Professional Documents
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of Materials, 4th ed
Donald R. Askeland Pradeep P. Phul
Objectives of Chapter 2
Chapter Outline
Section 2.1
The Structure of Materials:
Technological Relevance
Nanotechnology
Micro-electromechanical (MEMS)
systems-Airbag
sensors
Nanostructures
Figure 2.1
Example of Technologies
Atomic Structure
Diamond edge of
cutting tools
Example of Technologies
Nanostructure
Nano-sized particles of
iron oxide ferrofluids
Microstructure
Mechanical strength of
metals and alloys
Macrostructure
Section 2.2
The Structure of the Atom
The atomic number of an element is equal to the
number of electrons or protons in each atom.
The atomic mass of an element is equal to the average
number of protons and neutrons in the atom.
The Avogadro number of an element is the number of
atoms or molecules in a mole.
The atomic mass unit of an element is the mass of an
atom expressed as 1/12 the mass of a carbon atom.
Example 2.1
Calculate the Number of Atoms in Silver
Calculate the number of atoms in 100 g of silver.
Example 2.1 SOLUTION
23 atoms
(
100
g
)(
6
.
023
10
mol )
The number of silver atoms is =
(107.868 g mol )
=5.58 1023
Example 2.2
Nano-Sized Iron-Platinum Particles
For Information Storage
Scientists are considering using nano-particles of such
magnetic materials as iron-platinum (Fe-Pt) as a
medium for ultrahigh density data storage. Arrays of
such particles potentially can lead to storage of
trillions of bits of data per square incha capacity that
will be 10 to 100 times higher than any other devices
such as computer hard disks. If these scientists
considered iron (Fe) particles that are 3 nm in
diameter, what will be the number of atoms in one
such particle?
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Example 2.3
Dopant Concentration In Silicon Crystals
Silicon single crystals are used extensively to make
computer chips. Calculate the concentration of silicon atoms
in silicon, or the number of silicon atoms per unit volume of
silicon. During the growth of silicon single crystals it is often
desirable to deliberately introduce atoms of other elements
(known as dopants) to control and change the electrical
conductivity and other electrical properties of silicon.
Phosphorus (P) is one such dopant that is added to make
silicon crystals n-type semiconductors. Assume that the
concentration of P atoms required in a silicon crystal is 10 17
atoms/cm3. Compare the concentrations of atoms in silicon
and the concentration of P atoms. What is the significance of
these numbers from a technological viewpoint? Assume that
density of silicon is 2.33 g/cm3.
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Example 16.9
Comparing Electronegativities
Using the electronic structures, compare the electronegativities
of calcium and bromine.
Example 2.4 SOLUTION
The electronic structures, obtained from Appendix C, are:
Ca: 1s22s22p63s23p6
4s2
Br: 1s22s22p63s23p63d10
4s24p5
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Example 2.5
Calculating the Conductivity of Silver
Calculate the number of electrons capable of conducting an
electrical charge in ten cubic centimeters of silver.
Example 2.5 SOLUTION
The valence of silver is one, and only the valence electrons are
expected to conduct the electrical charge. From Appendix A, we
find that the density of silver is 10.49 g/cm3. The atomic mass of
silver is 107.868 g/mol.
Mass of 10 cm3 = (10 cm3)(10.49 g/cm3) = 104.9 g
(104.9 g )(6.023 10 23 atoms / mol )
5.85 10 23
Atoms =
107.868 g / mol
Electrons = (5.85 1023 atoms)(1 valence electron/atom)
= 5.85 1023 valence electron/atom per 10 cm3
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Example 2.6
How Do Oxygen and Silicon Atoms Join to
Form Silica?
Assuming that silica (SiO2) has 100% covalent bonding,
describe how oxygen and silicon atoms in silica (SiO2) are
joined.
Example 2.6 SOLUTION
Silicon has a valence of four and shares electrons with
four oxygen atoms, thus giving a total of eight electrons
for each silicon atom. However, oxygen has a valence of
six and shares electrons with two silicon atoms, giving
oxygen a total of eight electrons. Figure 2-16 illustrates
one of the possible structures.Similar to silicon (Si), a
tetrahedral structure also is produced. We will discuss
later in this chapter how to account for the ionic and
covalent nature of bonding in silica.
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Example 2.7
Design of a Thermistor
A thermistor is a device used to measure temperature by
taking advantage of the change in electrical conductivity
when the temperature changes. Select a material that might
serve as a thermistor in the 500 to 1000oC temperature
range (see Figure 2-17).
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Example 2.8
Describing the Ionic Bond Between
Magnesium and Chlorine
Describe the ionic bonding between magnesium and
chlorine.
Example 2.8 SOLUTION
The electronic structures and valences are:
Mg: 1s22s22p6
3s2
valence = 2
Cl: 1s22s22p6
3s23p5
valence = 7
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Example 2.9
Determine if Silica is Ionically or
Covalently Bonded
In a previous example, we used silica (SiO2) as an example of
a covalently bonded material.In reality, silica exhibits ionic and
covalent bonding. What fraction of the bonding is covalent?
Give examples of applications in which silica is used.
Example 2.9 SOLUTION
From Figure 2-10, we estimate the electronegativity of silicon
to be 1.8 and that of oxygen to be 3.5. The fraction of the
bonding that is covalent is:
Fraction covalent = exp[-0.25(3.5 - 1.8)2] = exp(-0.72) =
0.486
Although the covalent bonding represents only about half of
the bonding, the directional nature of these bonds still plays an
important role in the eventual structure of SiO2.
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Example 2.10
Design Strategies for Silica Optical Fibers
Silica is used for making long lengths of optical fibers
(Figure 2-4). Being a covalently and ionically bonded
material, the strength of Si-O bonds is expected to be
high. Other factors such as susceptibility of silica
surfaces to react with water vapor in atmosphere have a
deleterious effect on the strength of silica fibers. Give n
this, what design strategies can you think of such that
silica fibers could still be bent to a considerable degree
without breaking?
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Example 2.11
Design of a Space Shuttle Arm
NASAs space shuttles have a long manipulator robot
arm, also known as the Shuttle Remote Manipulator
System or SRMS (Figure 2-26), that permits astronauts
to launch and retrieve satellites. It is also used to view
and monitor the outside of the space shuttle using a
mounted video camera. Select a suitable material for this
device.
Figure 2.26 NASAs Shuttle
Remote Manipulator
System: SRMS (for Example
2.11). Courtesy of Getty
Images)
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