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Module 5:

Food Matters
Chapter 7 Food Chemistry

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Chapter 7 Food Chemistry


7.1 How are substances extracted and separated
from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be
identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?
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Objectives
Explain that substances can be extracted

and separated through the following


techniques:
(i) dissolving (ii) filtration (iii) evaporation (iv)
distillation and (v) paper chromatography
Describe the applications of the various
separation techniques in homes and food
industries
Use a measuring cylinder to measure
volume of liquids / solids
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Separating Mixtures

A mixture is one that contains two


or more different substances that
are not chemically combined
together.

The food we eat usually consists of


mixtures of solids and liquids.

For example, orange juice is made


up of orange pulps, sugars, water
and many other substances
including Vitamin C.

The components in it can be


separated using separation
techniques.

curry gravy is a rich


mixture of spices

a home purification system


for clean drinking water

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Separating Mixtures
Some separation

techniques are:

(a) Dissolving
(b) Filtration
(c) Evaporation
(d) Distillation
(e) Paper
chromatography

sugar cane juice is extracted


from sugar cane stems

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Dissolving

A mixture of two solids can be separated by using a


solvent which dissolves only one of them.

For example, a mixture of salt and sand can be separated


by adding water to the mixture. Salt will dissolve in water
but sand will not.

We can obtain sand by filtration of the mixture and salt


from evaporation of the filtrate.

separating a mixture of salt and sand

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Dissolving of solutes
Dissolving of solutes is commonly used

at home.

Some examples include:

(a) Cooking of soup


(b) Drinks sweetener
(c) Cleaning of the household

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Cooking of soup
Soup stock (flavourings) either in solid or

liquid forms, is dissolved in water to flavour


the soup.

soup stock is added to water to make soup

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Drinks sweetener
Sugar is dissolved in drinks (e.g. coffee

and tea) to make the taste better.

sugar is added to water when making tea

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Cleaning of the household


Detergent is dissolved in water to remove dirt

from clothes, and clean oily dishes and the floor.

detergent is dissolved in water

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Dissolving in the food industries


(a) Water is added in the

production of soft drinks,


to dissolve the mixture of
sweeteners, colourings
and flavourings.

Carbon dioxide gas is also

dissolved in the drink to


create the fizzy effect
which improves the taste
of the drink.

soft drinks contain a


mixture of sweetened
flavourings and colourings

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Dissolving in the food industries


(b) In the production of
perfumes, flower
extracts such as
lavender and rose are
dissolved in alcohol to
manufacture perfumes.
(c) Chlorine is dissolved
in our drinking water
and swimming pools to
kill harmful bacteria.

perfumes are mixtures of


natural plant extracts

bacteria in swimming pools are destroyed when


chlorine is added
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Filtration

Filtration is used to separate a


mixture of an insoluble solid from a
liquid.

In the diagram on the right, the


mixture is poured into a filter funnel
with a filter paper.

The filter paper allows the liquid to


pass through it but not the insoluble
solid particles of the mixture.

filtration experimental set-up

In this case, sand left on the filter


paper is called the residue and the
water that passes through it and
collected in the beaker is called the
filtrate.
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Filtration
At home, filtration is

used in air-conditioners
to filter air that may
contain dust and smoke
particles.

When cooking pasta, the

fastest and easiest way


to separate the pasta
from the boiling water is
to pour the contents of
the pot into a strainer.
This separates the pasta
from the water.

a strainer is
used to separate the
pasta from water

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Filtration
A cup of tea can be made by using a strainer to

prevent tea leaves from entering the cup.

filtering tea from insoluble


tea leaves

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A simple filtration system

Activity Book Link


Activity 7.2
Water Purification
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Simple filtration system


A simple filtration system can be set up to

purify water.

Impurities are removed by passing the water

through a bed of sand, gravel and pebbles.

The filtered water can then undergo further

stages (e.g. chlorine and UV treatment) to


improve the water quality to be fit for
drinking.

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Evaporation
Evaporation is used to

separate a dissolved solid


from a liquid. The dissolved
solid must not decompose
when heated.

For example, salt can be

obtained from salt solution


by evaporation.

Solid salt will be left behind

water in a salt solution


evaporates, leaving
the salt crystals behind

in the evaporating dish.

