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STATES OF MATTER
5.1 Gas
5.2 Liquid
5.3 Solid
At the end of the lesson, student should be able to :
Partial pressure
Dalton's law
(j) perform calculation using Dalton's law
(k) compare the ideal and non-ideal behaviours of gases in terms of
intermolecular forces and molecular volume
(l) explain the conditions at which real gases approach
the ideal behaviour.
(m) explain qualitatively van der Waals equation and relate the
values of a and b to intermolecular forces and molecular volume
of a gas
General
Properties
of Gas
Particles of gas are far apart and fill the available space.
PV = k Where:
k = constant
V = volume
P = pressure
T = temperature
n = number of moles
at different pressure and volume :
P1 V1 = P2 V2
Where
P1 = initial pressure
V1 = initial volume
P2 = final pressure
V2 = final volume
G ra p h o f P v e rs u s V G ra p h o f P v e rs u s 1
V
P
P
1
V V
pressure is inversely pressure is directly
proportional to volume proportional to 1
volume
Graph of PV versus P
PV
PV = constant
P
Example 1
0.4 atm
Example 2
46.36 mL
a) Charless Law :
The volume of a fixed amount of gas at
constant pressure is directly proportional to the
absolute temperature of the gas (in Kelvin).
T = absolute temperature
in Kelvin (K)
V1 V2
T1 T2 T(K) = TC + 273.15
V V
0 T(K) -273.15
T(0C)
Example 1
-81.54 C
Example 2
5.08 mL
The Combination of Boyles and Charless Law
1
Boyles law : V
P
Charless law : VT
T
V
P
T
V =k
P
PV
=k
T
P1V1 =
P2 V2
T1 T2
Example 1
Ans : 35.32 L
Example 2
2 moles of chlorine gas kept in a cylinder
with piston occupies a volume of 49 L.
When another 3 moles of chlorine gas is
pumped into the cylinder at constant
temperature and pressure the piston
moves upwards to accommodate the gas.
Calculate the final volume of the gas.
Ans : 73.5 L
C) Avogadros Law
At constant pressure and temperature,
temperature the volume of a
gas is directly proportional to the number of moles of the
gas present
V n (P and T are constant)
V = k n
V
=k
n where :
n = number of moles
V1 V2 k= constant
n1 n2
Combination of Boyle's law, Charles's law and Avogadro's law :
1
B o y l e 's L a w : V
P
C h a rle s ' L a w : V T
A v o g a d r o 's L a w : V n
nT
V Where :
P
R = gas constant
V = R
nT
T = Temperature(K)
P
n = number of moles
PV = nRT V = volume
Ideal gas equation P = Pressure
Value of R depend on the unit of pressure and
volume used in the equation.
unit of unit of value of unit of R
pressure volume R
atm L or dm3 0.08206 L atm mol1 K1
m m
PV = R T w h e re : n =
M r M r
W h a t m a s s o f K C lO 3 is r e q u ir e d to p r o d u c e
2 .4 0 L O 2 g a s th a t m e a s u r e d a t a p r e s s u r e o f
1 a tm a n d a te m p e ra tu re o f 2 6 o C . T h e
r e a c tio n e q u a tio n is
2 K C l O 3 ( s ) 2 K C l ( s ) + 3 O 2 ( g )
Daltons Law of Partial Pressure
The total pressure of mixture of non reacting gases is the
sum of the partial pressures exerted by each of the gas in the
mixture
PT = P A + P B + P C
A c c o r d in g to id e a l g a s e q u a tio n :
nART
p re s s u re e x e rte d b y g a s A = P A =
V
nBR T
p re s s u re e x e rte d b y g a s B = P B =
V
in th e m ix tu r e o f g a s e s A a n d B :
P T = P A + P B
nART nBR T
=
V V
= (n A + n B )R T n TR T
V P T =
V
w hen nA + nB = nT
M o le fr a c tio n a n d p r e s s u r e s
D a lt o n s t h e o r y a llo w s u s t o f o r m a r e la t io n s h ip
b e t w e e n M o le f r a c t io n s , p a r t ia l p r e s s u r e a n d a to t a l
p re s s u re .
