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STRUCTURE
Chemistry @ MBCC
Pre-University Sciences
Science 1
Hypothesis
What is a hypothesis?
An educated guess, based on observation
A hypothesis can be used to:
to guide experimentation
aid in problem solving
help develop new theories
Hypotheses
can be supported or refuted through experimentation
can be disproven, but not proven to be true
Theory
Scientific theory summarizes a hypothesis or group
of hypotheses that have been supported with repeated
testing
Theories are well-established explanations for
experimental data
A theory is an accepted hypothesis
Theory
valid as long as there is no evidence to dispute it
usually can not be proven, but can be disproven
DALTONS ATOMIC
THEORY
Four main assumptions:
1. Matter consists of small particles called atoms
2. Atoms are indestructible or indivisible
3. Atoms of the same elements are identical in mass &
properties
4. Atoms combine chemically in simple whole number
ratio to form compounds
- Atoms combine in more than one simple whole number ratio
Daltons Notebook
A page from Dalton's
notebook, burned
in the bombing of
Manchester
in World War II
Note the
Atomic Structure
Atoms are electrically neutral species
Contains equal numbers of Protons and Electrons
Neutrons are uncharged
Nucleus
Subatomic Particles
Mass of subatomic particles is measured
Relative Mass
Relative
Charge
Location
Proton
+1
Nucleus
Neutron
Nucleus
Electron
1/1837
Orbital
Electrons
(lightest) are
deflected at large
angles to the
positive (+) poles
Protons
(heaviest) are
deflected at
smaller angles
towards the
negative () poles
Neutrons
(uncharged)
continue
undeflected
through the field
Behaviour of subatomic
particles in an Electric (or
Magnetic) field
Use Flemings
diagram
represent
magnetic field
going into the
paper
Lighter
particles are
deflected
more
compared to
the heavier
particles
Behaviour of particles in
a Magnetic field
http://term2chemace.wikispaces.com/1.2+-+Behaviour+in+Different+Types+of+Fields
Review: Definitions
Atomic Number (Proton number)
Number of protons in the nucleus of an atom
Mass Number (Atomic Mass/Nucleon Number)
sum of the protons and neutrons in the nucleus of the atoms
Isotopes
Atoms of an element that have the same
Isotopes
Element
Hydrogen
Carbon
Chlorine
Bromine
Isotope
Atomic
Number
(Protons)
Neutrons
Mass
Number
Hydrogen-1
Hydrogen-2
Hydrogen-3
Carbon-12
12
Carbon-13
13
Chlorine-35
17
18
35
Chlorine-37
17
20
37
Bromine-79
35
44
79
Bromine-81
35
46
81
Cl
34.97
75.8
37
Cl
36.97
24.2
75.8
24.2
Ar
34.97
36.97
100
100
A r 26.507 8.947
A r 35.45
Atomic
Weight
Natural Cl
35.45
35
Cl
34.97
37
Cl
36.97
Homework
Calculate the relative atomic mass (Ar) of
zirconium from the mass spectrum data of zirconium
atoms given below.
Atomic
Isotope
Atomic Weight
Relative Abundance/%
Zr
90
51.5
Zr
91
11.2
Zr
92
17.1
Zr
94
17.4
Zr
96
2.8
90
91
92
94
96
Home Work
Calculate the relative isotopic abundance
of the two isotopes of hydrogen (1H and 2H)
given the following data below.