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Decomposition of sugar

sugar blackens upon heating

Sugar cannot be separated from sugar

solution by evaporation because it


decomposes and turns black upon heating.

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Obtaining salt by evaporation


Activity Book Link
Activity 7.3
Making Table Salt

piles of salt in salt pans

Evaporation is used in salt mines. When

temperatures are high, the salt water in the


salt pans are evaporated leaving the salt
behind. The salt is then piled up to dry.
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Condensation
When the water boils in the kettle, it changes into

steam. When the steam touches a cold surface, e.g.


metal pot or spoon, it cools down and changes into
water.

The change from a gas to a liquid is called

condensation.

steam from boiling water condenses on


the lid of the container
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Distillation

Distillation is used to separate a liquid from a solution. It


can also be used to separate a liquid from a mixture of
liquids having different boiling points.

distillation experimental setup

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Distillation
Pure water can be obtained from

seawater using distillation.

Distillation can also be used to separate

a mixture of ethanol and water.

Ethanol will be distilled first from the

mixture because of its lower boiling


point 78C) as compared to water
(100C).

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Process of distillation

Activity Book Link


Activity 7.4
Simple Distillation

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Chromatography

Chromatography is a method of using a solvent to


separate a mixture into its components.

Food colourings are often used to improve the


appearance of our food and drinks. Food colourings are
usually a mixture of coloured dyes.

Chromatography can be used to test if the dyes in food


colourings are safe for consumption. Chromatography
can also be used to detect banned drugs in urine
samples

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Paper chromatography
(a) A small drop of ink is placed on one end of the
chromatography paper.
(b) When this end of the chromatography paper is
soaked in a solvent, the solvent travels up the paper,
carrying with it the dyes in the ink.
Activity Book Link
Activity 7.5
Investigating the
Components of Food
Dyes

separating ink using chromatography

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Paper chromatography
(c) There are two coloured
spots formed on the
chromatogram. This shows
that
the ink sample is a mixture and it
contains two different coloured
dyes.
(d) The dyes that are more
soluble will move faster and
further up the
chromatogram
whereas the dyes that are less
soluble
will move slower and
form spots at lower positions.

different coloured dyes


appear on the
chromatogram after
the ink has dissolved in the
solvent

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Chapter 7 Food Chemistry


7.1 How are substances extracted and separated
from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be
identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?
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Objectives
Describe a chemical reaction as a
process that leads to the formation of
new products
Give examples of everyday changes that
involve chemical reactions : (i) decaying
of food (ii) burning (iii) rusting (iv) cooking
of food
Give examples of everyday situations in
slowing down / preventing chemical
reactions (e.g. Preserving food, reducing
amount of heat, fuel and air supply for
burning, tin plating against rusting)

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What is a chemical reaction?


Chemical reactions

even inside us.

happen around us and

Digestion of food is an example of a

chemical reaction and is an important


process before we can derive energy from
food.

All chemical reactions lead to new products

being formed.

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Chemical reactions in everyday life

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Ways to slow down chemical reactions

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Ways to slow down chemical reactions

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Ways to slow down chemical reactions

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Ways to slow down chemical reactions

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Chapter 7 Food Chemistry


7.1 How are substances extracted and separated
from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be
identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?
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Objectives
Describe the properties of acids by their
taste and effects on litmus paper and
universal indicator
Describe acidity, neutrality and alkalinity
in terms of the pH scale (whole numbers
only)
Measure the pH of various common
household substances and food using
homemade pH indicator, litmus paper,
universal indicator and a pH meter

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Properties of Acids

Acids are present in


everyday items. Acids can
be identified by the
following properties:
(a) Sour taste
Lemons, oranges and
grapefruits contain
an acid called citric acid
which gives them their sour
taste. Vinegar tastes sour
because it contains ethanoic
acid.
foods containing acids

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Properties of Acids
(b) Turns blue litmus paper red
When both red and blue litmus papers are placed in an
acidic solution (e.g. lemon juice), the blue litmus paper
turns red, while the red litmus paper remains red.

blue litmus turns red in acid while red


litmus paper remains unchanged
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Properties of Acids
(c)

Acids also produce colour change in universal


indicator. The table below shows the colour change of
the universal indicator when tested with some sample
substances which are acidic.