C o n s id e r th e fo llo w in g c o n d itio n a t c o n s ta n t T
and V
If P n RT A A
P to ta l n to ta l( R T )
Thus: PA n A (R T ) PA n
A
P to ta l n to ta l ( R T ) P T o ta l n T o ta l
P A X A P to ta l X A = m o le fr a c tio n o f g a s A
Example
1
A gaseous mixture of 7.00 g N2 and 3.21 g CH4 is placed in a
12.0 L cylinder at 25 oC.
The gas collected is actually a mixture of the gas and water vapour.
PT Pgas PH 2O
Vapour pressure of water, Pwater = 23.8 torr
Example 1
T h e g a s m o le c u le s h a v e h ig h k in e tic
e n e r g ie s a n d m o v e a t h ig h s p e e d
T h e m o le c u le s a r e a b le to fr e e th e m s e lv e s
fr o m th e in te r m o le c u la r fo r c e s th a t a c t
b e tw e e n th e m .
T h e in te r m o le c u la r fo r c e s c a n b e
n e g le c te d , th u s th e y b e h a v e a lm o s t
id e a lly .
G r a p h P V /R T a g a in s t P fo r N 2
a t d iffe r e n t te m p e r a tu r e s
PV
RT 273K
T h e lin e s
a p p ro a c h th e
600K id e a l lin e w h e n
1000K T in c r e a s e s
T h e v a lu e a p p r o a c h e s 1 .0
a t a v e r y lo w p r e s s u r e
9
Van der Waals Equation
Since real gas does not exhibit ideal gas behavior
at high pressure and low temperature :
the ideal gas equation (PV=nRT) needs to be
adjusted
adjusting the equation, two parameters need to
be reconsidered :
attractive forces between the gas molecules
volume of the gas molecules
a) Attractive Forces Between Molecules
n = n u m b e r o f m o le s
P = P + n 2a a = c o rre c tin g fa c to r fo r
id e a l re a l p re s s u re
V2 V = v o lu m e o f c o n ta in e r
(b ) V o lu m e o f th e g a s m o le c u le s
S in c e th e g a s o c c u p y a s iz e a b le p o r tio n
o f a c o n ta in e r , th e s p a c e in w h ic h th e
m o le c u le s a r e a b le to m o v e a r e le s s
th a n th e v o lu m e o f th e c o n ta in e r .
V r e a l < V c o n ta in e r
T h e c o r r e c tio n fa c to r d o n e to th e
v o lu m e is :
nb v
V = v o lu m e
V = V c o n ta in e r - nb n = n u m b e r o f m o le s
b = s iz e fa c to r
R e f e r r in g t o t h e id e a l g a s e q u a t io n :
PV = nRT
B y r e p la c in g th e s e in to th e e q u a tio n
P id e a l = P re a l + n 2a & V = V c o n ta in e r - nb
V2
(P re a l + n 2a ) ( V n b ) = n R T
V2
T h e v a n d e r W a a ls e q u a tio n
V a lu e o f a :
a is a p o s itiv e c o n s ta n t w h ic h d e p e n d s o n th e
s tre n g th o f th e a ttra c tiv e fo rc e s b e tw e e n m o le c u le s
M o le c u le s w ith a h ig h e r v a lu e o f a h a v e s tro n g e r
a ttra c tiv e fo rc e s .
V a lu e o f b :
b is a c o n s ta n t to re p re s e n t th e v o lu m e o c c u p ie d
b y th e m o le c u le s .
