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P R O C E S S D E S I GN
P R ES E N T A T IO N
P RA IR I E VI E W A & M
U N I VE R S I T Y
D E PA R T M EN T O F
C H E M IC A L EN GI N E E R IN G
Group 5
Fadi Musallam
Patrick Monkam
Christoff Lindsey
Wendpanga Zampaligre
AGENDA
Project Introduction
Problem Statement
Project Summary
Background
Process Design
PROBLEM STATEMENT
The purpose of this project is to design a grass-root plant for
330 days
1.1 x 104 kg/hr
9.8 x 104 Metric ton/year
EVALUATION OF
PROPERTIES
AND USES
What is Cumene?
Insoluble in water
VALUE
120.2
Boiling Point, C
152.39
Freezing Point, C
-96.03
0.8786
0.124
Viscosity(0 C)
1.076
Flash Point, C
44
Autoignition temperature, C
523
ACETONE
BENZENE
CUMENE
PHENOL
PROPYLENE
Alpha
methyl
styrene
BLOCK FLOW
P&ID DIAGRAMS
METHODS OF PRODUCTION
Types of Processes
A fixed bed, Kieselguhr supported phosphoric acid
catalyst system developed by UOP (Universal Oil
Products)
2. A homogeneous AlCl3 and hydrogen chloride
catalyst system developed by Monsanto
3. Dow-Kellog Technology Using Zeolite Catalysts
1.
hazards
Transalkylation reaction
Overall yield of the process as high as 97 wt%
Corrosion of Pipes and Equipments
ECONOMIC &
VIABILIITY
EVALUATIONS
GLOBAL DEMAND
GB&I RESEARCH
MARKET ANALYSIS
Asia-Pacific
European-Middle East,
http://www.icis.com/chemicals/cumene/
KBR
Shell Global
GFS Chemicals Inc.
DynaChem Inc.
US Chemicals LLC
The Chemical Company
Sunoco Chemicals
Chemstar
Capital Raisin Corporation
Constraints:
Raw Material Supply
Transport Facilities
Availability of Utilities
Availability of suitable land
Adequate Climate
Location with respect to the
marketing area
Alkylation
Reactor
Flash Drum
Benzene
Distillation
Column
Cumene
Purification
Distillation
Column
DESIGN OF
PROCESS
UNITS
PHYSICAL PROPERTIES
Primarily comprised of Silica and
Alumina Tetrahedral
Cage-like structure with voids in
framework
HIGHER SELECTIVITY
DEACTIVATION STABILITY
Surface area , /g
500-800
Particle porosity
0.5
Catalyst density,
kg/
1000
tortuosity
Void fraction
5
0.4
REACTION KINETICS
REACTIONS
STANDARD
HEAT OF
RXN
RATE
CONSTANT
REACTION
RATES
E= 1.04 x
KJ/kmol
E= 1.47 x
KJ/kmol
= 2.32 xl/mol
sec
=,
Weight of Catalyst,
=1.57 x kg
Bed volume,
=15.7
Reactor volume
=1.1=17.3
A=
=Ah
t= +
= x3.5
CALCULATED VALUES
h=3.5
t= +
feed condition
specification
temperature
values
156.6 C
pressure
35.3 bar
b/p ratio
catalyst
reactor
material
whsv
propane inert
p conversion
bed voidage
5.08%
99.90%
40
particul diameter
2.4 mm
density
1000kg/m3
weight
bed volume
height
1.57 x 10^4 kg
15.7 m3
6.46 m
Int diameter
1.84 m
volume
thickness
carbon steel
2/h
17.3 m3
75mm
DE-PROPANIZER VESSEL
DESIGN STEPS FOR FLASH DRUM SIZING:
Calculation of maximum allowable vapor velocity
Calculation of the diameter
Calculation of the height
DE-PROPANIZER VESSEL
MASS BALANCE
FEED
OVERHEAD
BOTTOM
32800
2800
30000
Benzene
0.6
0.87
0.56