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Colour changes of the universal indicator in


different acid conditions

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The pH Scale
pH is a measure of the strength of an acidic

or alkaline solution.

The pH scale is a range of numbers from 0

to 14 that shows how acidic, alkaline or


neutral a substance is.

Neutral solutions have a pH of 7.


Acidic solutions have pH values of less than

7.

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The pH Scale
A solution with a lower pH is more acidic than

one with a higher pH.

Alkalis have pH values of more than 7.


A solution with a higher pH is more alkaline

than one with a lower pH.

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The pH scale

Activity Book Link


Activity 7.6
Testing for Acids
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Indicators
Indicators can be used to test for the

presence of acids and alkalis.

An indicator will change colour depending

on whether the solution tested is acidic or


alkaline.

There are many types of indicators

commonly used in the laboratory to


indicate the pH of solutions.

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Litmus indicator

The commonly used litmus


indicators are the red and blue
litmus.

Litmus is a dye obtained from


plants and can be used as a
solution or in paper form.

Blue litmus turn red in acidic


solutions, and red litmus turn blue
in alkaline solutions.

litmus solution and


litmus paper

In neutral solutions, both the red


and blue litmus will not change
colour.
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Natural indicators
Some flowers, vegetables and berries can

be used as natural indicators.

For example, the coloured juice extracted

from the red cabbage turns pink when


tested with acidic substances and green
when tested with alkaline substances.

Other examples include extracts from

grape peels and orchid flowers.

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Natural indicators

red cabbage juice is a natural indicator as it


changes colour in different pH

orchid flowers are natural indicators

berries, grapes and are natural indicators


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Universal indicator
The universal indicator is a mixture of several

different types of indicators. It can show a


variety of colours depending on how acidic or
alkaline a substance is.

Each colour corresponds to a pH value. The

universal indicator is used in the form of a


solution or a paper.

The pH of the acid of or alkali can be

determined by comparing the colour of the


universal indicator against the colour chart.

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Universal indicator solution


and universal indicator paper

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pH meter
A pH meter is an instrument used to measure

the pH of a substance accurately.

A pH meter consists of a pH probe which is

connected to a datalogger.

A pH probe is placed in a solution to determine

its pH value and the pH value of the solution is


recorded on the datalogger.

Among the four indicators, the pH meter gives

the most accurate pH reading of a solution.

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pH meter can measure an


accurate pH reading of a solution

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Chapter 7 Food Chemistry


7.1 How are substances extracted and separated
from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be
identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?
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Objectives
Describe the characteristic properties of

food acids on the following items that


are commonly found at home
(i) metals ( e.g. cooking utensils )
(ii) bases ( e.g. antacids )
(iii) carbonates ( e.g. baking soda,
effervescent Vitamin C tablets)

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Reaction of Food Acids with Metal


Utensils
Some common examples of acids found in

food are lemon and orange juice (citric acid), tea


(tannic acid) and soft drinks (carbonic acid).

soft drinks contain carbonic acid

lemons contain citric acid

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Acid reaction with metals


Acids react with some metals to produce a salt and

hydrogen gas.

For example, when some magnesium strips are

added to a test tube of lemon juice, bubbles can be


observed to form on the magnesium strips.

The bubbles on the magnesium strips are hydrogen

gas.

The presence of hydrogen gas can be tested using a

lighted splint. Hydrogen gas will extinguish a


lighted splint with a pop sound.

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Testing for hydrogen gas

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Acid reaction with metals

The general word equation to represent the reaction of a


metal with acid is:
acid + metal salt + hydrogen gas

Most cooking utensils are made of metal.

Over time, these utensils may become rusty. The rust can
be removed by soaking the rusty utensils in vinegar or
rubbing them with lemon slices.

The acid in the vinegar or lemon will react with the rust to
form a soluble substance that can be easily washed off.

rusty utensil

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Reaction of Food Acids with Carbonates


Acids react with carbonates to give off carbon

dioxide gas.

Some examples of carbonates found in or daily

life are baking powder, egg shells, Vitamin C


tablets and sea shells.