L a rg e r m o le c u le s h a v e b ig g e r v a lu e o f b
5.2 Liquids
At the end of this topic, students should
be able to :
m o le c u le a t
th e s u rfa c e
m o le c u le w ith in
th e liq u id
these intermolecular attractive forces will
pull the molecules into the liquid
Thus, cause the surface to stretch and
tighten
the stronger the intermolecular attractive
forces, the higher the surface tension
3. Viscosity
is a measure of the resistance of a liquid
to flow
m o le c u l e s e s c a p e f r o m t h e s u r f a c e o f a l iq u id
: r e f e r r e d a s v a p o u r m o le c u le s
P r e s s u r e e x e r t e d b y t h e v a p o u r m o le c u le s
o n t h e s u r f a c e o f a l iq u id is k n o w n a s t h e
vapour pressure
I f e v a p o r a t io n o c c u r s in a n o p e n c o n t a in e r ,
v a p o u r m o le c u le s w ill d if f u s e d a w a y u n t il
t h e liq u id d r ie s u p
in a c lo s e d s y s t e m :
v a p o u r m o le c u le s w h ic h le a v e s t h e s u r f a c e a r e
t r a p p e d in t h e c lo s e c o n t a in e r
t h e s e v a p o u r m o le c u le s a r e in c o n s t a n t r a n d o m
m o t io n
t h e m o le c u le s s t r ik e t h e w a ll o f c o n t a in e r a n d
ex ert som e pressure
A s t h e q u a n t it y o f m o le c u le s in t h e v a p o u r p h a s e
in c r e a s e , s o m e m o le c u le s m a y lo s e e n e r g y a n d
condense
E v e n t u a lly ,
t h e r a t e o f e v a p o r a t io n = t h e r a t e o f c o n d e n s a t io n .
( T h e s y s t e m a c h ie v e d d y n a m ic e q u ilib r iu m )
A t e q u ilib r iu m , t h e n u m b e r o f v a p o u r m o le c u le s
a b o v e liq u id a r e c o n s t a n t .
F actor that affects the vapour pressure
T em perature
A p p ly in g t h e h e a t c a u s e s m o r e m o le c u le s h a v e h ig h
k in e t ic e n e r g y
M o r e m o le c u le s w ill b e a b le t o o v e r c o m e t h e
in t e r m o le c u la r f o r c e s a n d e s c a p e f r o m t h e liq u id t o
form vapour
T em perature , vapour pressure
I n t e r m o le c u la r f o r c e s
M o le c u le s w it h w e a k in t e r m o le c u la r f o r c e s c a n e a s ily
v a p o u r is e d
M o r e v a p o u r m o le c u le s w ill e x e r t p r e s s u r e o n t h e liq u id
surface
I n t e r m o le c u la r f o r c e s , v a p o u r p r e s s u r e
B o ilin g
A p r o c e s s in w h ic h liq u id m o le c u le s
c h a n g e to v a p o u r a t a p a r tic u la r
te m p e r a tu r e a n d a t a n a tm o s p h e r ic
p re s s u re .
H a p p e n s th r o u g h o u t th e liq u id .
E v a p o r a tio n
liq u id m o le c u le s c h a n g e to v a p o u r a t
a n y te m p e ra tu re a n d p re s s u re .
O c c u r s o n ly a t th e s u r fa c e o f a liq u id
B o ilin g P o in t: th e te m p e ra tu re a t
w h ic h t h e v a p o u r p r e s s u r e o f a l i q u id i s
e q u a l to th e e x t e r n a l a t m o s p h e r ic
p re s s u re .
N o rm a l B o ilin g P o in t: th e te m p e ra tu r e
a t w h ic h a liq u id b o ils w h e n t h e e x t e r n a l
p re s s u re is 1 a tm ( t h a t is t h e v a p o u r
p re s s u re is 7 6 0 m m H g )
B o ilin g P o in t - p r o c e s s
I n c r e a s in g t h e t e m p e r a t u r e w ill in c r e a s e in t h e v a p o u r
pressure.
A s h e a t is a p p lie d , t h e v a p o u r p r e s s u r e o f a s y s t e m w ill
in c r e a s e u n t il it r e a c h e s a p o in t w h e r e b y t h e v a p o u r
p r e s s u r e o f t h e liq u id s y s t e m is e q u a l t o t h e
a t m o s p h e r ic p r e s s u r e .
