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What is petroleum
What is petroleum
Petroleum is a mixture of naturally occurring hydrocarbons which
may exist in the solid, liquid, or gaseous states, depending upon the
conditions of pressure and temperature to which it is subjected.
Whereas natural gas contains a few lighter hydrocarbons, both crude
oil and tar deposits may consist of a large number of different
hydrocarbons.
1) Liquid Hydrocarbons: Crude oil or Petroleum
2) Gas Hydrocarbons: Natural Gas: methane,
butane, propane, etc.
3) Solid Hydrocarbons: Tars and Asphalt
What is petroleum
Virtually all petroleum is produced from the earth in either liquid or gaseous form,
and commonly, these materials are referred to as either crude oil or natural gas,
depending upon the state of the hydrocarbon mixture.
Petroleum consists chemically of approximately 11 to 13 wt % hydrogen and 84 to
87 wt % carbon.
Traces of Oxygen, Sulfur, Nitrogen, and Helium may be found as impurities in crude
petroleum.
Although all petroleum is constituted primarily of carbon and hydrogen, the
molecular constitution of crude oils differs widely .
Sulfur Compounds.
Nitrogen
Oxygen
Little metals
1) Nitrogen (
2) carbon dioxide
3) hydrogen sulfide (
Chemistry of Petroleum
Resins and Asphaltenes
The chemicals in petroleum are classified as:
1) Paraffins
2) Naphthenes
3) Aromatics
4) Resins-asphaltenes
Resins and asphaltenes are large molecules, primarily hydrogen and carbon,
with one to three sulfur, oxygen, or nitrogen atoms per molecule.
The basic structure is composed of rings, primarily aromatic, with from three to
ten or more rings in each molecule. The non hydrocarbon atom can be a part of
the ring structure or can be located in links connecting the rings.
The color of petroleum is determined largely by the quantity of resins and
asphaltenes present, although the greenish cast of some crude oils is probably
due to the presence of molecules containing six or more rings.
Composition of petroleum
Average and Range of Hydrocarbon series molecules in Crude Oil
Origin of petroleum
The theories of the origin of petroleum may be classified as:
1) Organic
2) Inorganic
Origin of petroleum
Origin of petroleum:
1) Organic theories:
The organic theories assume that petroleum evolved from
decomposition of vegetable and animal organisms that lived during
previous ages.
2) Inorganic theories:
The inorganic theories attempt to explain the formation of petroleum
by assuming chemical reaction among water, carbon dioxide and
various inorganic substances such as carbides and carbonates, in the
earth.
Origin of petroleum
The organic theory of petroleum origin (most accepted)
Ancient seas covered much of the present land area millions of years ago
Over the years, rivers flowing down to these seas carried large volumes of mud
and sedimentary materials ( containing small plants and animals) into the sea.
The buildup of thousands of feet of mud and sediment layers over the sea floor.
The sea floors were slowly sink and squeezed to form the sedimentary rocks (the
sandstones and shales, and the carbonates)
Over many years, pressure, temperature, bacteria, and other reactions caused
these dead organisms to change into oil and gas.
The rocks where oil and gas were formed are known as the source rock.
Origin of petroleum
1)
2)
3)
4)
1) Primary migration
2) Secondary migration
2) Secondary migration:
The further movement of the hydrocarbons into reservoir rock in a
hydrocarbon trap or other area of accumulation is secondary migration.
Traps
If nothing stops oil from rising, it will reach surface.
A natural barrier, or trap, must exist for a petroleum
accumulation to form.
Trap:
A configuration of geologic features where oil and gas (petroleum) can be
barred from further movement.
Traps
As oil and gas are lighter than the ground water which permeates the porous rocks
below the water table, it is evident that the upward movement of petroleum must be
restricted in order that accumulations exist at depth
Traps
Theclosureofthetrapisthedistancebetweenthecrestandthespill
point(lowestpointofthetrapthatcancontainhydrocarbons).
Traps
Classification of Hydrocarbon Traps
1) Structural traps :Structuraltrapsaretrapsthatareformedbecauseof
adeformationintherocklayerthatcontainsthehydrocarbons.
a) Anticlinaltraps:anupwardfoldinthelayersofrock
b) Faulttraps:Afaulttrapoccurswhentheformationsoneithersideof
thefaulthavebeenmovedintoapositionthatpreventsfurther
migrationofpetroleum.
c) diapirictraps:producedbyintrusionofsaltormuddiapirs
2) Stratigraphic traps: resultwhenadepositionalbedchangesfrom
permeablerockintofine-grainimpermeablerock
Traps
Traps
Types of Rocks
Igneous Rocks
about20%ofallrocks
theyaretheproductofthecoolingofmoltenmagma
intrudingfrombelowthemantleofthecrust.
Metamorphic rocks
about14%ofallrocks
originatefrommechanical,thermal,andchemical
changesofigneousrocks
Sedimentary Rocks
about66%ofallrocks
theyareimportanttothestudyofpetrophysicsand
petroleumreservoirengineering.
Limestone and
dolomite
~13%
Siltstone, mud
and shale
~75%
Dimensions:
Air.
Specific gravity for liquids
at
T= 60 F = 15 F = 288.15 K
at
T= 60 F = 15 F = 288.15 K
Conversely,
Crude Oils
Light Crude
Heavy Crude