For example, when some egg shells are added

to vinegar, bubbles of gas can be observed to


form on the egg shells.

The bubbles formed are carbon dioxide gas.

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Testing for carbon dioxide


The presence of carbon dioxide gas can be tested

by bubbling it into limewater.

If carbon dioxide gas is present, the limewater will

turn chalky.

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Reaction of Food Acids with Carbonates

Vitamin C tablets consist of


an acid and a carbonate.
When the tablet is added to
water, the acid and carbonate
dissolve and react to produce
carbon dioxide gas which
results in the fizzy bubbling
effect

Baking powder contains


sodium bicarbonate (baking
soda) and an acid. During
baking, the baking soda and
the acid present in the baking
powder react to produce
carbon dioxide gas. This gas
helps to raise the cake and
makes it soft.

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Reaction of Food Acids with Carbonates


The general word equation to represent the

reaction of a carbonate with acid is:

acid + carbonate salt + carbon dioxide


+ water

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Reaction of Food Acids with Bases


Acids react with bases to produce a salt and water.
Bases dissolve in water to form alkalis. For example,

our stomach produces an acid which helps us in the


digestion of food.

At times if we eat too much and too fast, the acid

may flow backwards into our oesophagus.

We may feel a burning sensation. This is called acid

reflux or heartburn.

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Backflow of stomach acid into


oesophagus causes heart burn

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Antacids

If we do not have regular


meals, the acids produced in
our empty stomach may cause
us to suffer from gastric pains.

Over time, this may cause


damage to the inner walls of
the stomach.

Antacids, which contain a base,


can be used to neutralise the
excess acid. This process is
called neutralisation.

antacids neutralise
stomach acid

Activity Book Link


Activity 7.7
Properties of Acids

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Chapter 7 Food Chemistry


7.1 How are substances extracted and separated
from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be
identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?
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Objectives
State that neutralisation takes place

when an acid reacts with a base and the


products are salt and water only
State some applications of
neutralisation (e.g. action of tooth paste,
fabric softener and hair conditioner,
controlling of pH in soil, neutralising
industrial wastes)
Relate pH within the mouth to its effect
on dental health
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Neutralisation

Neutralisation occurs when an acid reacts with a base to


produce a salt and water only.

The general word equation to represent neutralisation is:


acid + base salt + water

For example, mixing sodium hydroxide and hydrochloric


acid produces two new substances, sodium chloride and
water.

The word equation is:

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Neutralisation
If sulfuric acid is used, the word equation becomes:

Sodium chloride and sodium sulfate are salts.


Neutralisation reactions are important because

there are many useful daily applications for them.

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Useful applications of neutralisation reactions in


everyday life

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Useful applications of neutralisation reactions in


everyday life

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Useful applications of neutralisation reactions in


everyday life

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Useful applications of neutralisation reactions in


everyday life

Activity Book Link


Activity 7.8
Neutralising Chemical
Waste

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Chapter 7 Food Chemistry


7.1 How are substances extracted and
separated from mixtures?
7.2 What is a chemical reaction and what are
its applications in daily life?
7.3 What are acids and how can they be
identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated
wastewater on the environment?
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Objectives
State some of the effects of phosphate

detergents (e.g. increase growth of algae


and water weeds) and acidic wastewater
on the rivers and seas
Understand the use of microbes in
sewage plants to treat the wastewater
before they are released to the rivers
and seas

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Effects of Untreated Sewage on the Environment

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Effects of Untreated Sewage on the Environment

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Effects of Untreated Sewage on the Environment

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Effects of Untreated Sewage on the Environment

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What are microbes and their uses?

Microbes such as bacteria are natures recyclers.

They can break down bodies of dead animals and plants


into simpler substances.

Bacteria are very useful in the treatment of waste water


because they produce enzymes to break down the waste
substances into smaller and simpler substances.

The bacteria population is also well regulated as they


grow quickly when there is a lot of food for them.

When the food supplies decrease, the bacteria


population will decrease rapidly.

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Microbes and their uses

magnified view of the


bacteria
scientists analysing bacterial colonies
multiplying on waste materials as their
source of food

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Sewage treatment

In sewage treatment plants, microbes such as aerobic bacteria are used


to decompose the waste sewage material.

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