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pH of 0.10 M H2Z in
0.50 M KHZ.
-5
Ka1 = 2.0 x 10
-9
Ka2 = 5.0 x 10
Salt or
Hydrolysis
Reactions
Hydrolysis
Any reaction in which water is
decomposed with all or part
of its decomposition portions
combining with the products
Hydrolysis
Water is added to
decompose
something
Hydrolysis
MX + HOH
HX + MOH
Salts
Salts
Ionic compounds
that dissolve ~
100 % in water
Salts of Acids
Salts of acids are
negative
(A )
Salts of Bases
Salts of bases are
Positive
+
+
(M or B )
Salt Solutions
When salts dissolve,
their ions can
recombine with water
Salt Solutions
The salts of weak acids
can recombine with
water producing basic
solutions
Salt Solutions
The salts of weak
bases can recombine
with water producing
acidic solutions
Salt Solutions
A + H 2O
HA + OH
B + H2O
H + BOH
Salt or
Hydrolysis
Problems
Salt Problem
Calculate the pH of
a 0.20 M solution
of NaBz
-5
Ka HBz = 6.4 x 10
-5
Salt or
Hydrolysis
Problems
Salt Problem
Calculate the pH of
a 0.20 M solution
of KNO2
Ka HNO2 = 7.1 x 10
-4
Salt Problem
Calculate the pH of a
0.10 M solution of
R-NH3Cl
Kb R-NH = 2.5 x 10
-5
Calculate the pH of
a 0.18 M solution
of KC2H3O2
Ka = 1.8 x 10
-5
Salt Applications
Salts of strong acids
& weak bases make
acidic solutions
Salt Applications
Salts of strong bases
& weak acids make
basic solutions
Salt Applications
Salts of strong acids
& strong bases make
neutral solutions
Predict Relative pH
NaAc
MnCl2
KNO3
NH4Br
KHSO4
NH4Ac
Predict Relative pH
KAc
KClO2
K2SO4
NaCl
NH4Cl
NaI
Anhydrides
Compounds without
water; that when
added to water, form
other compounds
Acid Anhydrides
Non-metal oxides
that form acids when
added to water
Basic Anhydrides
Metal oxides that
form bases when
added to water
Predict Relative pH
SO2
Na2O
NO2
CO2
CaO
Al2O3
Calculate the pH of
a 0.16 M solution
of KC7H5O2
Ka = 6.4 x 10
-5
Calculate the pH
of a solution of
0.0030 M KQ.
Ka HQ = 3.0 x 10-5
Drill: Calculate
the pH of
0.10 M HF.
-4
Ka HF = 6.5 x 10
Test
Review
Expect a straight
acid/base
problem like the
drill
Calculate the pH
of 0.10 M HF in
0.20 M KF.
-4
Ka HF = 6.5 x 10
Calculate the pH
of 0.10 M KF.
-4
Ka HF = 6.5 x 10
Predict Relative pH
K2O
MgO
ClO2
(NH4)2O
SO3
N2O3
Predict Relative pH
KAc
KClO2
K2SO4
NaCl
NH4Cl
NaI
Calculate the pH
of 5.0 M KCN.
-10
KaHCN= 5.0 x 10
Calculate pH of:
0.20 M MOH in
0.50 M MCl
-5
Kb = 5.0 x 10
Calculate pH of:
0.20 M MCl
-5
Kb = 5.0 x 10
Drill: Calculate
the pH of
0.20 M KQ.
-5
Ka HQ = 8.0 x 10
Calculate pH of:
0.20 M HNO2
Ka = 2.0 x 10
-4
Calculate pH of:
3.0 M HZ in
2.0 M KZ
Ka HZ = 3.0 x 10
-5
Calculate pH of:
0.20 M KR
-5
Ka HR = 2.0 x 10
Calculate pH of:
2.0 M HQ
Ka = 2.0 x 10
-6
Calculate pH of:
0.60 M HZ in
0.90 M KZ
Ka HZ = 3.0 x 10
-5
Calculate pH of:
0.20 M KQ
-7
Ka HQ = 2.0 x 10
Review of Acid/Base
descriptions and
Acid/Base, Buffer, &
Salt Equilibria
Strong Acids
Strong Bases
Acid rxns
Base rxns
A/B Equilibrium
Constants
KW, KA, KB, & pH
Calculate pH of:
0.025 M HNO3
0.020 M KOH
The take-home
portion of the
test is due by
8:15 tomorrow