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OIL PROCESSING

Fahmi Reza Wijanarko (2313100123)


Putri Ragefa Arumingsari (2314100022)
Putu Adhi Rama Jaya (2314100058)
Feby Listyo R. (2314100089)
Rinaldi (2314100136)
Rizka Aulia Rahmawati (2314100701)
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OVERVIEW
SECTION

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BACKGROUND
... Needs of (general) plastic in Indonesia is very
massive. ...
... Everyone needs a media to wrap something, or to put
something, or to cover something, to make it last longer. ...

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POLYMER?
Commonly, plastic is made from polymer.
There are Polyethylene (PE), Polypropylene
(PP), Polyvinyl Chlorine (PVC), Oriented
Polystyrene (OPP), etc.

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POLYPROPYLENE
Known to be used as food wrap, furniture, sack,
automotive uses, electronic tools, etc.
The main raw materials: Propylene
Propylene is made from Naphta-Cracking.

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HISTORY
1973:
Pertamina, The first company who produced Polypropylene.
1992:
PT. Tri Polyta Indonesia, the biggest Polypropylene producer
with 480.000 ton/year
1995:
PT. Chandra Asri produced olefins (Ethylene, Propylene,
Polyethylene, and Styrene Monomer)
2011:
PT. Tri Polyta Indonesia and Chandra Asri merged into
PT.Chandra Asri Petrochemical Tbk. (Ethylene, Propylene,
Polyethylene, Polypropylene, Butadiene, Synthetic Rubber,
Styrene Monomer)
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PRODUCT OF PP
1. PP-Homopolymer
Only consist of propylene.
Rigid, and translucent

2. PP-Random Copolymer
Consist of propylene and ethylene which are arranged randomly
Elastic, and more pellucid than the homopolymer

3. PP-Impact Copolymer
Consist of propylene and ethylene-propylene-rubber.
The color is white and rigid

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Raw Materials
Propylene
Ethylene
Hydrogen
Nitrogen
CO
Catalyst : Xiang Yang, SHAC 201, LYNX 1010
Co-Catalyst : TEAl (Tri Ethyl Aluminium)
SCA
H2O
Additive

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PROCESS
SECTION

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PRODUCTION PROCESS

Gambar 1 Process Flow Diagram (Diagram)

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HYDRO SKIMMING
COMPLEX
1. Primary Unit
- Crude Distillation Unit (CDU)
- Naphta Re-Run Unit (NRU)
- Naphta Hydrotreating Unit (NHU)

2. Secondary Unit
- Platforming Unit (PL-I)
-Continous Catalyst Regeneration (CCR)
-Platforming Unit (PL II)

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CRUDE DISTILLATION UNIT

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Function of CDU
Berfungsi untuk memisahkan fraksi-fraksi yang
terkandung dalam minyak mentah dengan cara distilasi
atmosferik, yaitu pemisahan fraksi berdasarkan
perbedaan titik didih.

Part of CDU
Main Compartment
Crude Distillation Tower
Atmospheric Sidestream Stripper

Supporting Compartment
Heater, reboiler, fraction accumulator, KO Drum, fuel
gas KO drum, heat exchanger, fan, compressor, pump

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IMAGES HERE
+ OPERATIONAL CONDITION

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NAPHTA RE-RUN UNIT

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Function of NRU
Berfungsi untuk memisahkan fraksi ringan dari straight
run naphtha pada topping unit menjadi Light Naphtha
dan Heavy Naphtha serta gas untuk bahan bakar kilang
(feed gas).

Part of NRU
Main Compartment
Re-Run Tower
Re-Run Stabilizer

Supporting Compartment
Re-run accumulator, stabilizer accumulator, reboiler,
heat exchanger, pump

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IMAGES HERE
+ OPERATIONAL CONDITION

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NAPHTA HYDROTREATING UNIT

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Function of NHU
Berfungsi menghilangkan impurities, seperti sulfur,
oksigen dan nitrogen, serta menjenuhkan olefin yang
terdapat dalam stabilized naphtha dari Delayed Coker
Unit (DCU) dan naphtha dari Hydrocracker dengan
bantuan katalis S-16.

