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Heat Transfer
Heat transfer from hot regions to
cold regions takes place
whenever there is a temperature
difference.
The rate at which heat flows
from hot to cold depends on
many factors, but there will
always be some flow.
The shape of the temperature
gradient is defined by the
conditions (hot and cold face
temperatures, thermal
conductivity of barrier, heat
capacity and thickness of
material etc.).
Temp
Hot face
Cold face
Hot face
temp
Temperature
gradient
Cold face
temp
Transient Conditions
During transient conditions the system sees a net gain or loss in heat
T=0
Both sides of wall
at ambient temp
T = 10 mins
Radiator started
but heat has not
reached cold side
of wall
T = 30 mins
Cold side of wall
warming up
T = 60 mins
Steady state
achieved
mICROTHERm
mICROTHERm
Thermal Conductivity of
Solids, Liquids and Gases
Microtherm VIP
Microtherm
Gases
Liquids
Other solids
Metals
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Conduction
All materials transfer heat by conduction as their component atoms
or molecules exchange energy through collisions.
Solids are the most effective conductors of heat. Although the
atoms in a solid have fixed positions, they constantly vibrate and
interact with their neighbours. In hot areas the atoms vibrate more
strongly, so the interactions tend to pass energy to cooler regions
resulting in heat flow. Some solids conduct heat much better than
others, depending on the way the atoms are bonded together.
Liquids are generally less good conductors of heat than solids.
The interactions are weaker than in solids and this makes energy
transfer less efficient.
Gases are very poor conductors of heat. The atoms or molecules
are widely separated and interact rarely compared to solids and
liquids.
Conduction Through a
Heated Rod
HOT
(lots of vibration)
COLD
(not much vibration)
Heat travels
along the rod
Microporous Insulation
Control of Solid Conduction
Solid conduction is minimised by:
Using solids with low intrinsic thermal conductivity.
mICROTHERm
Gaseous Conduction
Gaseous conduction at atmospheric pressure is much less efficient
than solid conduction because interactions between molecules are
less frequent. However, it is still an important heat transfer
mechanism.
When a gas molecule collides with another gas molecule, energy is
exchanged. This is an efficient way of transferring heat through a
gas.
Microporous Insulation
Control of Gaseous Conduction
The average distance travelled by a molecule between collisions with
other gas molecules is defined as the mean free path of the gas.
To effectively prevent gaseous collisions the average pore size
should be smaller than the mean free path of the gas (60 nm in air at
0C). This is the definition of a microporous insulation.
Due to the extremely small particle size of the
silica particles (5-25 nm), the pore size in
mICROTHERm meets this criterion.
However, up to 80% of thermal conductivity
through mICROTHERm at room
temperature occurs by this mechanism. This is
still much less than other insulation materials.
Mean free path of gas molecule
Convection
Convection is heat transfer by bulk
movement within a heated fluid
such as a liquid or a gas.
Free convection is caused by
expansion of fluids when heated,
causing hot regions to become
buoyant. Circulation occurs as the
hot fluid cools and sinks down
again.
Free convection systems can be
very large and convey massive
amounts of heat, for instance in
weather systems and the circulation
of molten rock inside the Earth.
Velocity = v
Velocity
Boundary
Layer
Temperature
Boundary
Layer
Velocity = 0
Free convection
Forced convection
Microporous Insulation
Control of Convection
Gaseous convection is easily eliminated as a heat transfer
mechanism through all common insulation materials by making the
average void space in the structure small enough that convection
currents cannot form.
The higher the temperature in the material, the smaller the voids
need to be.
Infra-Red Radiation
Radiation is heat transfer by the emission of electromagnetic waves
which carry energy away from the emitting object.
Radiative heat losses from a surface increase rapidly with
temperature as defined by the Stefan-Boltzmann equation.
q = (T4surface - T4surroundings)
q = radiative heat flux in W/m2
= emissivity of the surface (between 0 and 1, depending on the material)
= Stefan-Boltzmann constant in W/m2K4
Tsurface = temperature of object in K
Tsurroundings = temperature of surroundings in K
Infra-red radiation is the principal mode of heat loss at
temperatures above about 100 C
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Radiative
Convective
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Increasing heat
Microporous Insulation
Control of Infra-Red Radiation
mICROTHERm insulation includes thermally stable metal oxide
Incident radiation
Opacifier particles
Effect of Opacifier on
Performance of Microporous Silica
Opacifiers are the reason for the low slope in the
mICROTHERm thermal conductivity curve.
0.1
0.09
0.08
0.07
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0
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