Cumene
0.37
0.05
0.4
DIPB
0.02
0.04
Propane
0.01
0.08
Assumptions:
- 100% evaporation of propane
- 100% DIPB at the bottom
DE-PROPANIZER VESSEL
DESIGN CALCULATIONS
Operating Conditions
Temperature
Pressure
55 C
0.35 atm
Vapor Density
3.2 kg/m3
Liquid Density
820 kg/m3
Assumptions:
- K= 0.107 m/s
DE-PROPANIZER VESSEL
DESIGN CALCULATIONS
Calculation of the cross-sectional area of the flash drum
AC = QV/u
AC : average cross-sectional area (m 2)
QV : vapor flow rate (m3/s)
u : maximum allowable vapor velocity (m/s)
AC = 1.5 m2
Assumptions:
- 5 minutes hold-up time
DESIGN SUMMARY
Design Parameters
Value
Orientation
Vertical
Diameter(m)
1.4
Total Height(m)
5.6
Material of Construction
Carbon Steel
XiF
XiD
XiB
96oC
Propane
0.0021
0.0031
Benzene
0.6689
0.9869
.01
Cumene
0.3315
0.01
0.9364
DIPB
.01750
0.0536
1.72
atm
178oC
Propane
6.80338
804
247.04
Benzene
7.2009
1415.8
248.028
Cumene
6.9366
1460.793
207.777
DIPB
7.57869
2133.558
235.681
ANTOINE
EQUATION
PROPANE
BENZENE
CUMENE
DIPB
T (96oC)
37.9
1.6
.172
.0172
T(178oC)
180.9
9.6
1.77
.3096
CUMENE
DIPB
22.04
0.93
0.10
.01
214.68
9.07
1.00
.10
P = 1.72 atm
Ki =
distribution
coefficient
Kc reference
CUMENE
DIPB
105.20
5.57
1.03
0.19
101.89
5.39
1.00
0.18
P = 1.72 atm
Ki =
distribution
coefficient
Kc reference
LD = 9.07
AVERAGE VOLATILITY
Lw = 5.39
FENSKES EQUATION
xLDD composition of
light key in distillate
xHDD composition of
heavy key in distillate
xHWW composition of
heavy key in bottoms
xLWW composition of
light key in bottoms
L,avg = 6.99
Nm = 4.69
BENZENE
CUMENE
DIPB
104.0
6.71
0.14
Component Xif
Composition
Xpropane
0.0021
Xbenzene
0.668
Xcumene
0.311
Xdipb
.0175
PROPANE
BENZENE
CUMENE
Xpropane 0.0031
Xbenzene 0.9869
Xcumene0.01
Xdipb 0.0
The calculated theta will be used to calculate the minimum reflux rati0
=1.216
=1.216
=0.216
DIPB
Rm =
0.216
R = 0.324
R = 0.324
R = 0.324
0.245
0.245
R
R=
= 0.216
0.216
0.18
0.18
11 theoretical stages
0.3115
XLF
0.6689
100.1
kgmole/hr
207.47
kgmole/hr
XLW
.01
XHD
.01
Ns = 6 ; Ne = 5
(cP)
Feed
Bottoms
Distillate
0.4692
0.262
0.1759
CALCULTION OF FLOWRATES
SYSTEM OF EQUATIONS
D = 16271 kg/hr
R = 0.324
L1 = 5271.8503 kg/br
L = 5271.8503 kg/br
V1 = 21543 kg/hr
D = 16271 kg/hr
L1 = 5271.8503 kg/hr
L2 = 33762.385
F = 28491 kg/hr
B = 12219 kg/hr
L2 = 33762.385 kg/hr
V2 = 21543 kg/hr
L2 = 33762.4 kg/hr
V2 = 21543.0 kg/hr
AVG
0.9752
6.662
4.485
3.91
845.4
717.7
791.1
784.7
24.1
13.01
18.72
55.83
Assuming 24 inches
The K value was determined to be 0.34ft/s
DESIGN EQUATIONS
EQUATION
H = 2.3 Nactual
VARIABLES
VALUES
L= 784.73
V= 3.91
= 55.83
Kv= 0.34
V = 21543.o
V= 3.91
vdesign = 1.43 m/s
1.07 m2
Towercross= 1.07m2
1.16 m = 3.8 ft
Nactual= 18
D = 1.16 meters
L = 12.9 meters
VALUE
0.216
0.
60%
5
18
1.16 m
0.6
13 m
Carbon Steel
Tray 6
Components
Cumene,
Diipropylbenzene(DIPB),
and Benzene
Cumene
Heavy Key
DIPB
Assumptions:
pseudo-binary separation between
the key components.
