Professional Documents
Culture Documents
Activator
Adjuvants
?
Utility
Modifier
Adjuvants
Utility
Products
Adjuvant Confusion!
Compendium of Herbicide Adjuvants
(Southern Illinois University 1/02)
Lists 36 different companies selling various types
of adjuvants. There are more!
Lists 440 different adjuvants. There are many
more!
What is an Adjuvant?
An adjuvant is any additive used in
conjunction with a pesticide to increase
biological activity and/or to modify various
physical properties of a spray solution.
Importance of Adjuvants
Spray applications are affected by many physical variables
Pesticide Stability
Solubility
Compatibility
Foaming
Suspension
Surface Tension
Droplet Size
Drift
Volatilization
Coverage
Adherence
Penetration
Utility Products
Minimize Application Problems
Foam Markers, Tank Cleaners
Adjuvants Types
Surfactants (also called spreaders or wetting agents)
An adjuvant that reduces surface surface tension between
the spray solution droplets and the pest targets surface,
thus providing greater coverage.
Spreader/Stickers/Extenders
Combine spreading and adhesive qualities to improve
coverage and retention of pesticide.
Deposition Aid
Reduces the amount of fine spray particles that carry
pesticide out of target areas. (polyacrylimides,
encapsulators, others)
Reduces evaporation of the spray droplet; Used during
high temperature, low humidity and low spray volume
situations.
Buffer Agents/Acidifiers
Generally lower the pH of the spray solution and reduce
rapid changes in pH either higher or lower.
Reduces the degradation of pesticides by chemical hydrolysis.
Dimate, Malathion, Sevin, etc.
Colorants
Used to alter the color of spray solutions.
Defoaming Agents
Suppresses foam of various pesticide solutions, aids in
filling tanks
Foaming Agents
Used for marking swath width.
Quality Issues
Lack of consistent regulation
Confusion and Opportunity
Yes, there is a difference among adjuvants - All
adjuvants are NOT created equal.
(Dr. Richard K. Zollinger-NDSU)
Activator Adjuvants
Herbicide Specific
Work well with some herbicides, but not all!
Non-ionic surfactants work well with Roundup while
oil based surfactants inhibit Roundup performance.
Herbicides Differ
Water soluble versus oil soluble
Contact versus Systemic
Weed Specific
Work well with some, but not all weeds!
Oil based surfactants are generally more effective for
annual grasses and lambsquarters which have waxy
cuticles.
Environmentally Specific
Soil moisture, temperature, humidity
Non-ionic surfactants provide better crop tolerance
during high humidity conditions than do oil based
adjuvants. Meanwhile, methylated seed oil based
adjuvants provide better control during very dry
conditions compared to non-ionic surfactants or
conventional crop oil concentrates.
Surfactants
Surfactants
Form a bridge between unlike chemicals
that dont readily mix
water and oil
water and the wax on a leaf surface
Surfactants
Without Surfactant
With Surfactant
Surfactants
Surfactant Activity
Structure
Hydrophilic
Activity
Oil droplet
Lipophilic
Water
Charged Surfactants
(Anionic, Cationic and Amphoteric)
Anionic surfactants have a negative charge and
have limited compatibility with pesticides.
Cationic surfactants have a positive charge and
have limited compatibility with pesticides.
Amphoteric surfactants have both charges and
may vary their charge with changes in pH.
Charged adjuvants may be more effective with
salts (glyphosate, 2,4-D amine, etc.)
Uncharged Surfactants
(Non-Ionic)
Uncharged or non-ionic surfactants are
compatible with most pesticides
There is a wide variety of non-ionic chemistry
Some inert chemicals are considered to be
adjuvants as they reduce surface tension. These
chemicals (butanol, diethylene glycol, etc.) have
little or no biological activity.
Surfactants
Typical ingredients of surfactants
Polyethylene Glycol
used mainly as a filler, no biological activity
Diethylene Glycol
used mainly as a filler, no biological activity
Diols
These terms can all mean the same thing and may
refer to the same constituent.
Surfactant Load
HLB - Hydrophilic:Lipophilic Balance
Contact Angle
Draves Wetting
Surface Tension
Surfactant Load
Is a measure of the exact content of true
non-ionic surfactants in a particular
product.
Expressed as percentage.
A product with a true surfactant load of
< 50% may not meet the requirement for
an adjuvant as specified by some
pesticide manufacturers.
10% Water
10% Water
90/10 Surfactant ?
(89.9/10.1)
90/10 Surfactant ?
(55/45)
HLB
(Hydrophilic:Lipophilic Balance)
HLB is the relationship between the nature
of the hydrophilic and lipophilic portions
of the surfactant molecule. The range of
HLB is 1-20. The higher the value the
more hydrophilic the surfactant. Most
effective surfactants have a value between
10-18. The HLB is not measured, it is
calculated. Research has shown that there
is significant herbicide/HLB/weed
interactions
10
Prime Oil
Destiny
Superb HC
Sterling/Banvel, Blazer,
Galaxy, Gramoxone,
Liberty, Pursuit, Reflex,
Cornerstone/Roundup/Touchdown,
etc.
Soluble
20 Water
(Hydrophilic)
Preference
Activate Plus
Silkin
Surfactants
Contact Angle
This is a profile measurement of a drop
of water in contact with a solid surface.
When a surfactant is added to water the
surface tension of the solution is reduced
and the spreads out over a greater area.
