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Engineering Thermodynamics
The thermodynamics properties of
fluids (II)
Q&A_-10-
11/17/2005(10)
Ji-Sheng Chang
Property relations
Property relations
Property relations
Property relations
G
1
P V
(
)dP,
0 RT P
RT
GR
dP
P
( Z 1) ,
0
RT
P
(constant T)
(constant T)
Property relations
H
dP
P Z
T
,
0 T
RT
P P
(constant T)
Property relations
0 T
0
RT
P
P P
(constant T)
Property relations
Property relations
GR
dP
P
( Z 1) ,
0
RT
P
(constant T)
dP/P=d/+dZ/Z,
as the formula (6.58)
GR
d
( Z 1)
Z 1 ln Z ,
0
RT
(constant T)
RT
V
(constant T)
Property relations
GR
P Z 1
dP,
0 P
RT
(constant T)
Phase diagram
1. PT phase diagram of water
2. The Solid/Liquid equilibrium curve
500
for water
for most component
400
300
P /b a r
PC,TC
200OC path
200
Solid
100
Critical properties
Liquid
PC=220.55 bar
Gas
TC=647.1 K
0
0
200
400
T /K
600
800
1000
TTri=273.16 K
B
ln P /kPa A
T/ C C
sat
Property
PTri=0.611 kPa
TTri=273.16 K
Tn=373.15 K
at P= 1.01325 bar = 1 atm
Property relations
Problems
Calculate the residual Gibbs
energy of the 200C superheat
steam at 10 bar, using the PVT
data from steam tables
Properties
P/kPa
1
P/bar
V/cm3g- V/cm3mol
1
0.01 218350
(Z-1)/P
3933575 0.999951
-0.00493
-1
50
0.5
-0.00514
100
-0.00518
200
-0.00522
300
-0.00528
400
-0.00533
500
-0.00539
600
-0.00545
700
-0.00551
800
-0.00557
Properties
P/kPa
P/bar
900
V/cm3g- V/cm3mol
(Z-1)/P
-0.00563
1000
10
-0.0057
1100
11
-0.00577
1200
12
-0.00583
1300
13
-0.0059
1400
14
-0.00597
1500
15
-0.00604
1550
15.5
127.61 2298.894
0.90582
-0.00608
1554.9
15.55
-0.00606
-1
G R /R T o f s u p e r h e a t s te a m
200OC
[ b a r -1 ]
-0 .0 0 2
(Z -1 )/P
-0 .0 0 4
-0 .0 0 6
-0 .0 0 8
0
[bar ]
12
16
20
Example 1
Deriving the
formulas
The equations of
residual Gibbs free
energy
Three type of the
two term virial
equation
Deriving the
formulas
Second virial
coefficient
Based molecular
thermodynamic, it
is integrated from
potential function
Example 2
Example 3
Theorem of
corresponding states
Two-parameter theorem of
corresponding states
Given T and P
Finding Tc, Pc
Calculate Tr, Pr
Using Tr, Pr to finding the reduced
properties from Table E.1 to E.16
Theorem of
corresponding states
Three-parameter theorem of
corresponding states
Given T and P
Finding Tc, Pc,
Calculate Tr, Pr
Using Tr, Pr, to finding the
reduced properties from Table E.1 to
E.16
Theorem of
corresponding states
Example 4
Example 5
Example 6