydrogen-atom
Ephoton = E2-E1
orbits have
specific
energies, given
by a simple
formula
En = (-RH)
n = 1,2,3,4,. . .
RH is the
Rydberg
constant
2.18 x 10-18 J
Combining equations
Given: E = h and E = E2-E1
combining them results in
= E = ( RH) (1 - 1 )
h
h
n 2i n 2f
Further simplification:
= ( RH) (1 - 1 )
n 2i n 2f
If electrons behave
as both particles
and waves, where
are they located in
an atom?
Heisenberg Uncertainty
Principle (1927)
It is impossible to determine simultaneously
both
the position and velocity of an electron or
any
other particle.
(p) ( x) = h (Plancks constant)
p = uncertainty in momentum
x = uncertainty in position
1924 Louis de
Broglie
Electrons should be
considered as waves
confined to the space
around the nucleus.
http://youtube.com/watch?v=x_tNzeouHC4
Bohr applet:
http://www.colorado.edu/physics/2000/quantumzone/bohr.html
mv2 = hv
=h
mv
( + + ) + 82m (E-V) = 0
x2 y2 z2
h2
(psi) = wave amplitude function
m = mass of electron
E = energy
V = potential energy
x, y, and z are the coordinates in space where
the equation is solved
Quantum numbers
Describe the properties of atomic orbitals and the
properties of electrons in these orbitals. There are
4 quantum numbers, the first three of which
result from the solutions to Schrdingers wave
equation.
Principal quantum number (n) the main energy
level occupied by the electron. n= 1,2,3,4, . . .
10
Principal
quantum
number
Orbital
quantum
number
Magnetic quantum
number
n=1
l = 0 (s)
ml = 0
+,
n=2
l = 0 (s),
l = 1 (p)
l = 0 (s),
l = 1 (p),
l = 2 (d)
ml = 0
ml = -1, 0, +1
+,
+ , ; + ,
; + ,
ml = 0
ml = -1, 0, +1
ml = -2, -1, 0, +1, +2
+,
+ , : + , ; +
,
+ , ; + , ;
+ , ; + , ;
+,
l = 0 (s),
l = 1 (p),
l = 2 (d),
l = 3 (f)
ml = 0
ml = -1, 0, +1
ml = -2, -1, 0, +1, +2
ml = -3, -2, -1, 0, +1,
+2, +3
+,
+ , ; + , ; + ,
+ , ; + , ; + , ;
+ , ;
+,
+ , ,; + , ; + , ;
+ , ; + , ; + , ;
+,
n=3
n=4
s
o
r
b
i
t
a
l
p orbitals
d
orbital
s
f orbitals
Electron configurationsrules
Aufbau
principle:
An electron
occupies the
lowest energy
orbital that can
receive it.
Diagonal Rule
Hunds Rule
orbitals of equal
energy are each
occupied by one
electron before any
orbital is occupied by
a second electron,
and
all electrons in singly
occupied orbitals
must have the same
spin.
Example 1
Boron atomic number 5
Longhand: 1s22s22p1
Shorthand: [He]2s22p1
Orbital diagram:
1s
2s
2p
Example 2
Orbital diagram:
Degenerate orbitals
a group of orbitals with the same
energy
Examples: Chromium (24) Cr
Shorthand: [Ar]4s13d5 NOT [Ar]4s23d4
Mo and W are similar
Copper (29) Cu
Shorthand: [Ar]4s13d10 NOT [Ar]4s23d9
Ag and Au are similar
Additional Definitions
Paramagnetic: An atom has
unpaired
electrons in its electron
configuration.
(Look at its orbital diagram)
Diamagnetic: All electrons in an
atom
Ion Configurations
Electrons will be added to, or taken away
from
orbitals in the following order: s, p, d, f (i.e.
the outer or valence shell first)
Examples:
Cl- 1s22s22p63s23p5 for Chlorine becomes
1s22s22p63s23p6