Atomic Isotope Atomic Weight
Natural H
1.0080
1.0078
2.0141
Radioactivity
1.4 E xp la in th e ph en o menon
of ra di oa cti v ity
Radioactive Isotopes
Nucleus
Strong nuclear force of attraction between nucleons
(protons & neutrons)
Nuclei Stability
Nuclei becomes stable by impulsively ejecting
radioactive particles or radiation
Alpha particles
Beta particles
4
2
He 2
0
1
Gamma radiation
Behaviour of Radioactive
Particles in a Magnetic Field
Alpha Particles
2
He
Helium Nuclei
4
2
4
2
Symbol
He
238
92
U He
4
2
234
90
Th
Beta Particles
n 11p
0
1
Na
0
1
24
12
Mg
Gamma Radiation
Electromagnetic waves of short wavelength
Emission of alpha or beta particles are usually
accompanied by emission of gamma rays
Band of Stability
Plot of
Nuclei above
the band of
stability with a
high n/p ratio
can move
towards the
band of stability
by emitting a
beta particle
Heavy nuclei
with atomic
number >84
tend to move
towards stability
by emitting an
alpha particle
Band of Stability
http://ccef-coree.com/wp-content/uploads/2010/05/image033.jpg
Homework
1. Find seven or more uses of radioactive isotopes?
2. Find six ways in which radioactive waste is
disposed?
3. List and explain the main steps involved in Mass
Spectrometry
4. Draw and label a diagram of a Mass Spectrometer
5. List the uses of Mass Spectroscopy
Mass
Spectrometer is
used to analyze
the masses of
isotopes and
their relative
abundances
Principle of MS
1. VAPOURISATIO
N
2. IONISATION
3. ACCELERATION
4. DEFLECTION
5. DETECTION
The Mass
Spectrometer
Fast moving ions are deflected by magnets; lighter ions are deflected the most
Angle of deflection depends on m/z ratio
Detection
Percentage
abundance (or
intensity) vs
m/z
m/z is mass to
charge ratio
Ions with a
single charge
are selectively
accelerated
Ions with a
single charge
have m/z value
which is
equivalent to
mass itself
Mass
Homework
Use the data from the mass spectrum below to
determine the RAM of the element
The Electromagnetic
transmitted energy
EMR consists of all types of energy that can be
seen, felt or recorded
EMR can be viewed as:
Particle
Wave
EMR Particle
EMR can be viewed as particles (packets) of
Have no mass
Travel in wavelike pattern
Speed of light (High Velocity)
EMR Wave
EMR can be viewed as a travelling wave
Wavelength
Frequency
Velocity (Speed)
E h
where: E is the energy (J)
h is Plancks constant (6.63 x 10-34 J s)
is frequency (Hz or s-1)
EMR Calculations
The wavelength and frequency of EMR are
related
c
c = 3 x 108 ms-1
Useful Conversions
EMR Calculations
Energy can be expressed in terms of the speed of
light, wavelength or wavenumber
hc
E h
1 m is equal to 10-6 m
5 m is equal to 5 x 1 x 10-6 m = 5 x 10-6 m
5 x 10-6 m
E 3.978 x 10-20 J
Useful Conversions
Deci, d 10-1
Centi, c
10-2
Milli, m
10-3
Micro , 10-6
Nano, n
10-9
Pico, p 10-12
Femto, f
10-15
Atomic Spectra
Atoms interact with EMR
Atoms absorb (or emit) light of a
particular wavelength (or frequency)
Distinct lines
Two types of line spectrum
Absorption spectrum
Emission spectrum
Absorption Spectrum
A Line spectrum
Emission Spectrum
A Line spectrum
Coloured lines on dark background represent
wavelengths of light emitted by element
Energy Levels
Atoms and molecules have
unique set of energy levels
Emission
Quantum of energy (photon) is emitted from the atom
resulting from the excited electron in a higher energy
level falling back to a lower energy level
Atomic Spectra
Each element produces a unique spectrum that
can be used to identify it
explains
Energy of the electron is
quantised
Atom or molecule absorbs or
Emission Spectrum of
Hydrogen
Each line in the emission (line) spectrum of
hydrogen
Specific frequency
Specific wavelength
Specific quantum of energy (E = Ey Ex)
Evidence: Discrete energy levels in the atom
There is a point in
spectrum where the
lines converge
Convergence
corresponds to
electrons falling
from the highest
possible energy
level (highest
frequency)
Line Series
Balmer Series
Electron transitions from higher energy levels to principal
quantum number, n = 2
Paschen Series
Electron transitions from higher energy levels to principal
quantum number, n = 3
Pfund Series
Electron transitions from higher energy levels to principal
quantum number, n = 5
Quantum numbers
The properties of an atom's electron
configuration are described by four quantum
numbers
=
=
=
=
1
2
3
4
2
8
18
32
s,
p, d, f
Each energy level has n sublevels
Energy
Level
n=1
n=2
n=3
n=4
No. of
Sublevels
1
2
3
4
Sublevels
1s
2s, 2p
3s, 3p, 3d
4s, 4p, 4d,
4f
Shapes of Orbitals
Shapes of Orbitals
Sublevel
s
No. of
Orbitals
1
Max.