B o ilin g o c c u r s a n d t h e t e m p e r a t u r e t a k e n a t t h is p o in t
is k n o w n a s t h e b o ilin g p o in t .
A t t h is p o in t , t h e c h a n g e o f s t a t e f r o m liq u id t o g a s
o c c u r s n o t o n ly a t t h e s u r f a c e o f t h e liq u id b u t a ls o in
t h e in n e r p a r t o f t h e liq u id .
B u b b le s f o r m w it h in t h e liq u id .
F a c to r s a ffe c tin g th e b o ilin g p o in t:
1 . A tm o s p h e r ic p r e s s u r e
W h e n t h e e x t e r n a l a t m o s p h e r ic p r e s s u r e is
lo w , liq u id w ill b o il a t a lo w e r t e m p e r a t u r e
2 . In t e r m o le c u la r f o r c e s
A s u b s t a n c e w it h w e a k in t e r m o le c u l a r f o r c e s
c a n e a s i l y v a p o u r is e a n d t h e s y s t e m r e q u ir e s
le s s h e a t t o a c h ie v e a t m o s p h e r ic p r e s s u r e ,
t h u s it b o ils a t a lo w e r t e m p e r a t u r e .
5.3 Solid
O BJECTIVE
( a ) S t a t e t h e p r o p e r t ie s o f s o lid .
( b ) E x p la in t h e p r o c e s s o f :
- f r e e z in g - s u b lim a t io n
- m e lt in g - d e p o s it io n
( c ) D if f e r e n t ia t e b e t w e e n a m o r p h o u s a n d c r y s t a llin e
s o lid s .
( d ) D e s c r ib e t h e t y p e s o f b o n d in g a n d t h e
in t e r p a r t ic le / in t e r m o le c u la r f o r c e s in v o lv e d in t h e
f o llo w in g c r y s t a llin e s o lid s u s in g a p p r o p r ia t e e x a m p le s .
i. m e t a llic iii. m o le c u la r c o v a le n t
ii. io n ic iv . g ia n t c o v a le n t
Properties of solid
liq u id
s u b lim a tio n
d e p o s itio n
s o lid gas 5
M e l t in g ( F u s io n ) P r o c e s s
S o lid is c h a n g in g in t o a liq u id
W h e n a s o lid s u b s t a n c e is h e a t e d :
- it s p a r t ic le s g a in e n e r g y
- t h e r e f o r e a b le t o v ib r a t e m o r e r a p id ly
- a t c e r t a in t e m p e r a t u r e , t h e k in e t ic e n e r g y is h ig h e r
e n o u g h t o o v e r c o m e t h e in t e r m o le c u la r f o r c e s o f
a t t r a c t io n b e t w e e n s o lid p a r t ic le s .
t h e p a r t ic le s a r e f r e e t o m o v e a n d t h e s o lid s t a r t t o
m e lt
M e lt in g p o in t t h e t e m p e r a t u r e a t w h ic h s o lid a n d
liq u id c o e x is t in e q u ilib r iu m
F r e e z in g ( S o l id ifi c a t io n ) P r o c e s s
L iq u id is c h a n g in g in t o a s o lid
w h e n t h e t e m p e r a t u r e o f a liq u id is lo w e r e d , t h e
k in e t ic e n e r g y o f t h e liq u id p a r t ic le s d e c r e a s e s
t h e liq u id p a r t ic le s v ib r a t e a t a s lo w e r ra t e
w h e n t h e in t e r m o le c u la r f o r c e s a r e s t r o n g
e n o u g h t o h o ld t h e p a r t ic le s t o g e t h e r in a fi x e d
a n d o r d e r ly a rr a n g e m e n t , t h e liq u id f r e e z e s .
F r e e z in g p o in t a t e m p e r a t u r e a t w h ic h t h e liq u id a n d
s o lid p h a s e s o f a s u b s t a n c e s c o e x is t a t e q u ilib r iu m .