Benzene considered as dead-weight
Equation
where LDrelative volatility of the light
key at the top,
LW - relative volatility of the light key at
the bottom
where xLD composition of light key in
distillate,
XLD
0.9884
XLW
0.004
XHD
0.001
XHW
0.996
L,av
6.6568
Nm
Underwood method:
Correlation (E0)
= 37 Units
is the theoretical number of trays
is the actual number of trays
= 6.86 m^3
D= 2.86m
Calculating the Column Height
Htower= 25.84m
DESIGN SUMMARY
Design Parameters
Value
0.18
0.22
42%
7
36
2.86
0.61
25.84
Carbon Steel
PROFITABILITY
ANALYSIS
Fraction of
delivered
equipment
Solid- processing Solid-fluid
plant
processing plant
Direct Costs
0.10
0.45
0.10
0.10
0.10
0.39
0.47
0.47
0.18
0.26
0.16
0.31
0.10
0.10
0.25
0.29
0.15
0.12
0.40
0.55
1.69
2.02
Indirect Costs
0.33
0.32
0.39
0.34
0.04
0.04
0.17
0.19
0.35
0.37
1.28
1.26
Fixed capital investment (FCI)
0.36
0.68
0.11
0.18
0.10
0.70
2.60
0.36
0.68
0.11
0.18
0.10
0.70
2.60
0.33
0.41
0.04
0.22
0.44
1.44
0.33
0.41
0.04
0.22
0.44
1.44
0.89
0.89
0.70
0.75
Total capital investment (TCI)
Plant Design and Economics for Chemical Engineers, 5th edition, by Peters, Timmerhaus and West.
3.200
0.320
3.520
1.654
1.267
2.394
0.387
0.634
0.352
2.464
12.672
1.162
1.443
0.141
0.774
1.549
5.069
17.741
3.133
20.874
Item
Raw materials
Operating labor
Operating supervision
Utilities
Maintenance and repairs
Operating supplies
Laboratory charges
Royalties (if not on lump-sum basis)
Catalysts and solvents
Taxes (property)
Financing (interest)
Insurance
Rent
Depreciation
Plant
overhead,
general
Administration
Distribution & selling
Research & Development
Default factor,
user may change
0.15
Basis
of operating labor
0.06
of FCI
of maintenance & repair
0.15
0.15
of operating labor
of co
0.01
0
-Variable cost =
0.02
of FCI
0
of FCI
0.01
of FCI
0
of FCI
1.380
0.000
0.000
1.380
76.264
0.000
0.000
0.000
0.000
Calculated
separately
Fixed Charges =
0.6
Plant Overhead =
Manufacturing cost =
0.2
0.05
0.04
General Expense =
TOTAL PRODUCT COST WITHOUT DEPRECIATION = co =
63.010
1.380
0.207
2.563
0.000
0.000
0.207
0.763
0.000
68.130
0.000
0.000
0.000
0.000
0.000
of labor, supervision and maintenance
1.587
0.952
0.952
69.083
1.587
76.264
76.264
0.317
3.813
3.051
7.181
76.264
Plant Design and Economics for Chemical Engineers, 5th edition, by Peters, Timmerhaus and West.
60
40
20
-4
-2
0
0
-20
Time/Years
-40
10
12
14
$ 20,874,000
$ 79,241,000
$1,310,000
Return on Investment
(ROI)
21%
SAFETY AND
ENVIRONMETAL
CONSIDERATIONS
Deviation
Possible Cause
Less of
flow
Partially failure of
pump
Control valves fails
to respond
Possible Consequences
Insufficient feed to
tower
Incomplete
separation
Action Required
Check
maintenance
Install alarm
system
More of
flow
Overflow
Control valves fail to
respond
Overfeed to
distillation
Pressure increases in
the distillation
Reverse
flow
Failure of pump
Backflow of mixture
Non-return valve
Very flammable
Headache, dizziness, unconsciousness
Leukemia
Damage to bone marrow
Flash Point -11.63 C ; Auto Ignition ignite at 498 C
Propylene
Flammable
High concentration inhalation can cause unconsciousness
Flash Point -108 C; Auto Ignite at 480 C
http://www.epa.gov/iris/toxreviews/0306tr.pdf
Cumene
Flammable
May
cause cancer
Slight skin irritation
Flash Point 44 C ; Auto Ignite at 523 C
Benzene and Propylene must be kept away from any heat source, spark
or flames.
Benzene and Propylene will be transported through pipe lines to the
plant
Cumene
Cumene should be stored away from sources of ignition and in a wellventilated area
Cumene can be stored in carbon steel or other metal including cooper
and iron.
Cumene is shipped in Ocean going vessels, barges, truck and mostly
pipe lines.
http://www.axiall.com/pdf/cumene_info.pdf
CUMENE
DIPB
Health Effects
First Aid
Measures
Engineering
Controls
Very hazardous
Toxic to lungs
and nervous
system
In case of
contact, flush
eyes
Wash skin
immediately
Provide
Ventilation
Adhere to vapor
concentration
threshold
ACKNOWLEDGEMENTS
Dr. Osborne-Lee
Dr. Michael Gyamerah
Dr. Emmanuel Dada
Dr. Audie Thompson
Dr. Sheena Reeves
Dr. Jorge Gabitto
Industrial Advisory Council Members
The Chemical Engineering Department PVAMU
QUESTIONS?
REFERENCES
Eagleson, Mary (1993). H. In Concise Encyclopedia Chemistry.