Part of NHU
Main Compartment
Hydrotreating Reactor
Naphtha Stripper
Naphtha Splitter
Supporting Compartment
Feed surge drum, compressor suction drum, drum, heat
exchanger, pump, fan, compressor

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IMAGES HERE
+ OPERATIONAL CONDITION

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HYDRO CRACKING
COMPLEX
1. Hydrocracker Unibon (HCU)
2. Amine and LPG Recovery
3. Hydrogen Plant
4. Sour Water Stripper
5. Nitrogen Plant

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HYDROCRACKER UNIBON
(HCU)

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Function of HCU
Berfungsi untuk mengolah Heavy Vacuum Gas Oil
(HVGO) yang berasal dari HVU dan Heavy Cooker Gas
Oil (HCGO) yang berasal dari DCU menjadi fraksi yang
lebih ringan melalui reaksi Hydrocracking dengan
bantuan gas Hidrogen (H2) yang berasal dari H2 plant.

Part of HCU
Main Compartment
Reactor
Fractination Collumn

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IMAGES HERE
+ OPERATIONAL CONDITION

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AMINE AND LPG RECOVERY

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Function of Amine & LPG Recovery
Berfungsi untuk menghilangkan senyawa sulfur dari gas
LPG yang dihasilkan di unit-unit lain untuk mencegah
rusaknya katalis di H2 plant serta mencegah terjadinya
korosi di tangki LPG, dan untuk mendapatkan produk-
produk LPG degan kadar C3 dan C4 yang diinginkan.

Part of Amine & LPG Recovery


Main Compartment
Absorben Section (off gas amine absorberand LPG
amine absorber
Amine Regeneration (vapor amine stripper)

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IMAGES HERE
+ OPERATIONAL CONDITION

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HYDROGEN PLANT (H2 PLANT)

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Function of H2 Plant
Berfungsi untuk menghasilkan hidrogen dengan
menggunakan sistem reforming dan gas yang kaya
hidrogen. Unit ini terdiri dari 2 buah train dan dibangun
untuk memenuhi kebutuhan hidrogen yang diperlukan
pada proses Hydrocracking Unit.

Part of H2 Plant
Main Process
Desulfurization
Steam reforming
Shift convention
CO2 absorbtion
Methanator

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IMAGES HERE
+ OPERATIONAL CONDITION

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SOUR WATER STRIPPER (SWS)

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Function of SWS
Berfungsi untuk me-reuse air dari refinery sour water
dengan menurunkan kadar kontaminan berupa H 2S dan
NH3 yang terkandung di dalamnya.

Part of SWS
Main Compartment
Sour Water Degassing Drum
Sour Water Stripper

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IMAGES HERE
+ OPERATIONAL CONDITION

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NITROGEN PLANT (N2 PLANT)

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Function of N2 Plant
Berfungsi untuk menghasilkan nitrogen yang diperlukan
pada proses start up dan shut down unit-unit proses,
regenerasi katalis dan media blanketting tangki-tangki.
Prinsip operasinya adalah pemisahan oksigen dan
nitrogen dari udara berdasarkan titik embunnya. Proses
ini menggunakan molecular sieve absorber untuk
menyerap uap air dalam udara.

Part of N2 Plant
Main Compartment
Screw Compressor
Intercooler
System Fresh Refrigerant
Retification Column
Nitrogen Storage Tank
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IMAGES HERE
+ OPERATIONAL CONDITION

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HEAVY OIL
COMPLEX
1. High Vacuum Distillation Unit (HVU)
2. Delayed Coking Unit (DCU)
3. Distillate Hydrotreating Unit (DHDT)
4. Coke Calciner Unit (CCU)

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HIGH VACUUM DISTILLATION
UNIT (HVU)

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Function of HVU
Berfungsi untuk memisahkan umpan LSWR dari CDU
berdasarkan perbedaan titik didih. Prinsip operasi unit
HVU adalah distilasi pada kedaan vakum, karena
penurunan tekanan menyebabkan penurunan titik didih
hingga proses pemisahan dapat dilakukan tanpa terjadi
thermal cracking.

Part of HVU
Main Compartment
Feed Surge Drum
Vacuum Tower
Heat Exchanger

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IMAGES HERE
+ OPERATIONAL CONDITION

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DELAYED COKING UNIT (DCU)

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Function of DCU
Berfungsi untuk mengolah short residu dari Vacuum
Distillation Unit (HVU) menjadi coke (kokas), fraksi-
fraksi minyak yang lebih ringan dan gas. Prinsip reaksi
adalah thermal cracking, yaitu perengkahan
hidrokarbon berat menjadi hidrokarbon rantai pendek
pada temperature tinggi (500 oC). Tingginya
temperature menyebabkan terjadinya polimerisasi.

