Professional Documents
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COMMUNICATIO
N
29 CFR
1910.1200
OBJECTIVES
How The Worker Right To Know Law Affects
Schlumberger Workers
Location of the Written Hazard
Communication Program
How To Recognize and Evaluate Chemical
Hazards
What Are Labels and How Are They Used
How to Locate and Use Material Safety Data
Sheets
What Controls Should be Used When
Working With Chemical Hazards
TOXICOLOGY
LD5
0
OSHA
Exposure
Limit
DOSE - RESPONSE
RELATIONSHIPS
PELs/TLVs ARE BASED ON THE BEST AVAILABLE
DATA FROM:
Past Industrial Experience
Experimental Human Data
Experimental Animal Studies
Combination of All Three
PELs/TLVs
Refer to Airborne Concentrations of Substances and
Represent Conditions Under Which It Is Believed
That Nearly All Workers May Be Repeatedly Exposed
Day After Day Without Adverse Health Effects
Time-Weighted Average
Concentration given for a normal 8-
hour
workday or Exposure
Short-Term 40-hour work week
Limit
Maximal Concentration to which workers
may be exposed for a period up to 15 minutes
C
o
n STEL
c
e
n
t
r TWA
a
t
i
o
n
Time
Ceiling
Concentration that should not be
exceeded even instantaneously
C
o
n CEILING
c
e
n
t
r
a
t
i
o
n
Time
TOXICOLOGY
Toxicity X Exposure (Dose) = Chemical Hazard
FUEL
OXYGEN
HEAT PROPER
MIXING
PERCENTAGE IN AIR
100%
75%
50%
13%
2.5%
0%
In this example, 2.5% is the Lower Explosive Limit (LEL) and 13%
is the Upper Explosive Limit (UEL) for Acetone
CORROSIVES
ROUTES OF EXPOSURE
INHALATION, SKIN/EYE CONTACT, AND INGESTION
HOW DO THEY INJURE?
DIRECT DAMAGE DUE TO pH
ACIDS - pH < 4.0
e.g., Hydrochloric and Sulfuric Acid
CAUSTICS pH >10.5
e.g., Sodium Hydroxide
pH SCALE
ACID NEUTRAL BASE
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
IRRITANTS
and SENSITIZERS
IRRITANTS
Burns or Irritates Eyes, Nose, Skin,
Mouth, or Lungs etc.
Acid Mist, Ammonia
SENSITIZERS
Causes Allergic Type Response After First
Exposure to the Chemical
After Initial Exposure It Takes Only a
Fraction of the Exposure to Elicit an
Allergic Response, e.g., Isocyanates
TOXIC MATERIALS
ASPHYXIANTS
Simple Asphyxiant - Suffocates by Displacing
Oxygen, e.g., Nitrogen and Carbon Dioxide
Chemical Asphyxiants- Suffocates by Not Allowing the
Uptake of Oxygen in the Lungs, e.g., Carbon
Monoxide and Hydrogen Sulfide
NARCOTICS/ANESTHETICS
Depress Central Nervous System Functions
Symptoms Such As Lightheadedness, Fatigue up
to Unconsciousness and Death
Most Organic Solvents Are in This Category
TOXIC MATERIALS
TARGET ORGAN EFFECTS
Act by causing damage to specific organs or
organ systems
Liver - Hepatotoxins, e.g., Carbon Tetrachloride
Kidneys - Nephrotoxins, e.g., Chromium
Neurotoxins-Central Nervous System e.g.,
Mercury
Cardiac - Heart, e.g., Methylene Chloride
Respiratory - Lungs, e.g., Silica
Reproductive System, e.g., Lead
Blood Forming Tissues, e.g., Benzene
TOXIC MATERIALS
MUTAGENS
Causes Change in the Genetic Code
Such Changes May Be Inherited If Damage
Occurs to the Sperm or Egg
Lead and Benzene Are Examples
TERATOGENS
Means Monster Making
Causes Damage to Developing Fetus
Ethyl Alcohol (Drinking) and Radiation Are
Examples
CARCINOGEN
CARCINOGEN IS ANOTHER WORD FOR
CANCER
These Substances Cause or Promote
the Growth of Cells
Mechanisms Are Not Well Understood
Most Carcinogens Are Site or Tissue
Specific
Vinyl Chloride causes liver cancer
Asbestos causes lung cancer
Benzene causes bone marrow cancer
Ultraviolet light causes skin cancer
HAZARD
COMMUNICATION
29 CFR 1910.1200
Bhopal, India December 3rd,
1984
METHYL ISOCYANATE
Extremely Toxic
Very Volatile
Heavier than air
REQUIREMENTS FOR
SCHLUMBERGER
WRITTEN PROGRAM
CHEMICAL INVENTORY
LABELING
MATERIAL SAFETY DATA SHEETS (MSDSs)
TRAINING
WRITTEN PROGRAM
NATIONAL
FIRE
PROTECTION
ASSOCIATION
NATIONAL FIRE PROTECTION
ASSOCIATION
NUMBERS REPRESENT THE
DEGREE OF HAZARD
LABELING
HMIS
HMIS
WHMIS
WHMIS
LABELING
MATERIAL SAFETY
DATA SHEETS
RESPONSIBILITY OF THE CHEMICAL
MANUFACTURER AND IMPORTER TO
DEVELOP
EACH EMPLOYER WILL HAVE A MSDS FOR
EACH CHEMICAL
EACH EMPLOYER MUST MAKE THEM
ACCESSIBLE
THEY MUST BE IN ENGLISH
MUST LIST INGREDIENTS AT THE
FOLLOWING THRESHOLD QUANTITIES:
1% Or Greater for Hazardous
Ingredients
0.1% Or Greater for Carcinogens
NO BLANK CATEGORIES ON THE MSDSs
SECTION 1 CHEMICAL PRODUCTS AND COMPANY
IDENTIFICATION
Provides the chemical name on the label to the MSDS. Also listed is the name address
and the phone number of the company manufacturer or distributor who provides the
chemical.
Information on material spill response, containment and required spill response PPE.
Information about chemical storage & handling and measures to prevent overexposure.
PROTECTION
Engineering controls & personal protective equipment to reduce chemical exposure.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
This section tells about the physical and chemical properties of the chemical.
Characteristics include appearance, odor, physical state, pH, vapor pressure, vapor
density, boiling point, freezing/melting point, solubility in water and specific gravity or
density.
Information All potentially hazardous chemical reactions are identified in this section.
Includes information on chemical stability, conditions to avoid,
incompatibility,hazardous decomposition and hazardous polymerization.
SECTION 11 TOXICOLOGICAL INFORMATION
Provides information such as acute data, carcinogen potential, reproductive effects,
target organ effects, and other physiological aspects.