This flatter droplet has a lower contact
angle reading. A water droplet has a
contact angle of 93 degrees. A superior
wetter will have a contact angle of 45
degrees or less.
CONTACT ANGLE
Water
Water + Preference (NIS)
Water + Activate Plus (NIS)
Water + Silkin (silicone NIS)
Water + Prime Oil (COC)
Water + Destiny (MSO)
940
380
350
240
580
590
Draves Wetting
This is a test to measure the time in
seconds it takes to completely wet a
woven cotton skein. A superior wetter
will require less than 20 seconds for
wetting to occur. The lower the score in
this test the better wetting characteristics
the product has.
Water
Water + Preference (NIS)
Water + Activate Plus (NIS)
Water + Silkin (silicone NIS)
Water + Prime Oil (COC)
Water + Destiny (MSO)
Seconds
>300
16
11
2
>300
>180
Surface Tension
Surface tension is a condition that exists
at the free surface of a liquid. The
surface tension test measures the force
required to pull a floating ring off of the
surface of a liquid. This force is
measured in dynes/cm. Water has a
value of 74 while typical spreaders will
have a value of 30-50. Super wetters will
be 10-30.
SURFACE
TENSION
Surface tension is a condition that exists at the free surface of a solution.
The dynes per centimeter (dynes/cm) measurement in the test determines
the amount of force required to pull a floating ring off the surface of the
solution. The higher the dynes/cm, the more force is applied.
Since surfactants affect tension, the lower the
dynes/cm the better the coverage. Conversely,
the higher the dynes/cm of the solution, the
greater the impact on coverage.
The surface tension of water is approximately
74 dynes/cm. Typical wetting agents will reduce
surface tension to 30-50 dynes/cm, while
super wetters reduce this figure to 10-30
dynes/cm.
Water
Water + Preference (NIS)
Water + Activate Plus (NIS)
Water + Silkin (silicone NIS)
Water + Prime Oil (COC)
Water + Destiny (MSO)
73
35
32
27
36
52
Glycerol acid
Hydroxy carboxylic acid
Phosphate esters
Phosphoric Acid
Plycarboxylic acid
Polyacrylic acid
Propionic acid
Sulphates
Urea
UAN
2,4-D Amine
MCPA Amine
Concerns with
AMS/Polyglycolether Products
Ammoniated Salt Adjuvants
Advertised as AMS substitutes
Do not meet label recommendations for NIS or AMS
Generally NOT approved
SPRAY GRADE
AMMONIUM
SULFATE.
AMMONIUM
SULFATE
SOLUTION
PREMIXES
HARD WATER
WATER pH 8.2
DEIONIZED
WATER
WATER 800
PPM CA
RRPW
COLQ
VELE
800 PPM CA +
AMS
Roundup/Adjuvant/AMS Trial
% Barnyardgrass Control (17 DAT)
100
90
80
70
W/AMS
WO/AMS
60
50
40
30
Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. No
1
2
3
4
5
6
7
8
9
10
11 Adj.
Adjuvant
Roundup Original Rate = 16 oz/a; LSD (.10) = 2; Adjuvants rates varied by product
Roundup/Adjuvant/AMS Trial
% Waterhemp Control (17 DAT)
100
90
80
70
W AMS
W/O AMS
60
50
40
30
Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. No
1
2
3
4
5
6
7
8
9
10
11 Adj.
Adjuvant
Roundup Original Rate = 16 oz/a; LSD (.10) = 13.8; Adjuvants rates varied by product
Roundup/Adjuvant/AMS Trial
% Velvetleaf Control (17 DAT)
100
90
80
W AMS
W/O AMS
70
60
50
Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. No
1
2
3
4
5
6
7
8
9
10
11 Adj.
Adjuvant
Roundup Original Rate = 16 oz/a; LSD (.10) = 11; Adjuvants rates varied by product
Roundup/Adjuvant/AMS Trial
% Foxtail Control (17 DAT)
100
90
80
70
W/AMS
WO/AMS
60
50
40
30
Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. Adj. No
1
2
3
4
5
6
7
8
9
10
11 Adj.
Adjuvant
Roundup Original Rate = 16 oz/a; LSD (.10) = 2; Adjuvants rates varied by product
Accent
Beacon
85-92%
Emulsifier/Surfactants 8-15%
Prime
Oil+UAN
Destiny+UAN
Only UAN
No Additives
LSD (.10) = 5
Yes !
Rate
% Visual Damage
% Damaged Stalks
----
73
67
4 oz/a
37
33
Pounce +
Preference
4 oz/a
2 pt/100 g
30
23
Pounce +
Placement
4 oz/a
4 oz/a
27
23
Pounce +
Placement +
Preference
4 oz/a
4 oz/a
2 pt/100 g
23
17
Pounce +
Rivet
4 oz/a
2 qt/100 g
30
23
7.6
9.5
None
Pounce
LSD P=(0.05)
PLACEMENT!
NO PLACEMENT!
Droplets/cm2
Untreated
12.8
20.8
Droplets/cm2
Upper Untreated
16.6
22.5
Middle Untreated
12.0
22.3
Lower - Untreated
9.7
17.6
% Improvement
63%
% Improvement
36%
86%
81%
Plants
Herbicide
Environment
Adverse
Spray
Conditions
Good
High
Weed
Control
and/or
Crop
Injury
Low
Thank You!
Steve Barnhart