Part of DCU
Main Compartment
Coke Drum
Fractinator
Stripper
Heat Exchanger

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IMAGES HERE
+ OPERATIONAL CONDITION

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DISTILLATE HYDROTREATING UNIT (DHDT)

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Function of DHDT
Berfungsi untuk mengolah light coker gas oil (LCGO)
dari delayed coker unit (DCU) dengan cara
menjenuhkan material hasil cracking yang tidak stabil
dan membuang pengotor seperti sulfur dan nitrogen
dengan bantuan gas hidrogen bertekanan. Reaksi yang
terjadi dalam reaktor adalah penjenuhan olefin,
penghilangan sulfur, penghilangan nitrogen,
penghilangan oksigen, penghilangan logam, dan
penghilangan halida.
Part of DHDT
Main Compartment
Heat Exchanger
Reactor
Stripper
HP Separator
Splitter
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IMAGES HERE
+ OPERATIONAL CONDITION

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COKE CALCINER UNIT (CCU)

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Function of CCU
Berfungsi untuk mengolah green coke menjadi calcined
coke. Proses pengolahannya adalah pembakaran pada
suhu 1350oC untuk menghilangkan material karbon
yang mudah menguap dan kandungan air.

Part of CCU
Main Compartment
Green Coke Bin/Drum
Calciner Rotary Kiln
Cooler

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IMAGES HERE
+ OPERATIONAL CONDITION

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STORAGE &
PACKAGING
SECTION

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SILO AND BAGGING
Pneumatic conveying blower let the air to bring the
pellet to silo storage.

These are the kinds of silo in PT. Chandra Asri Tbk.


Transition bin silo
Aim grade bin silo
Utility bin silo

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UTILITY
SECTION

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UTILITY UNIT
1. Instrument Air System
2. Sea Water System
3. Fire Water System
4. Water Treatment
5. Hydrogen Generator
6. Steam Boiler
7. Liquid Propylene Storage

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INSTRUMENT AIR
SYSTEM

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SEA WATER SYSTEM
Use only for cooling water unit in PHE (Plate and Frame
Heat Exchanger), Hypochlorite Plant, and fire system (in case
there is no fresh water that available).

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SEA WATER INTAKE

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HYPOCHLORITE UNIT
To produce NaOH from sea water to control the
spreading of microbiology organism in sea water intake.

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PLATE AND FRAME HEAT EXCHANGER

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FIRE WATER SYSTEM
Fire Water is supplied from fresh water-tank that has 11
kg/cm2G pressure.

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WATER TREATMENT
1. Water for cooling in PHE is sea water.
2. Water for steam-boiler is demineralized water.
3. Water for fire-system is fresh water.
4. Water for hydrogen generator is polish water.

Note:
Polish water is made from demineralized water by
using mix bed polisher.
Demineralized water is made from demineralization
process

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HOW TO MAKE
DEMINERALIZED WATER

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HYDROGEN
GENERATOR
To produce hydrogen and oxygen from water polish by
electrolysis process.

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STEAM BOILER
To produce steam from demineralized water.
Use Deaerator to separate oxygen (from demineralized
water) to reduce corrosion at boiler during operation.

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LIQUID PROPYLENE
STORAGE
There are 2 types of propylene storage:

1. Low Pressure Propylene Storage (2 Tanks)


Cylindrical with double wall (perlite and re-silent blanket).
Fixed roof tank
Capacity: 12000 MT
Temperature: -48C

2. High Pressure Propylene Storage (2 Tanks)


Spherical
Pressure: 30 kg/cm2G
Capacity: 2 x 3000 m3 ; 1 x 4000 m3
Temperature: 30C

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LOW PRESSURE
PROPYLENE TANK
Tokeep propylene in liquid condition. Vapor that
formed was flown into BOG compressor (2 stages) and
converted to 15-16 kg/cm2G with the 115C-120C.
After that, cooled by condenser till the temperature is
about 30C-35C, with constant pressure. The
condensate was stored to the condensate drum, so the
pressure will be decreased and sent to the flash drum
(operational condition of P=3 kg/cm2G, T=-12C) and
then stored back to tank.
The process transfer from storage tank to the
purification unit need to go through propilene pre-
heater (heating media for butanol) until T=30C.
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WASTE WATER
TREATMENT

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WASTE TREATMENT
Controlled by SHE (Safety, Health, and Environmental
Division).
These are kinds of pollution caused on PT. Chandra Asri Tbk.
with each of their preventive ways:
Sound Pollution (use Silencer)
Solid Waste (trash, random-size polypropylene)
Liquid Waste
Neutralization Pit
Distributor pond and oil separator
Final Check Water Pit (to check the condition of water from neutralization
pit and oil separator then
Septic-tank (to process the sanitary water)
Air Waste
Flare (1000 ton/day. Pilot burner use propane)

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CLOSING
STATEMENT

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