S u b l im a t io n P r o c e s s
Th e p r o c e s s b y w h ic h a s u b s t a n c e c h a n g e s
d ir e c t ly f r o m s o lid t o t h e g a s e o u s s t a t e w it h o u t
p a s s in g t h r o u g h t h e liq u id s t a t e .
O c c u r s o n s o lid w it h w e a k in t e r m o le c u la r f o r c e s
o f a t t r a c t io n
D e p o s it io n P r o c e s s
Th e p r o c e s s w h e r e m o le c u le s f r o m v a p o u r s t a t e
c h a n g e t o t h e s o lid s t a t e .
Th e o p p o s it e p r o c e s s o f s u b lim a t io n
T y p e s o f S o l id
c r y s t a l l in e s o l id a m o r p h o u s s o l id
A s o lid t h a t h a s h ig h ly o rd e r e d S o lid t h a t d o e s n o t h a v e a
s t r u c t u r e w h e re a t o m s , io n s o r re g u la r t h r e e d im e n s io n a l
m o le c u le s s h o w a r e g u la r a rr a n g e m e n t o f a t o m s o r
re p e t it io n in t h re e d im e n s io n a l m o le c u le s
a rra n g e m e n t F o rm e d w h e n a sa t u ra t e d
F o rm e d w h e n a s a t u ra t e d liq u id is c o o le d r a p id ly
liq u id is c o o le d s lo w ly E x a m p le :
It s a t o m s , m o le c u le s o r io n s g la s s
o c c u p y s p e c ifi c p o s it io n p la s t ic m a t e r ia l
E x a m p le : ic e , s u g a r, s a lt
c h a rc o a l
T y p e s o f C r y s t a l l in e S o l id
1 . M e t a llic s o lid
C lo s e p a c k e d s t ru c t u re
C o m p o se d o f a to m s o f th e sa m e m e t a l lin k e d
t o g e t h e r b y m e t a llic b o n d
T h e p ro p e rt ie s o f m e t a l:
H ig h e le c t ric a l a n d t h e rm a l c o n d u c t iv it y
L u s t re
D u c t ile a n d m a lle a b le
E x a m p le s : a ll m e t a llic e le m e n t s : N a , M g , F e
2. I o n ic s o lid s
c o n s is t o f io n s ( c a t io n & a n io n ) h e ld t o g e t h e r b y io n ic
bonds
P h y s ic a l p r o p e r t ie s o f io n ic s o lid :
- H ig h m e lt in g p o in t
- H a r d b u t b r it t le
- D o e s n o t c o n d u c t e le c t r ic it y in t h e s o lid s t a t e b u t
d o e s c o n d u c t e le c t r ic it y in m o lt e n s t a t e o r in
aqueous state.
E x a m p le : N a C l, C s C l
3 . M o le c u la r c o v a le n t s o lid
c o m p o s e d o f m o le c u le s h e ld t o g e t h e r b y
in t e r m o le c u la r fo rc e s (v a n der W a a ls
a n d / o r h y d ro g e n b o n d s)
E x a m p le : io d in e [ I 2 (s) ]
4. G ia n t c o v a le n t s o lid s
v e r y la r g e m o le c u le s / g ig a n t ic s t r u c t u r e
c o m p o se d o f a t o m s lin k e d to g e th e r b y
c o v a le n t b o n d
e x a m p le s : d ia m o n d , g r a p h it e , S iO 2
5.4 Phase
Diagram
Learning Outcomes :
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Regions of the diagram
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Important Points
1. Point T :
- Known as the triple point
- Triple point is the point at which the vapour, liquid and
solid states of a substance are in equilibrium.
- Triple point for water is 0.01C and 0.06 atm.
2. Point C :
- Known as the critical point
- Critical point is the point on a phase diagram at which
the vapour cannot be condensed to a liquid.
- The liquid gas line ends at the critical point.
- Above the critical point, the liquid cannot be
distinguished from its vapour form.
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(ii) Phase Diagram of CO2
B C
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TRIPLE POINT
for most compounds, the TB curve slant to
the right because solid is denser than liquid
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ANOMALOUS BEHAVIOR OF H2O