Electrons
2
10
14
Quantum Numbers
s Orbitals
Spherical
Each energy level has one s orbital
Maximum number of electrons = 2
1s and 2s orbitals are similar in shape however
electron density is closer to the nucleus for the 1s
orbital
p Orbitals
Dumb-bell shape
Each energy level has three (3) degenerate p
orbitals i.e. three (3) orbitals of EQUAL ENERGY
Electronic
Configurations
How do we fill up energy levels with electrons?
We use three rules
1. Aufbau Principle
Electrons are added one at a time,
starting with the lowest energy orbital
s orbitals have slightly lower energy than the p
orbitals in the same energy level i.e. 2s < 2p
s<p<d<f
1. Aufbau Principle
(Contd)
Anomaly
Irregularity in the position of the 3d and 4s orbitals
3d has slightly more energy than 4s
4s fills first then 3d orbitals followed by 4p orbitals
2. Pauli Exclusion
Principle
No more than two electrons can occupy an orbital
The two (2) electrons in the same orbital must
have opposite spins
Why?
3. Hunds Rule
Electron-in-Box Method
The E.C for nitrogen may be written as:
Orbital Method
Principal Quantum number (1, 2, 3 etc.)
Symbol for the orbital (s, p, d, f)
Superscript that shows the number of electrons in
the sublevel
Orbital method to
write the E.C as:
But remember the
Electronic Configurations
Atomic Number
Symbol
Electronic
Configuration
1s1
He
1s2 or [He]
Li
[He] 2s1
Be
[He] 2s2
10
Ne
Electronic Configurations
Atomic Number
Symbol
Electronic
Configuration
11
Na
[Ne] 3s1
12
Mg
[Ne] 3s2
13
Al
14
Si
15
16
17
Cl
18
Ar
19
[Ar] 4s1
20
Ca
[Ar] 4s2
Electronic Configurations
Atomic Number
Symbol
Electronic
Configuration
21
Sc
22
Ti
23
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
Filling up Orbitals
or full
Given two configurations, the atom would
"choose" the more stable one
For example:
Cr
Cu
decreases energy
Spin pairing of the 4s orbital increases energy
https://www.caymanchem.com/app/template/chemAssistant,Tool.vm/itemid/4001
1. Atomic Radii
Atomic radiusis generally stated as being
the distance from an atoms nucleus to the
outermost orbital of electron
As distance increases:
nuclear attraction for the outer electron decreases
ionization energy decreases
Energy (kJ)
1st
496
3s
2nd
4562
2p
3rd
6912
2p
4th
9543
2p
5th
13353
2p
6th
16610
2p
7th
20114
2p
2. Nuclear Charge
The effective nuclear charge (zeff )of an atom is
the net positive charge felt by the valence electron
As Zeff increases:
attraction of the nucleus for the outer electron
increases
ionization energy increases
http://wps.prenhall.com/wps/media/objects/602/616516/Chapter_06.html
Element
1st
2nd
3rd
4th
Na
496
4562
6912
9543
101
2
1903
2912
4956
??
738
1451
7733
??
787
1577
3231
5th
6th
Group
13353 16610
2223
3
??
4356
6273
16091 19784
??
3.5
For example in Mg we
3.0
2.5
Anomalies
1st I.E. of boron is smaller than beryllium (similarly Al smaller than Mg)
1st I.E. of oxygen is smaller than nitrogen (similarly S smaller than P)
Be 1s22s2
1s2 2s22p1