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Classifications
Fuels can be broadly classified by origin as,
(i)Primary or natural fuels: coal, wood etc
(ii)Secondary or artificial or derived fuels: petrol, diesel
Liquid fuels
(iii)
Gaseous fuels
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Basis
Origin
Source Natural or
primary
Artificial
Secondary
Derived
Physical
State
or
or
Petrol,
kerosene,
gas oil, coal tar,
alcohol
Liquid
fuels
Natural gas
Gaseous
fuels
Characteristics of Fuels
The physical properties for which fuels are tested
and their ideal requirements are listed below :
(i)Calorific value or specific heat of combustion.
- efficiency of fuel: how much heat it produces
(ii)
Ignition temperature
(iii)
Flame temperature
(iv)
(v)
Aniline point
(vi)
Knocking.
Viscosity
(x)
Coke number.
(ii)
Percentage of moisture
(iii)
(ii)
Calorific Value
number of units of heat evolved during complete
combustion of unit weight of the fuel.
A British Thermal Unit: the heat required to raise
the temperature of one pound of water from 60 F to
61 F.
The Calorie: the heat required to raise the temperature
of one gm of water by 1C (15C to 16C) at standard
atmospheric pressure.
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Bomb Calorimeter
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If H = % of hydrogen in fuel
9H/100 g = mass of water from 1 g of fuel= 0.09H g
So heat taken by water in forming steam = 0.09 H
587 cal
LCV = HCV - 0.09 H 587 cal/g
By considering fuse wire correction, acid correction
& cooling corection
L = [{(W+w)(t2-t1+ cooling correction)}- {acid +fuse
correction}]/x cal/g or kcal/kg
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Sr.
No.
Property
Solid Fuels
Liquid Fuels
Gaseous Fuels
1.
Calorific value
Low
Higher
Highest
2.
Specific gravity
Highest
Medium
Lowest
3.
Ignition point
High
Low
Lowest
4.
Efficiency
Poor
Good
Best
5.
6.
Cannot be used
Already in use
Can be used
7.
Mode of supply
Cannot be piped
Can be piped
Can be piped
8.
Large
9.
Relative cost
Cheaper
Costly
More costly
other two
10.
Care is necessary
than
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Combustion
Combustion is a process in which oxygen from the
air reacts with the elements or compounds to give
heat.
As the elements or compounds combine in indefinite
proportions with oxygen, we need to calculate what is
minimum oxygen or air required for the complete
combustion of compounds. The commonly involved
combustion reactions are :
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C + O2 CO2
2H2 + O2 2H2O
OR H2 + (O) H2O
S + O2 SO2
2CO + O2 2CO2
OR CO + (O)
CO2
v)
CH4 + 2O2 CO2 + 2H2O
vi) 2C2H6 + 7O2 4CO2 + 6H2O
vii) C2H4 +3O2 2CO2 + 2H2O
viii) 2C2H2 + 5O2 4CO2 + 2H2O
i)
ii)
iii)
iv)
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C
+
O2
CO2
(12 gm) +
(32 gm)
(44gm)
1
1
1
e.g
by weight
by volume
2H2 +
O2
by weight
(4 gm) +
by volume
2
S
by weight
by volume
+
O2
(32 gm) +
1
2H2O
(32 gm)
(36gm)
1
2
SO2
(32 gm)
(64gm)
1
1
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Weight of
elements per kg.
of coal
Weight of O2 required
for complete combustion
in kg.
C = 0.85
H = 0.1
O = 0.05
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Classification of Coal
Sr Types
No of Coal
Moisture
of Air
Dried At
40C
C
%
H
%
O
%
Ash
%
Calorific
Value
(kcal/kg)
Uses
1.
Peat
25
57
35
5400
2.
Lignite
20
67
20
6500
Manufacture
of
producer gas, thermal
power plants.
3.
Bitumi
nous
83
15
8000
For
metallurgical
coke, coal gas, boiler,
domestic purpose
4.
Anthra
cite
92
8600
Boilers, metallurgical
fuel, domestic
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Analysis of Coal
Moisture
It is determined by heating about one gm. of finely
powdered coal at 105C to 110C for an hour in
electric oven. The loss in weight is reported as due to
moisture.
% Moisture = [loss in wt of sample 100]/wt of coal
taken
Decreases calorific value of coal
Takes away heat in the form of latent heat
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Volatile matter
For determining volatile matter content, a known weight of
dried sample is taken in a crucible with properly fitting lid.
It is then heated at 950C 20C for exactly seven minutes
in previously heated muffle furnace. The loss in weight is
due to volatile matter which is calculated as
Volatile matter = [loss in wt at 9500C 100]/wt of coal
sample
Decreases calorific value
Forms smoke and pollutes air
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Fixed carbon
% of Fixed carbon = 100 (% of moisture + % of ash +
% of volatile matter)
In any good sample of coal, the percentages of
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Determination of C & H
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C + O2
CO2
12 parts
44 parts
2H2 + O2
2H2O
4 parts
36 parts
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Determination of Nitrogen
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Procedure
The method consists of heating a substance with sulphuric acid, which
decomposes the organic substance by oxidation to liberate the reduced
nitrogen as ammonium sulphate. In this step potassium sulphate is added to
increase the boiling point of the medium (from 337 C to 373 C) . Chemical
decomposition of the sample is complete when the initially very dark-coloured
medium has become clear and colourless.
The solution is then distilled with a small quantity of sodium hydroxide, which
converts the ammonium salt to ammonia. The amount of ammonia present,
and thus the amount of nitrogen present in the sample, is determined by back
titration. The end of the condenser is dipped into a solution of boric acid. The
ammonia reacts with the acid and the remainder of the acid is then titrated with
a sodium carbonate solution by way of a methyl orange pH indicator.
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Degradation:
Sample + H2SO4 (NH4)2SO4(aq) + CO2(g) + SO2(g) + H2O(g)
Liberation of ammonia:
(NH4)2SO4(aq) + 2NaOH Na2SO4(aq) + 2H2O(l) + 2NH3(g)
Capture of ammonia:
B(OH)3 + H2O + NH3 NH4+ + B(OH)4
Back-titration:
B(OH)3 + H2O + Na2CO3 NaHCO3(aq) + NaB(OH)4(aq) + CO2(g) + H2O
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Determination of Nitrogen
Nitrogen is calculated by Kjehldals Method.
The nitrogen is converted to NH3 and passed through a known volume
of standard acid. On neutralization, the excess acid is back titrated
with a base.
1000 ml of x N acid
14 gm of Nitrogen
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Determination of Sulphur
% Sulphur: [wt of BaSO4 obtained 32 100]/wt
of coal taken 233
Determination of Oxygen:
The oxygen is determined indirectly by calculation
as
% of Oxygen = 100 (% of C + % of H + % of N +
% of S + % of Ash)
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